Antibacterial Corrosion Inhibitor for the Protection of Mild Steel in 1 M HCl Solution

Document Type : Original Article

Authors

1 Department of Chemical Engineering, University of Technology, P. O. Box: 10001, Baghdad, Iraq

2 Technical Hospital Al-Muthana, Ministry of Health, P. O. Box: 66002, Al-Muthana, Iraq

3 Air Conditioning and Refrigeration Technology Department, Al-Mustaqbal University College, P. O. Box: 51001, Babylon, Iraq

4 Department of Production Engineering and Metallurgy, University of Technology, Baghdad, P. O. Box: 10001, Iraq

5 Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia (UKM), P.O. Box: 43000, Bangi 43600, Selangor, Malaysia

6 Energy and Renewable Energies Technology Center, University of Technology, P. O. Box: 10001, Baghdad, Iraq

7 Department of Medicine, University of Al-Ameed, P. O. Box: 56001, Karbala, Iraq

Abstract

Mild steel is widely utilised as a construction material because of its mechanical qualities and low cost but its weak acid corrosion resistance limits its application. The ability of para-chlorobenzoyl-hydrazinylmethane (P-CBHM) as a corrosion inhibitor and antibacterial agent was investigated by gravimetric measurements, density functional theory (DFT) and antibacterial studies. The weight loss results showed that the inhibition efficiency of P-CBHM to prevent the corrosion of mild steel in 1.0 M HCl increased with concentration from 100 to 500 ppm, with a maximum inhibition efficiency of 96.5 % at 500 ppm. The inhibitory action of the inhibitor was explained in terms of adsorption on the mild steel surface which follows a Langmuir isotherm via physisorption and chemisorption mechanisms. P-CBHM has significant corrosive protection efficacy and antimicrobial activity similar to the common antibacterial agent, chloramphenicol. The novelty of this work was the investigation of the protective response of P-CBHM which was analysed analytically on the corrosion of mild steel in 1.0 M hydrochloric acid using gravimetric and thermometric techniques and its antibacterial effects.

Keywords

Main Subjects


1.   A. Al-Amiery, L. Shaker, A. Kadhum, M. Takriff, Corrosion inhibition of mild steel in strong acid environment by 4-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)amino)benzenesulfonamide, Tribol. Ind., 42(2020), 89-101. 
2.   K. Aly, A. Mahdy, M. Hegazy, N. Al-Muaikel, S. Kuo, M. Gamal Mohamed, Corrosion resistance of mild steel coated with phthalimide-functionalized polybenzoxazines, Coatings, 10(2020), 1114.
3.   A. Al-Amiery, T. Salman, K. Alazawi, L. Shaker, A. Kadhum, M. Takriff, Quantum chemical elucidation on corrosion inhibition efficiency of Schiff base: DFT investigations supported by weight loss and SEM techniques, Int. J. Low Carbon Technol., 15(2020), 202-209.
4.   A. Al-Amiery, L. Shaker, A. Kadhum, M. Takriff, Synthesis, characterization and gravimetric studies of novel triazole-based compound, Int. J. Low Carbon Technol., 15(2020), 164-170. 
5.   K. Aly, M. Mohamed, O. Younis, M. Mahross, M. Abdel-Hakim, M., Sayed, Salicylaldehyde azine-functionalized polybenzoxazine: Synthesis, characterization, and its nanocomposites as coatings for inhibiting the mild steel corrosion, Prog. Org. Coat., 138(2020), 105385.
6.   K. Aly, O. Younis, M. Mahross, E. Orabi, M. Abdel-Hakim, O. Tsutsumi, M. Sayed, Conducting copolymers nanocomposite coatings with aggregation-controlled luminescence and efficient corrosion inhibition properties, Prog. Org. Coat., 135(2019), 525-535.
7.   A. Al-Amiery, A. Kadhum, A. Kadihum, A., Mohamad, C. How, S. Junaedi, Inhibition of mild steel corrosion in sulfuric acid solution by new schiff base, Mater., 7(2014), 787-804. 
8.   A. Al-Amiery, L. Shaker, Corrosion inhibition of mild steel using novel pyridine derivative in 1 M hydrochloric acid, Koroze Ochr. Mater., 64(2020), 59-64. 
9.   A. Al-Amiery, Anti-corrosion performance of 2-isonicotinoyl-n-phenylhydrazinecarbothioamide for mild steel hydrochloric acid solution: Insights from experimental measurements and quantum chemical calculations, Surf. Rev. Lett., 28(2021), 1-8. 
10. M. Mohamed, S. Kuo, A. Mahdy, I. Ghayd, K. Aly, Bisbenzylidene cyclopentanone and cyclohexanone-functionalized polybenzoxazine nanocomposites: Synthesis, characterization, and use for corrosion protection on mild steel, Mater. Today Commun., 25(2021), 101418.
11. M. Mohamed, A. Mahdy, R. Obaid, M. Hegazy, S. Kuo, K. Aly, Synthesis and characterization of polybenzoxazine/clay hybrid nanocomposites for UV light shielding and anti-corrosion coatings on mild steel, J. Polym. Res., 28(2021), 297.
12. S. Al-Baghdadi, T. Gaaz, A. Al-Adili, A., Al-Amiery, M. Takriff, Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation, Int. J. Low Carbon Technol., 16(2021), 181-188. 
13. S. Al-Baghdadi, F. Hashim, A. Salam, T. Abed, T. Gaaz, A. Al-Amiery, A. Kadhum, K. Reda, W. Ahmed, Synthesis and corrosion inhibition application of NATN on mild steel surface in acidic media complemented with DFT studies, Results Phys., 8(2018) 1178-1184. 
14.  S. Al-Baghdadi, A. Al-Amiery, A. Kadhum, M. Takriff, Computational calculations, gravimetrical, and surface morphological investigations of corrosion inhibition effect of triazole derivative on Mild Steel in HCl, J. Comput. Theor. Nanosci., 17(2020), 4797-4804. 
15. S. Al-Baghdadi, A. Kadhim, G. Sulaiman, A. Al-Amiery, A. Kadhum, M. Takriff, Anticorrosion and antibacterial effects of new Schiff base derived from hydrazine, J. Phys. Conf. Ser., 1795(2021), 012021.1
16. S. Al-Taweel, T. Gaaz, L. Shaker, A. Al-Amiery, Protection of mild steel in h2so4 solution with 3-((3-(2-hydroxyphenyl)-5-thioxo-1,2,4-triazol-4-yl)imino)indolin-2-one, Int. J. Corros. Scale Inhib., 9(2020), 1014-1024. 
17.  A. Alamiery, E. Mahmoudi, T. Allami, Corrosion inhibition of low-carbon steel in hydrochloric acid environment using a Schiff base derived from pyrrole : gravimetric and computational studies, Int. J. Corros. Scale Inhib., 10(2021), 749-765. 
18.  A. Alamiery, L. Shaker, T. Allami, A. Kadhum, S. Takriff, A study of acidic corrosion behavior of Furan-Derived schiff base for mild steel in hydrochloric acid environment: Experimental, and surface investigation, Mater. Today, 44(2021), 2337-2341. 
19.  M. Mohamed, A. Mahdy, R. Obaid, Synthesis and characterization of polybenzoxazine/clay hybrid nanocomposites for UV light shielding and anti-corrosion coatings on mild steel, J. Polym. Res., 28(2021), 297. 
20.  ASTM International, Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test, (2011), 1-9
21.  A. Eltmimi, A. Alamiery, T. Allami, M. Yusop, Inhibitive effects of a novel efficient Schiff base on mild steel in hydrochloric acid environment, Int. J. Corros. Scale Inhib., 4(2021), 634-648. 
22. H. Habeeb, H. Luaibi, T. Abdullah, R. Dakhil, A. Kadhum, A. Al-Amiery, Case study on thermal impact of novel corrosion inhibitor on mild steel, Case Stud. Therm. Eng., 12(2018), 64-68. 
23. H. Habeeb, H. Luaibi, R. Dakhil, A. Kadhum, A. Al-Amiery, T. Gaaz, Development of new corrosion inhibitor tested on mild steel supported by electrochemical study, Results Phys., 8 (2018), 1260-1267. 
24.  M. Hanoon, A. Resen, L. Shaker, A. Kadhum, A. Al-Amiery, Corrosion investigation of mild steel in aqueous hydrochloric acid environment using n-(Naphthalen-1yl)-1-(4-pyridinyl)methanimine complemented with antibacterial studies, Biointerface Res. Appl. Chem., 11 (2021), 9735-9743. 
25.  M. Hanoon, D. Zinad, A. Resen, A. Al-Amiery, Gravimetrical and surface morphology studies of corrosion inhibition effects of a 4-aminoantipyrine derivative on mild steel in a corrosive solution, Int. J. Corros. Scale Inhib., 9 (2020), 953-966. 
26. D. Jamil, A. Al-Okbi, S. Al-Baghdadi, A. Al-Amiery, A. Kadhim, T. Gaaz, A. Kadhum, A. Mohamad, Experimental and theoretical studies of Schiff bases as corrosion inhibitors, Chem. Cent. J., 12(2018), 1-9.
27.  Q. Jawad, A. Hameed, M. Abood, A. Al-Amiery, L. Shaker, A. Kadhum, M. Takriff, Synthesis and comparative study of novel triazole derived as corrosion inhibitor of mild steel in hcl medium complemented with calculations, Int. J. Corros. Scale Inhib., 9(2020), 688-705. 
28. S. Junaedi, A. Al-Amiery, A. Kadihum, A. Kadhum, A. Mohamad, Inhibition effects of a synthesized novel 4-aminoantipyrine derivative on the corrosion of mild steel in hydrochloric acid solution together with quantum chemical studies, Int. J. Mol. Sci., 14(2013), 11915-11928. 
29.  S. Junaedi, A. Kadhum, A. Al-Amiery, A. Mohamad, M. Takriff, Synthesis and characterization of novel corrosion inhibitor derived from oleic acid: 2-Amino 5-Oleyl-1,3,4-Thiadiazol (AOT), Int. J. Electrochem. Sci., 7(2012), 3543-3554. 
30.  S. Junaedi, A. Al-Amiery, A. Kadihum, A. Kadhum, A. Mohamad, Inhibition effects of a synthesized novel 4-aminoantipyrine derivative on the corrosion of mild steel in hydrochloric acid solution together with quantum chemical studies, Int. J. Mol. Sci., 14(2013), 11915-11928.
31.  H. Obayes, A. Al-Amiery, G. Alwan, T. Abdullah, A. Kadhum, A. Mohamad, Sulphonamides as corrosion inhibitor: Experimental and DFT studies, J. Mol. Struct., 1138(2017), 1-9. 
32.  E. Sheet, J. Yamin, H. Al-Salihi, A. Salam, K. Reda, W. Ahmed, M. Mahdi, A. Al-Amiery, N-(3-nitrobenzylidene)-2-aminobenzothiazole as new locally available corrosion inhibitor for iraqi oil industry, J. Balk. Tribol. Assoc., 26(2020), 194-203.
33.  J. Yamin, E. Sheet, A. Al-Amiery, Statistical analysis and optimization of the corrosion inhibition efficiency of a locally made corrosion inhibitor under different operating variables using RSM, Int. J. Corros. Scale Inhib., 9(2020), 502-518. 
34. D. Zinad, M. Hanoon, R. Salim, S. Ibrahim, A. Al-Amiery, M. Takriff, A. Kadhum, A new synthesized coumarin-derived schiff base as a corrosion inhibitor of mild steel surface in hcl medium: Gravimetric and studies, Int. J. Corros. Scale Inhib., 9(2020), 228-243. 
35.  A. Hilchie, K. Wuerth, R.Hancock, Immune modulation by multifaceted cationic host defense (antimicrobial)peptides. Nat. Chem. Biol. 9(2013), 761–768.
36. Kadhim, A. Al-Amiery, R. Alazawi, M. Al-Ghezi, R. Abass, Corrosion inhibitors. A review. Int. J. Corros. Scale Inhib., 10(2021), 54–67. 
37. Kadhim, A. Al-Okbi, D. Jamil, A. Qussay, A. Al-Amiery, T. Gaaz, A. Kadhum, A. Mohamad, M. Nassir, Experimental and theoretical studies of benzoxazines corrosion inhibitors. Results Phys., 7(2017), 4013–4019. 
38.  Kadhim, G. Sulaiman, A. Abdel Moneim, R. Yusop, A. Al-Amiery, Synthesis and characterization of triazol derivative as new corrosion inhibitor for mild steel in 1M HCl solution complemented with antibacterial studies. J. Phys. Conf. Ser., 1795(2021), 012011. 
39.  D. Zinad, Q. Jawad,  M. Hussain, M. Mahal, L. Mohamed, A. Al-Amiery, Adsorption, temperature and corrosion inhibition studies of a coumarin derivatives corrosion inhibitor for mild steel in acidic medium: Gravimetric and theoretical investigations. Int. J. Corros. Scale Inhib., 9(2020), 134–151. 
40. A. Resen, M. Hanoon, W. Alani, A. Kadhim, A., Mohammed, T. Gaaz, A. Kadhum, A. Al-Amiery, M. Takriff, Exploration of 8-piperazine-1-ylmethylumbelliferone for application as a corrosion inhibitor for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib., 10(2021), 368-387. 
41.  Salim, Q. Jawad, K. Ridah, L. Shaker, A. Al-Amiery, A. Kadhum, M. Takriff, Corrosion inhibition of thiadiazole derivative for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib., 9(2020), 550-561. 
42.  Salman, Q. Jawad, K. Ridah, L. Shaker, A. Al-Amiery, Selected bis-thiadiazole: synthesis and corrosion inhibition studies on mild steel in HCl environment, Surf. Rev. Lett., 27(2020), 1-5. 
43. T. Salman, Q. Jawad, M. Hussain, A. Al-Amiery, L. Mohamed, A. Kadhum, M. Takriff, Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects, Int. J. Corros. Scale Inhib., 8(2019), 1123-1137. 
44. T. Salman, Q. Jawad, M. Hussain, A. Al-Amiery, L. Shaker, A. Kadhum, M. Takriff, New environmental friendly corrosion inhibitor of mild steel in hydrochloric acid solution: Adsorption and thermal studies, Cogent Eng., 7(2020), 1826077. 
45.L. Shaker, A. Al-Adili, A. Al-Amiery, M. Takriff, The inhibition of mild steel corrosion in 0.5 M H2SO4 solution by N-phenethylhydrazinecarbothioamide (N-PHC), J. Phys. Conf. Ser., 1795(2021), 012009. 
46. A. Alamiery, Study of corrosion behavior of N'-(2-(2-oxomethylpyrrol-1-yl) ethyl) piperidine for mild steel in the acid environment, Biointerface Res. Appl. Chem., 12(2022), 3638-3646
47.Alamiery, A. Mohamad, A. Kadhum, M. Takriff, Comparative data on corrosion protection of mild steel in HCl using two new thiazoles, Data Brief, 40(2022), 107838
48. A.M. Mustafa, F.F. Sayyid, N. Betti, L.M. shaker, M.M. Hanoon, A.A. Alamiery, A.A.H. Kadhum, M.S. Takriff, Inhibition of mild steel corrosion in hydrochloric acid environment by 1-amino-2-mercapto-5-(4-(pyrrol-1-yl)phenyl)-1,3,4-triazole, S. Afr. J. Chem. Eng., 39(2022), 42-51.
49. A. Alamiery, Investigations on corrosion inhibitory effect of newly quinoline derivative on mild steel in HCl solution complemented with antibacterial studies, Biointerface Res. Appl. Chem., 12(2022), 1561-1568
50. A. Alkadir Aziz, A. A. Annon, M. Abdulkareem, M Hanoon, M. Alkaabi, L. Shaker, A. Alamiery, W.N.R. Wan Isahak, M. Takriff, Insights into corrosion inhibition behavior of a 5-mercapto-1,2,4-triazole derivative for mild steel in hydrochloric acid solution: experimental and DFT studies, Lubricants, 9(2021), 1-14. 
51.  A. Alamiery, Short report of mild steel corrosion in 0.5 M H2SO4 by 4-ethyl-1-(4-oxo-4-phenylbutanoyl) thiosemicarbazide, J. Tribolog, 30(2021), 90-99.
52.Alamiery, W.N.R.W. Isahak, M. Takriff, Inhibition of mild steel corrosion by 4-benzyl-1-(4-oxo-4-phenylbutanoyl)thiosemicarbazide: Gravimetrical, adsorption and theoretical studies, Lubricants, 9(2021), 1-10.
53.M.A. Dawood, Z.M.K. Alasady, M.S. Abdulazeez, D.S. Ahmed, G.M. Sulaiman, A.A.H. Kadhum, L.M. Shaker6 and A.A. Alamiery, The corrosion inhibition effect of a pyridine derivative for low carbon steel in 1 M HCl medium: Complemented with antibacterial studies, Int. J. Corros. Scale Inhib., 10(2021), 1766-1782. 
54. A. Alamiery, Corrosion inhibition effect of 2-N-phenylamino-5-(3-phenyl-3-oxo-1-propyl)-1,3,4-oxadiazole on mild steel in 1 M hydrochloric acid medium: Insight from gravimetric and DFT investigations, Mater. Sci. Technol., 4(2021), 398-406.
55. Alamiery, A.A. Anticorrosion effect of thiosemicarbazide derivative on mild steel in 1 M hydrochloric acid and 0.5 M sulfuric Acid: Gravimetrical and theoretical studies, Mater. Sci. Technol., 4(2021), 263-273.
56. Alamiery, W.N.R.W. Isahak, H., Aljibori, H. Al-Asadi, A. Kadhum, Effect of the structure, immersion time and temperature on the corrosion inhibition of 4-pyrrol-1-yl-n-(2,5-dimethyl-pyrrol-1-yl)benzoylamine in 1.0 m HCl solution, Int. J. Corros. Scale Inhib., 10 (2021), 700-713. 
57. Al-Amiery, A. Kadhum, A. Mohamad, Antifungal activities of new coumarins, Molecules, 17(2012), 5713-5723.