Effect of PDMS Anti-Blocking Agent in Water-Based Coatings on the Performance of Paper Substrates for Sustainable Packaging

Document Type : Original Article

Authors

Department of Industrial Printing and Packaging Technology, Politeknik Negeri Jakarta, P.O. Box: 16400, Depok, Indonesia.

Abstract

Cellulose-based paper is widely used in sustainable food packaging; however, its inherent limitations in barrier and mechanical properties restrict broader application. This study investigates the role of poly-dimethylsiloxane (PDMS) as an anti-blocking agent in water-based coatings applied to ivory board, kraft paper, and machine-glazed (MG) paper. Three coating formulations were evaluated: a control without PDMS (STD), and formulations containing 0.2 g of PDMS (T-1) and 0.5 g of PDMS (T-2). Coating performance was assessed for blocking resistance, rheological stability, surface friction, coating integrity, barrier properties, and mechanical performance under different storage conditions. The results demonstrate that PDMS incorporation significantly improves anti-blocking behavior, reduces the coefficient of friction, and enhances mechanical durability without compromising water resistance. The formulation with higher PDMS content (T-2) exhibited the most balanced and stable performance during storage, showing improved surface uniformity, lower friction, and enhanced sealing and rub resistance. Substrate-dependent behavior was observed: smooth, dense papers favored uniform surface film formation, while porous substrates promoted coating penetration and mechanical interlocking. These findings highlight the importance of optimizing PDMS concentration and substrate selection to develop high-performance, eco-friendly paper-based coatings for sustainable packaging applications. 

Keywords

Main Subjects

References

  1. Tanpichai S, Witayakran S, Wootthikanokkhan J, Srimarut Y, Woraprayote W, Malila Y. Mechanical and antibacterial properties of chitosan-coated cellulose paper for packaging applications: effects of molecular weight types and concentrations of chitosan. Int J Biol Macromol. 2020; 155:1510–1519. https://doi.org/10. 1016/j.ijbiomac.2019.11.128.
  2. Setajit C, Kongvarhodom C, Xiao H. Development of grease-resistant packaging paper using cellulose nanocrystals and sodium alginate. Sci Adv Mater. 2020; 12(2):212–219. https://doi.org/10.1166/sam. 2020.3628.
  3. Lignou S, Oloyede OO. Consumer acceptability and sensory profile of sustainable paper-based packaging. Foods. 2021;10(5):990. .https://doi.org/10.3390/foods 10050990
  4. Kunam PK, Ramakanth D, Akhila K, Gaikwad KK. Bio-based materials for barrier coatings on paper packaging. Biomass Convers Biorefin. 2024;14(12): 12637-12652. https://doi.org/10.1007/s13399-022-032 41-2.
  5. Zhang W, Xiao H, Qian L. Enhanced water vapour barrier and grease resistance of paper bilayer-coated with chitosan and beeswax. Carbohydr Polym. 2014; 101(1):401-406. https://doi.org/10.1016/j.carbpol. 2013. 09.097.
  6. Lo Faro E, Menozzi C, Licciardello F, Fava P. Improvement of paper resistance against moisture and oil by coating with poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and polycaprolactone. Appl Sci. 2021; 11(17):8058. https://doi.org/10.3390/app111780 58.
  7. Lo Faro E, Bonofiglio A, Barbi S, Montorsi M, Fava P. Polycaprolactone/starch/agar coatings for food-packaging paper: statistical correlation of the formulations’ effect on diffusion, grease resistance, and mechanical properties. Polymers. 2023; 15(19):3921. https://doi.org/10.3390/polym15193921.
  8. Marinelli A, Profaizer M, Diamanti MV, Pedeferri MP, Del Curto B. Heat-seal ability and fold cracking resistance of kaolin-filled styrene–butadiene-based aqueous dispersions for paper-based packaging. Coat. 2023; 13(6):975. https://doi.org/10.3390/coatings13060 975.
  9. Luo H, Zhang S, Li X, Wang J, Chen L. Anti-smudge and self-cleaning characteristics of waterborne polyurethane coatings modified with silicone additives. J Colloid Interface Sci. 2022;628:1070-1081. https://doi. org/10.1016/j.jcis.2022.08.017.
  10. Agustina LA, Lestari YD, Adhinanda AA, Ariesta MN. Study of inorganic-based anti-blocking agents as migration control of slip additives on the surface of polyethylene monolayer films. Acta Chim Asiana. 2024;7:366-376. https://doi.org/10.29303/aca.v7i1. 196
  11. Kumar V, Koppolu VR, Bousfield D, Toivakka M. Substrate role in coating of microfibrillated cellulose suspensions. Cellulose. 2017;24(3):1247-1260. https:// doi.org/10.1007/s10570-017-1201-5.
  12. Sharma M, Aguado R, Murtinho D, Valente A, Ferreira P. Micro-/nanofibrillated cellulose-based coating formu-lations: a solution for improving paper printing quality. Nanomaterials. 2022;12(16):2853. https://doi.org/10. 3390/nano12162853.
  13. Aloui H, Khwaldia K. Effects of coating weight and nanoclay content on functional and physical properties of bionanocomposite-coated paper. Cellulose. 2017; 24(10):4493-4507. https://doi.org/10.1007/s10570-017-1436-1.
  14. Sun G, Qian C, Li Z, Wang Q. Optimizing powder-to-liquid ratios in lost foam casting coatings: impacts on viscosity, shear-thinning behavior, coating weight, and surface morphology. Coatings. 2024;14(9):1089. https://doi.org/10.3390/coatings14091089.
  15. Benz B, Burton D, Ventresca D, Welsch G. Optimizing water and water vapor barrier properties of water-based barrier coatings. TAPPI J. 2025;24(1):7–23.
  16. Khlewee M, Desisto W, Bousfield DW. Water-based adhesive penetration into paperboard and coated paperboard. TAPPI J. 2025;24(1):48–54.
  17. Lin CB, Chang HS, Zhang Y, Yang F, Lee S. Spreading of water droplets on cellulose-based papers: the effect of back-surface coating. Langmuir. 2021;37 (1):e10291. https://doi.org/10.1021/acs.langmuir.0c02 991.
  18. Bolvardi B, Seyfi J, Hejazi I, Otadi M, Khonakdar HA, Davachi SM. Towards an efficient and durable superhydrophobic mesh coated by PDMS/TiO2 nanocomposites for oil/water separation. Appl Surf Sci. 2019; 492:143-152. https://doi.org/10.1016/j.apsusc. 2019.06.268.
  19. Huang J, Cai P, Li M, Wu Q, Li Q, Wang S. Preparation of CNF/PDMS superhydrophobic coatings with good abrasion resistance. Materials. 2020;13 (23):5380. https://doi.org/10.3390/ma13235380.
  20. Yue D, Lin S, Cao M, Lin W, Zhang X. Fabrication of transparent and durable superhydrophobic poly-siloxane/SiO2 coating on the wood surface. Cellulose. 2021; 28(6):3745-3758. https://doi.org/10. 1007/s10570-021-03758-1.
  21. Lavoine N, Desloges I, Dufresne A, Bras J. Microfibrillated cellulose: its barrier properties and applications in cellulosic materials—A review. Carbohydr Polym. 2012;90(2):735–764. https://doi. org/ 10.1016/j.carbpol.2012.05.026.
  22. Kumar D, Wu X, Fu Q, Weng J, Ho C, Kanhere PD, et al. Hydrophobic sol-gel coatings based on poly-dimethylsiloxane for self-cleaning applications. Mater Des. 2015;86:855-862. https://doi.org/10.1016/j. matdes. 2015.07.174.
  23. Joki-Korpela F, Pakkanen TT. Incorporation of polydimethylsiloxane into polyurethanes and charac-terization of copolymers. Eur Polym J. 2011;47(8): 1694-1708. https://doi.org/10.1016/j.eurpolymj. 2011. 06.006.
  24. Palumbo F, Lo Porto C, Favia P. Plasma nano-texturing of polymers for wettability control: why, what and how. Coatings. 2019;9(10):640. https://doi. org/ 10.3390/ coatings9100640.
  25. Dixit N, Maloney KM, Kalonia DS. Effect of processing parameters on the physical stability of silicone coatings. AAPS Pharm Sci Tech. 2012; 13(4): 1116–1124. https://doi.org/10.1208/s12249-012-9842-7.
  26. Sun G, Wang Q, Li S. Influence of mixing and standing times on the rheological properties of shell casting coatings. Coatings. 2024;14(8):954. https://doi.org/10. 3390/coatings14080954.
  27. Yan X, Li M, Zhao M, Zhou H, Wang Y. Effect of PDMS viscosity and curing agent content on the mechanical properties of PDMS fouling-release coatings. J Phys Conf Ser. 2022; 2174:012036. https://doi.org/10.1088/1742-6596/2174/1/012036.
  28. Xia Y, Zhu N, Zhao Y, et al. Construction of durable self-cleaning PDMS film on polyester fabric surface. Materials. 2023;16(2):52. https://doi.org/10.3390/ma 16020052.
  29. Fang J, Dong R, Zhou M, Liang L, Yang M, Xing H, et al. Hydrophobic, durable, and reprocessable PEDOT: PSS/PDMS–PUa/SiO2 film with conductive self-cleaning and de-icing functionality. Coatings. 2025; 15:90985. https://doi.org/10.3390/coatings150 90985
  30. Li Z, Rabnawaz M. Fabrication of food-safe water-resistant paper coatings using a melamine primer and polysiloxane outer layer. ACS Omega. 2018; 3:e00106. https://doi.org/10.1021/acsomega.8b00106
  31. Ji X, Wang H, Ma X, He C, Guo M. Progress in poly-dimethylsiloxane-modified waterborne poly-urethanes. RSC Adv. 2017;7:34086-34095. https://doi.org/10. 1039/ C7RA04768A.
  32. Jutila E, Koivunen R, Gane PAC. Effect of coating pigment, binder type and binder amount on planar liquid wicking on coated substrates. Nord Pulp Pap Res J. 2015; 30(2):173–186. https://doi.org/10. 14622/JPMTR-1419.
  33. Eduok U, Faye O, Szpunar J. Recent developments and applications of protective silicone coatings: a review of PDMS functional materials. Prog Org Coat. 2017;111: 124-163. https://doi.org/10.1016/j.porgcoat.2017.05.012.
  34. Tarigan JBR, Nainggolan I, Kaban J. The physico-chemical and antibacterial properties of galactomannan edible films. J Phys Conf Ser. 2018; 1116(1):012035.
  35. Croll SG. Surface roughness profile and its effect on coating adhesion and corrosion protection: a review. Prog Org Coat. 2020; 148:105847. https://doi.org/10. 1016/j.porgcoat.2020.105847.
  36. Samyn P. Wetting and hydrophobic modification of cellulose surfaces for paper applications. Bio Resources. 2013; 8(3):4323–4344.
  37. Ghaffar SH, Madyan OA, Fan M, Corker J. The influence of additives on the interfacial bonding mechanisms between natural fibre and biopolymer composites. Compos B Eng. 2018; 152:1-10. https://doi.org/10.1016/j.compositesb.2018.06.020
  38. Aslannejad H, Hassanizadeh SM, Raoof A, de Winter DAM, Tomozeiu N. Characterizing the hydraulic properties of paper coating layer using FIB-SEM tomography and 3D pore-scale modeling. Chem Eng Sci. 2017; 160:275-280. https://doi.org/10.1016/j. ces.2016.11.021
  39. Hinder SJ, Lowe C, Maxted JT, Watts JF. Migration and segregation phenomena of a silicone additive in a multilayer organic coating. Prog Org Coat. 2005;54 (2): 104-112.https://doi.org/10.1016/j.porgcoat.2005.06. 001.
  40. Samyn P, Van Erps J, Thienpont H, Schoukens G. Paper coatings with multi-scale roughness evaluated at different sampling sizes. Appl Surf Sci. 2011;257: 5613-5625. https://doi.org/10.1016/j.apsusc.2011.01. 059.
  41. Thorman S, Ström G, Holmberg K, Järnström PÅ. Uniformity of liquid absorption by coatings: technique and impact of coating composition. Nord Pulp Pap Res J. 2012;27(2):459-465. https://doi.org/10.3183/ npprj-2012-27-02-p459-465.
  42. Odhiambo JG, Li W, Zhao Y, Chen C. Porosity and its significance in plasma-sprayed coatings. Coatings. 2019; 9:460. https://doi.org/10.3390/coatings9070460.
  43. Keshmiri K, Huang H, Nazemifard N. Compatibility of polydimethylsiloxane microfluidic systems with high-viscosity hydrocarbons. SN Appl Sci. 2019; 1(7):666. https://doi.org/10.1007/s42452-019-0666-2.
  44. Rastogi VK, Samyn P. Bio-based coatings for paper applications. Coatings. 2015; 5:887-930. https://doi. org/ 10.3390/coatings5040887.
  45. Wang X, Tang H, Li X, Hua X. Investigation on mechanical properties of conducting polymer coating–substrate structures. Int J Mol Sci. 2009; 10(12):5257–5284. https://doi.org/10.3390/ijms10125257.
  46. Li Z, Rabnawaz M. Oil- and water-resistant coatings for porous cellulosic substrates. ACS Appl Polym Mater. 2018; 6:1234-1243. https://doi.org/10.1021/ acsapm. 8b00106.
  47. Neves LB, Afonso S, Nóbrega G, Barbosa LG, Lima RA. Methods to modify PDMS surface wettability and applications: a review. Micromachines. 2024; 15:670. https://doi.org/10.3390/mi15060670.
  48. Nugroho A, Kozin M, Mamat R, Bo Z, Fairusham M, Prisla M, et al. Nanoparticle-enriched palm oil biolubricants for enhanced tribological performance. Heliyon. 2024;10(22):e39742. https://doi.org/10.1016/j. heliyon.2024.e39742.
  49. Goff J, Sulaiman S, Arkles B. Applications of hybrid polymers generated from living anionic ring-opening polymerization. Molecules. 2021; 26:2755. https://doi. org/10.3390/molecules26092755.
  50. Hubbe MA, Szelez S, Venditti RA. Detergency mechanisms and interactions with cellulosic surfaces: a review. BioResources. 2015; 10:7167-7249. https://doi. org/10.15376/biores.17.4.Hubbe.
  51. Huang J, Yang M, Wan L, Tang K, Zhang H, Chen J, et al. Ultrafine powder coatings with dense structures and enhanced corrosion resistance. Chem Eng J. 2023; 455:140815. https://doi.org/10.1016/j.cej.2022.140815.
  52. Eduok U. Effect of silylating agents on super-hydrophobic and self-cleaning properties of siloxane/ cellulosic fabric filters. RSC Adv. 2021;11: 9586-9599. https://doi.org/10.1039/D0RA10565A.
  53. Si C, Cai M, Liu G, Zhang Y, Fan X, Zhu M. PDMS–PI composite coatings for multipurpose tribological applications. Tribol Int. 2023; 189:108919. https://doi. org/10.1016/j.triboint.2023.108919.
  54. Lee S, Segu DZ, Kim C. Enhancement of tribological performance of lubricants using polydimethylsiloxane powder additives. RSC Adv. 2024;14:31047-31056. https://doi.org/10.1039/D4RA05164E.
Progress in Color, Colorants and Coatings
Volume 19, Issue 4 - Serial Number 63
October 2026
Pages 417-434

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