Statistical Analysis of Levelness Parameter of CTAC Modified Cotton Knit Dyed with Fluorescent Pigment in Pad Batch Method

Document Type : Original Article

Authors

1 Department of Wet Process Engineering, Bangladesh University of Textiles (BUTEX), Tejgaon, Dahka-1208, Bangladesh

2 Department of Environmental Science & Engineering, Bangladesh University of Textiles (BUTEX), Tejgaon, Dahka-1208, Bangladesh

Abstract

Dispersion stability and application method of fluorescent pigment have a great influence on the level dyeing of cotton fabric. Focusing on this, cotton knit fabric is cationized with Cetyl Trimethyl Ammonium Chloride (CTAC), and then dyed with fluorescent pigment in the pad batch method. Here, cationization was performed so that fluorescent pigment can be entrapped on it, which reduces their migration, thus providing dispersion stability to provide level dyeing. The effect of varying pretreatment conditions was investigated, and optimum conditions for cationization and pigmentation were established in terms of statistical parameters of K/S value, like standard deviation (S), relative standard deviation (Sr), levelness (L), and unlevelness (U) parameters to obtain an accurate numerical value of levelness of cellulose fabric dyed with fluorescent pigment. The results display at pH 9 and 54 g/L CTAC concentration, providing higher CTAC adsorption. Besides, FTIR spectrophotometry analysis of scoured, bleached, and CTAC adsorbed fabric is carried out to reveal adsorption chemistry. Furthermore, for characterization of samples, color fastness to water, wash, perspiration (acidic and alkaline), and rubbing (wet and dry) are performed. Although tensile strength has increased, a slight reduction in bursting strength and softness of the dyed fabric is observed. However, the main novelty of this research is the utilization of the cationizer named CTAC that is padded before fluorescent pigment applications. The outcomes of the statistical analysis of the levelness parameter also suggest that the greater efficacy of CTAC for level dyeing of fluorescent pigmented fabric can be used in fashion as well as functional purposes.

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Main Subjects


  1. Bianchi DD, Martins AC. Fluorescent pigments and their diverse applications. In Paintistanbul–Turkcoat, 6th International Paint, Paint Raw Materials, Construction Chemicals, Adhesives and Raw Materials Congress, 2016 Istanbul 2016; 151-154.
  2. Yu LP, Zhang X, Wei DX, Wu Q, Jiang XR, Chen GQ. Highly efficient fluorescent material based on rare-earth-modified polyhydroxyalkanoates. Bio-macromolecules. 2019;20(9): 3233-41. https://doi.org/ 10.1021/acs.    
  3. Algamdy H. A promising perspective to upgrade cotton dyeing performances when dyed with a red fluorescent pigment. Ind Textila. 2024; 75(4): 389-95. https://doi.org/10.35530/IT.075.04.202398.
  4. Slama N, Ben Ticha M, Smiri B, Dhaouadi H. Exploration of the fluorescence property of acrylic fibers dyed with the residues extract of juglans regia barks. Sustainability. 2022;14(19):12275. https://doi. org/10.3390/su14.
  5. Wang H, Sun J. Wool fabrics colored with fluorescent pigment emulsion: their color performance and fluorescent properties. J Nat Fibers. 2022;19(3): 1069-83. https://doi.org/10.1080/15440478.2020. 788685.
  6. Hossain MD, Rashid MA, Kafi MA, Sarker F. Investigation on physical properties of fluorescent dyed cotton knit fabric. Chem Mater Eng. 2014; 2(5): 101-5. https://doi.org/10.13189/cme.2014.020501.
  7. Santos G, Marques R, Silva S, Oliveira J, Castro P, Pereira C, Pinheiro M. Innovative high-visibility protective clothing development. Textiles. 2021; 1(3): 405-18. https://doi.org/10.3390/textiles1030021.
  8. Subaihi A, Al-Qahtani SD, Attar RM, Alkhamis K, Alzahrani HK, Alhasani M, El-Metwaly NM. Preparation of fluorescent cotton fibers with anti-microbial activity using lanthanide-doped pigments. Cellulose. 2022;29(11):6393-404. https://doi.org/10. 1007/s10570-022-04665-9.
  9. Li M, Zhang L, Peng H, Fu S. Preparation of fluorescent pigment latex and its application on binder‐free printing of cotton fabrics. J Appl Polym Sci. 2018;135(6):45826. https://doi.org/10.1002/ app. 45826.
  10. Choudhury AR. Coloration of cationized cellulosic fibers–a review. AATCC J Res. 2014; 1(3): 11-9. https://doi.org/10.14504/ajr.1.3.2.
  11. Sheng JZ, Chi CL, Li WL, Zhang YP, Cao JL. Fluorescent pigment dyeing of cotton knits. Dye Finish. 2015; 2015(19): 6.
  12. Mahbub MA, Mahmud MH, Ahona MJ, Ahmed T, Ashraf SM, Sultana JA, Hasan M, Islam MT. Chitosan as a cationizing agent in pigment dyeing of cotton fabric. Carbohydr Polym Technol Appl. 2024; 7: 100502. https://doi.org/10.1016/j.carpta.2024.100502
  13. Fang K, Wang C, Zhang X, Xu Y. Dyeing of cationised cotton using nanoscale pigment dispersions. Color Technol. 2005; 121(6):325-8. https://doi.org/ 10.1111/j.1478-4408.2005.tb00377.x
  14. Fang K, Zhang L, Xu Y, Zhang X. Pigment dyeing of polyamide‐epichlorohydrin cationized cotton fabrics. J Appl Polym Sci. 2010; 118(5): 2736-42. https://doi. org/10.1002/app.32665.
  15. Islam MK, Kabir SM, Hosen MD, Islam MA. Fastness properties improvement of fluorescent pigments. Fibres Text. 2022; 29:45-53. https://doi.org/ 10.15240/tul/008/2022-2-005.
  16. Kumar M, Chinta SK, Kumar D. Adsorption and thermodynamic study of pigment dyeing on cationised cotton. Int J Fiber Text Res. 2013; 3(1): 6-12. 
  17. Li M, Zhang L, Qiu M, Zhang Y, Fu S. Dyeing property of fluorescent pigment latex on cationic knitted cotton fabrics. Text Res J. 2019; 89(3): 422-33. https://doi.org/10.1177/0040517517748494.
  18. Tang AY, Wang YM, Lee CH, Kan CW. Computer color matching and levelness of PEG-based reverse micellar decamethyl cyclopentasiloxane (D5) solvent-assisted reactive dyeing on cotton fiber. Appl Sci. 2017; 7(7): 682. https://doi.org/10.3390/app7070682.
  19. Ibrahim SF, Essa DM, Osman EM. Statistical method for determining the levelness parameters of different coloured polymeric fabrics. Int J Chem. 2011; 3(3): 11. https://doi.org/:10.5539/ijc.v3n3p11.
  20. Osman EM, El-Ebissy AA, Michael MN. Charac-terization and evaluation of the levelness parameters of natural dyes on natural fabrics. Res J Text Apparel. 2009; 13(2): 61-8. https://doi.org/10. 1108/RJTA-13-02-2009-B007.
  21. Ali S, Mughal MA, Shoukat U, Baloch MA, Kim SH. Cationic starch (Q-TAC) pre-treatment of cotton fabric: influence on dyeing with reactive dye. Carbohy Polym. 2015;117: 271-8. https://doi.org/10.1016/j. carbpol.20 14.09.064.
  22. Tania IS, Ali M, Azam MS. Mussel-inspired deposition of Ag nanoparticles on dopamine-modified cotton fabric and analysis of its functional, mechanical, and dyeing properties. J Inorg Organometal Polym Mater. 2021; 31(10): 4065-76. https://doi.org/10.1007/s10904-021-02034-w.
  23. Das D, Bakshi S, Bhattacharya P. Dyeing of EDTA-modified cotton with reactive dyes. Clothing Text Res J. 2016;34(3):196-206. https://doi.org/10.1177/0887 302 X16652998.
  24. Marković-Nikolić DZ, Bojić A, Petković G, Ristić N, Cakić M, Nikolić GS. The preparation and utilization of the cationic sorbent based on the surfactant modified bottle gourd shell. Adv Technol. 2017; 6(2): 38-50. https://doi.org/10.5937/savteh1702038M.
  25. Baghdadi M, Mazarji M, Sabouhi M, Kang AJ, Jafari A. Removal of cationic surfactants from aqueous solutions by modified cotton as a novel high capacity and low-cost adsorbent. J Adv Chem. 2014; 9(3).
  26. Negi A. Cationized cellulose materials: enhancing surface adsorption properties towards synthetic and natural dyes. Polymers. 2024; 17(1): 36. https://doi. org/10.3390/polym17010036.
  27. Fang K, Jiang X, Wang C, Wu M, Yan Y. Properties of the nanoscale hydrophilic cationic pigment based on quaternary surfactant. J dispers sci technol. 2008; 29(1):52-7. https://doi.org/10.1080/019326907016868 58.
  28. Zhang ZQ, Wu Y. Dyeing of blended fabric with pigment. AMM. 2013; 376: 30-3. https://doi.org/10. 4028/ww w.scientific.net/AMM.376.30.
  29. Haggag K, El-Molla MM, Shake NO, Alian NA, El-Shall FN. Use of the novel synthesized aqueous binders for pigment printing cotton fabrics using three modes of fixation. Int J Text Sci. 2012; 1(6): 49-6. https://doi.org/10.5923/j.textile.20120106.01.
  30. Ibrahim W, Sarwar Z, Khan A, Hassan A, Azeem A, Nazir A, Jamshaid H, Hussain U. A novel study of comparison properties of pigment and reactive dye-printed cotton fabric. J Nat Fibers. 2019. https://doi.org/10.1 080/15440478.2018.1440364.