Eco-Friendly Dyeing of Cotton Fabrics Using Dalbergia sissoo Wood Waste Extract and Bio-mordants for Multifunctional Performance

Document Type : Original Article

Authors

1 Department of Textile Engineering, Uttara University, P.O. Box: 1230, Dhaka, Bangladesh

2 Department of Textile Engineering, Dhaka University of Engineering & Technology, P.O. Box: 1707, Gazipur, Bangladesh

Abstract

Considering increasing environmental awareness, research has shifted towards the development of eco-friendly alternatives to synthetic dyes. This study analyzes the potential of Dalbergia sissoo wood waste, a natural dye source containing neoflavonoids, for use in 100 % cotton fabric. The dye was applied using bio-mordants at 90 °C for 60 minutes without using other auxiliaries. The color strength (K/S) results showed that the dyed cotton fabric without any mordant provided a moderate K/S value of 1.5. However, the involvement of amla as a bio-mordant considerably increased the color intensity, resulting in a higher K/S value of 3.2. FTIR analysis confirms the intermolecular interactions between cotton fibers and dye molecules. The colored fabrics provided satisfactory fastness properties. The undyed fabric and dyed fabric without mordant displayed high moisture management ability (OMMC 0.8563 and 0.8657, respectively), while dyed fabrics mordanted with aloe vera, tamarind, myrobalan, and amla showed lower performance due to pore blockage by bio-mordant residues. The dyed fabric exhibited functional properties, including improved ultraviolet protection, and achieved a reduction of 52.4 % in bacterial count compared to the undyed samples. Overall, the outcomes recommend that Dalbergia sissoo wood waste extract can be an effective natural dye for cotton fabric. Moreover, this approach offers an auxiliary-free dyeing process that aligns with eco-friendly textile practices and reduces the environmental footprint of conventional textile dyeing.

Keywords

Main Subjects


  1. Kato S, Kansha Y. Comprehensive review of industrial wastewater treatment techniques. Environ Sci Pollut Res. 2024; 31(39):51064-97https://doi.org/ 10.1007/ s11356-024-34584-0.
  2. Khatun MH, Mostafa MG. Phytochemical screening and extraction of natural dye from leaves of Polyalthia longifolia and its application on silk fabric. J Life 
    Earth Sci. 2019;14:87-92. https://doi.org/Phytochemical Screening and Extraction of Natural 89.
  3. Khatun MH, Mostafa MG. Optimization of dyeing process of natural dye extracted from Polyalthia longifolia leaves on silk and cotton fabrics. J Nat Fibers. 2022;19(16):12996-13011. https://doi.org/10. 1080/15440478.2022.2081281.
  4. Ratnawati DRI, Wisesa A, Sidyawati L. Mahogany wood as natural dyes for textile colouring: Experiment at home industry Batik Wonorejo Village Singosari Malang Regency. Proc Int Semin Lang Educ Cult. 2023; 742:66. https://doi.org/10.2991/978-2-38476-038-1_8
  5. Mia R, Bakar MA, Islam MR, Ahmed T. Eco-friendly coloration from mahogany wood waste for sustainable dyeing of organic nonwoven cotton fabric. Results Eng. 2023;17:101032. https://doi.org/10.1016/j. rineng. 2023.101032.
  6. Kandasamy N, Kaliappan K, Palanisamy T. Upcycling sawdust into colorant: Ecofriendly natural dyeing of fabrics with ultrasound assisted dye extract of Pterocarpus indicus Willd. Ind Crops Prod. 2021; 171: 113969.https://doi.org/10.1016/j.indcrop.2021.113969
  7. Islam T, Khan AM, Karim MR, Hossain S, Jalil MA. Assessing the dyeing efficacy and environmental impact of cotton fabric dyed with sawmill bio-waste extracts and metal salts. SPE Polym. 2024;5(3):444-456. https://doi.org/10.1002/pls2.10136.
  8. Rossi T, Silva PM, De Moura LF, Araújo MD, Brito JO, Freeman HS. Waste from eucalyptus wood steaming as a natural dye source for textile fibers. J Clean Prod. 2017;143:303-10. https://doi.org/10. 1016/j. jclepro.2016.12.109.
  9. Sultana S, Akter K, Sarker MKU, Bhuiyan RH, Haque MM, Islam MR. Color fastness and tensile properties of cotton fabric dyed with extract from Albizia procera sawdust. Fibers Polym. 2022; 23(10):2820-2827. https://doi.org/10.1007/s12221-022-4707-x.
  10. Safapour S, Shabbir M, Rather LJ, Assiri MA. Cleaner sustainable route to develop UV protective and colorful wool yarns: Natural flavonoid-based colorants from Millettia laurentii sawdust. Prog Color Colorant Coat. 2024;17(4):351-363. https://doi.org/ 10.30509/pccc.2024.167264.1278.
  11. Kumar P, Kushwaha P, Khedgikar V, Gautam J, Choudhary D, Singh D, et al. Neoflavonoids as potential osteogenic agents from Dalbergia sissoo heartwood. Bioorg Med Chem Lett. 2014; 24(12): 2664-2668. https://doi.org/10.1016/j.bmcl.2014.04. 056.
  12. Naoumkina M, Hinchliffe DJ, Thyssen GN. Naturally colored cotton for wearable applications. Front Plant Sci. 2024; 15: 1350405. https://doi.org/10.3389/ fpls. 2024.1350405.
  13. Lambrecht L, Capablanca L, Bou-Belda E, Montava I, Díaz-García P, Gisbert-Payá J. Enhancing poly-phenols and tannins concentration on cotton dyed with red tea. Sustainability. 2023; 15(4): 3062. https://doi. org/10.3390/su15043062     
  14. Somparsong Y, Mongkholrattanasit R, Venkataraman M, Srivorradatphisan S, Khojitmate S, Chonsakorn S. Extraction process of color powder and cotton screen printing with natural dyes from Longan leaf powder. ACS Omega. 2025;10(42):49413-25. https://doi.org/ 10. 1021/acsomega.5c00313.
  15. Deepali D, Gulia V, Kumar S, Rani J, Barwant MM, Kumar D. Dalbergia sissoo ethanolic extract: A natural source of antioxidant, antibacterial, and anticorrosive agents. Chem Biodivers. 2025; 22(9): e202500602. https://doi.org/10.1002/cbdv.202500602.
  16. Pandit P, Jose S, Pandey R. Groundnut testa: An industrial agro-processing residue for the coloring and protective finishing of cotton fabric. Waste Biomass Valor. 2021;12(6):3383-3394. https://doi.org/10.1007/ s12649-020-01214-y.             
  17. Nawaz N, Rehman A, Hussain MT, Safdar F, Iqbal K. Dyeing of wool with Dalbergia sissoo as an eco-friendly substituent of conventional hazardous synthetic dye. J Nat Fibers. 2022;19(15):10068-10081. https://doi.org/10.1080/15440478.2021. 1993480.
  18. Iqbal K, Afzal H, Siddiqui MOR, Bashir U, Jan K, Abbas A, et al. Dyeing of wool fabric with natural dye extracted from Dalbergia Sissoo using natural mordants. Sustain Chem Pharm. 2023; 33: 101094. https://doi.org/10.1016/j.scp.2023.101094.
  19. Che J, Dannenberg JM, Yu M, Yang X, Liu Y. Identification, extraction, and application of orange peel color extracts for silk fabric coloration. Heliyon. 2024; 10(1). https://doi.org/10.1016/j.heliyon.2023. e23836 .
  20. Vankar PS, Shanker R, Wijayapala S. Dyeing of cotton, silk and wool with bark extract of Artocarpus heterophyllus Lam. Res J Text Apparel. 2011; 15(2): 52–60. https://doi.org/10.1108/RJTA-15-02-2011-B006.
  21. Bhuiyan MR, Bakkar A, Ali A, Uddin MN, Talha AR, Mohammad RM. Synergistic effect of henna and betel leaf extract on dyeing and antimicrobial performance of silk fabric. Fiber Polym. 2024; 25(7): 2683-2693.https://doi.org/10.1007/s12221-024-00595 -4
  22. Rehman A, Irfan M, Hameed A, Saif MJ, Qayyum MA, Farooq T. Chemical-free dyeing of cotton with functional natural dye: A pollution-free and cleaner production approach. Front Environ Sci. 2022; 10: 848245. https://doi.org/10.3389/fenvs.2022.848245.
  23. Haque MA, Omio MAR, Saha R. Sustainable chemical-free dyeing of cotton-polyester blended (CVC) fabric with punica granatum extracts: a green approach. Prog Color Colorants Coat. 2026; 19(3): 317-327. https://doi.org/10.30509/pccc.2025.167652. 1443.
  24. Ji X, Zhao Z, Ren Y, Xu F, Liu J. Dyeing properties, color gamut, and color evaluation of cotton fabrics dyed with Phellodendron amurense Rupr. (Amur cork tree bark). Molecules. 2023; 28(5): 2220. https://doi. org/10.3390/molecules28052220.
  25. Vashist P, School S, Basak S, Ali W. Bark extracts as multifunctional finishing agents for technical textiles: A scientific review. AATCC J Res. 2021; 8(2): 26-37. https://doi.org/10.14504/ajr.8.2.4.
  26. Sivajiganesan S. Eco-friendly natural dye from bark of Acacia leucophloea for dyeing of cotton fabric using different temperature and mordant. Asian J Res Chem. 2017; 10(1): 1–5. https://doi.org/10.5958/0974-4150.2017.00001.3.
  27. Bhuiyan MR, Bakkar A, Ali A, Uddin MN, Talha AR, Mohammad RM. Synergistic effect of henna and betel leaf extract on dyeing and antimicrobial per-formance of silk fabric. Fibers Polym. 2024; 25(7): 2683-2693. https://doi.org/10.1007/s12221-024-00595 -4.
  28. Lambrecht L, Capablanca L, Bou-Belda E, Montava I, Díaz-García P, Gisbert-Payá J. Enhancing polyphenols and tannins concentration on cotton dyed with red tea. Sustainability. 2023;15(4):3062. https:// doi.org/10.3390/su15043062.
  29. Freymann E, Carvalho S, Garbe LA, Dwi Ghazhelia D, Hobaiter C, Huffman MA, et al. Pharmacological and behavioral investigation of putative self-medicative plants in Budongo chimpanzee diets. PLoS One. 2024; 19(6): e0305219. https://doi.org/10.1371/ journal.pone.0305219.
  30. Habib N, Adeel S, Ali F, Amin N, Khan SR. Environmental friendly sustainable application of plant-based mordants for cotton dyeing using Arjun bark-based natural colorant. Environ Sci Pollut Res. 2021; 28(38): 54041-54047. https://doi.org/10. 1007/ s11356-021-14536-8.
  31. Rahman MM, Kim M, Youm K, Kumar S, Koh J, Hong KH. Sustainable one-bath natural dyeing of cotton fabric using turmeric root extract and chitosan biomordant. J Clean Prod. 2023; 382: 135303. https://doi.org/10.1016/j.jclepro.2022.135303.
  32. Duru SC, Candan C, Nergis B. Development of UV-protective hemp-based eco-friendly textiles. J Appl Polym Sci. 2025; 142(15):e56737. https://doi.org/ 10.1002/app.56737.
  33. Boothby-Shoemaker WT, Mohammad TF, Ozog DM, Lim HW. Photoprotection by clothing: a review. Photodermatol Photoimmunol Photomed. 2022; 38(5): 478-488. https://doi.org/10.1111/phpp.12776.
  34. Choi NY, Park BI. Dyeing performance and anti-superbacterial activity of cotton fabrics dyed with Chamaecyparis obtusa. Molecules. 2023;28(18): 6497. https://doi.org/10.3390/molecules28186497.
  35. Brudzyńska P, Sionkowska A, Grisel M. Cotton textile dyeing by Plant-Derived Colorants in the Presence of Natural Additives. Fibers Polym. 2023; 24(10):3641-3655.https://doi.org/10.1007/s12221-023 -00332-3.
  36. Benli H. Bio-mordants: a review. Environ Sci Pollut Res. 2024;31(14):20714–20771. https://doi.org/10. 1007/s11356-024-32174-8.
  37. Uddin MA, Rahman MM, Haque AN, Smriti SA, Datta E, Farzana N, Chowdhury S, Haider J, Sayem AS. Textile colouration with natural colourants: a review. Journal of Clean Prod. 2022; 349:131489. https://doi:10.1016/j.jclepro.2022.131489.
  38. Khatun H, Alam S, Aziz MA, Karim MR, Rahman MH, Rabbi MA, et al. Plant-assisted green preparation of silver nanoparticles using leaf extract of Dalbergia sissoo and their antioxidant, antibacterial and catalytic applications. Bioprocess Biosyst Eng. 2024; 47(8): 1347-1362. https://doi.org/10.1007/s00449-024-03029 -w.
  39. Agrawal A, Gupta C, Aggarwal S. Textile application of natural dye extracted from myrobalan (Terminalia chebula): Process optimisation using RSM. J Text Assoc. 2025;86(2):221-229. https://doi.org/10.63665 /jta.v86i2.14.
  40. Istyami AN, Arif M, Azzindi MI, Pratiwi M, Adisasmito S, Damayanti NY, et al. Utilization of tamarind seeds extract as a natural and sustainable fabric dye. Indones J Chem Res. 2024;11(3):190-196. https://doi.org/10.30598/ijcr.2024.11-ast.
  41. Khan IA, Khalid H, Javed K, Fraz A, Pasha K, Khan A. Dyeing and functional finishing of cotton fabric using Ficus carica and Eucalyptus leaf extracts with Aloe barbadensis Miller as a bio-mordant. Resources. 2025;14(8):127. https://doi.org/10.3390/resources140 80127.
  42. Thakker AM, Sun D. Innovative plant-based mordants and colorants for application on cotton fabric. J Nat Fibers. 2022; 19(16): 14346-14364. https://doi.org/10.1080/15440478.2022.2064391.
  43. Saeed A, Hassan K, Sadaf SS. A review on colour fastness of natural dyed textiles. Pak J Sci Ind Res Ser A Phys Sci. 2023; 66(2): 201-212. https://doi.org/10. 52763/PJSIR.PHYS.SCI.66.2.2023.201.212.
  44. Pizzicato B, Pacifico S, Cayuela D, Mijas G, Riba-Moliner M. Advancements in sustainable natural dyes for textile applications: a review. Molecules. 2023; 28(16): 5954. https://doi.org/10.3390/molecules28165 954.
  45. Samanta AK, Agarwal P. Application of natural dyes on textiles. Indian J Fibre Text Res. 2009; 34(4): 384-399. https://doi.org/IJFTR.
  46. Kumar R, Dayal R, Onial P. Utilization of Tagetes minuta aerial parts as a source of natural dyes for textile coloration. Waste Biomass Valor. 2014; 5(4): 699-707. https://doi.org/10.1007/s12649-013-9266-3.
  47. Srivastava A, Singh TG. Utilization of Aloe vera for dyeing natural fabrics. Asian J Home Sci. 2011; 6: 1-4.
  48. Matusiak M, Kamińska D. Liquid moisture transport in cotton woven fabrics with different weft yarns. Materials. 2022; 15(18):6489. https://doi.org/10.3390/ ma 15186489.
  49. Amir S, Fan J. Concurrent and real-time measurement of fabric liquid moisture management properties using a novel sweating simulator. Text Res J. 2023; 93(3-4): 774-794. https://doi.org/10.1177/00 405175221124337.
  50. Chu C, Hu C, Sun Y, Yan H, Zhang Y, Ning F. Structural design and vertical wicking behavior of cotton roving-based materials for nutrient transport of indoor plant. J Eng Fibers Fabr. 2021;16:15589250 211066797. https://doi.org/10.1177/155892502110667 97.
  51. Serrano-Martínez VM, Ruzafa-Silvestre C, Hernández - Fernández C, Bañón-Gil E, Arán-Ais F, Orgilés-Calpena E. Improving cotton fabric dyeability by oxygen plasma surface activation. Surfaces. 2024; 7(4): 1079-1095. https://doi.org/10.3390/surfaces70 40071.
  52. Chao YC, Ho TH, Cheng ZJ, Kao LH, Tsai PS. A study on combining natural dyes and environmentally-friendly mordant to improve color strength and ultraviolet protection of textiles. Fibers Polym. 2017; 18(8):1523-1530. https://doi.org/10.1007/s12221-017- 6964-7.
  53. El-Zawahry M, Shokry G, El-Khatib HS, Rashad HG. Eco-friendly dyeing using hematoxylin natural dye for pretreated cotton fabric to enhance its functional properties. Egypt J Chem. 2021; 64(12): 7135-7145. https://doi.org/10.21608/ejchem.2021.82158.4049.
  54. Nazir F, Siddique A, Nazir A, Javed S, Hussain T, Abid S. Eco‐friendly dyeing of cotton using waste‐derived natural dyes and mordants. Color Technol. 2022;138(6):684-92. https://doi.org/10.1111/cote.126 29.
  55. Akatwijuka O, Abdelgawad AM, Hassanin AH. Valorization of natural bark cloth fabric from Ficus natalensis for potential antimicrobial applications. Biomass Convers Biorefin. 2024; 14(24): 31461-31474. https://doi.org/10.1007/s13399-023-04790-w
  56. Mia R, Das S, Banna BU, Ahmed T, Bakar MA. Enhancing antibacterial properties of organic cotton fabric using mahogany wood waste. Case Stud Chem Environ Eng. 2023;8:100387. https://doi.org/ 10.1016/ j.cscee.2023.100387.
  57. Bhuiyan MAR, Islam A, Islam S, Hossain A, Nahar K. Improving dyeability and antibacterial activity of Lawsonia inermis L. on jute fabrics by chitosan pretreatment. Text Cloth Sustain. 2017; 3(1): 1. https://doi.org/10.1186/s40689-016-0023-4.
  58. Yuan G, Guan Y, Yi H, Lai S, Sun Y, Cao S. Antibacterial activity and mechanism of plant flavonoids to gram-positive bacteria predicted from their lipophilicities. Sci Rep. 2021; 11(1): 10471. https://doi.org/ (2021) 11:10471.
  59. Yan Y, Xia X, Fatima A, Zhang L, Yuan G, Lian F, et al. Antibacterial activity and mechanisms of plant flavonoids against gram-negative bacteria based on the antibacterial statistical model. Pharmaceuticals. 2024; 17(3): 292. https://doi.org/10.3390/ph17030292
  60. Intharuksa A, Kuljarusnont S, Sasaki Y, Tungmunnithum D. Flavonoids and other polyphenols: bioactive molecules from traditional medicine recipes/ medicinal plants and their potential for phyto-pharmaceutical and medical application. Molecules. 2024;29(23):5760.https://doi.org/10.3390/molecules29235760.
  61. Hossain MM, Islam T, Jalil MA, Rakibuzzaman SM, Surid SM, Zabed MRI, et al. Advancements of eco-friendly natural antimicrobial agents and their transformative role in sustainable textiles. SPE Polym. 2024;5(3):241-276. https://doi.org/10.1002/pls2.10135. 
  62. Mao D, Xu H. The antimicrobial potential of plant-based natural dyes for textile dyeing: A systematic review using PRISMA. AUTEX Res J. 2024; 24(1): 20240016. https://doi.org/10.1515/aut-2024-0016.
  63. Alemu Reta B, Babu KM, Tesfaye T. Studies on healthcare and hygiene textile materials treated with natural antimicrobial bioactive agents derived from plant extracts. AATCC J Res. 2024; 11(2): 73-89. https://doi.org/10.1177/24723444231215444.
  64. Ketema A, Worku A. Optimization of process conditions of cotton fabric dyeing with nettle leaf extract for antibacterial application using central composite design. J Nat Fibers. 2023; 20(2): 2228485. https://doi.org/10.1080/15440478.2023.2228485.
  65. Nsangou ABD, Sibiescu D, Nkemaja DE, Noah PMA, Betene FE, Hambaté GV. Aloe vera gel as a biomordant in the finishing of vegetable textiles: a review. Bul Inst Polit Iaşi. 2024;68(72):4. https://doi. org/10.5281/zenodo.7539811.
  66. Prabhu KH, Teli MD. Eco-dyeing using Tamarindus indica L. seed coat tannin as a natural mordant for textiles with antibacterial activity. J Saudi Chem Soc. 2014; 18(6): 864-872. https://doi.org/10.1016/j.jscs. 2011.10.014.