Study of the Kinetics, Thermodynamics, and Adsorption Isotherm of Diamine Green B Dye Using the Biocatalyst Laccase@Fe-BTC

Document Type : Original Article

Authors

1 Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, P.O. Box: 1138, Urmia, Iran

2 Department of Civil Engineering, Faculty of Engineering, Qom university of Technology, P.O. Box: 1519-37195, Qom, Iran

3 Department of Chemical, Materials & Polymer Engineering, Buein Zahra Technical University. P.O. Box: 3451745346, Buein zahra, Qazvin

Abstract

In this study, the isotherm, kinetic, and thermodynamic properties of diamine green B dye adsorption were investigated using enzymatic metal–organic frameworks. First- and second-order kinetic models, along with the Elovich kinetic model, as well as Langmuir and Freundlich isotherm models, were applied to evaluate the data. Based on previous studies, the dye adsorption efficiency of this material was assessed by examining the effects of contact 
time, adsorbent dosage, and initial dye concentration. The optimal adsorption conditions for this nano-adsorbent were determined to be a contact time of 45 min and an adsorbent dosage of 5 g/L. The calculated thermodynamic parameters (ΔG, ΔH, and ΔS) indicate that the adsorption of the dye onto the enzymatic organometallic adsorbent is spontaneous, endothermic, and associated with an increase in randomness. The process followed the Elovich kinetic model. Among the tested isotherm models, the Freundlich isotherm provided the best fit to the experimental data.

Keywords

Main Subjects

References

  1. Alizadeh R, Tahmasebi F. Metal Organic Framework Nanocomposite Adsorbents with Enzyme Function to Remove Direct Green 6 Dye Pollution. J Stud Colorworld. 2024;14(1):45-55. https://dor.isc.ac/dor/20. 1001.1.22517278.1402.14.1.4.9.
  2. Mane VS, Mall ID, Srivastava VC. Use of bagasse fly ash as an adsorbent for the removal of brilliant. Dyes Pigm. 2007;73(3):269-78.https://doi.org/1016/j. dyepig. 2005.12.006.
  3. Donia AM, Atia AA, Al-amrani WA, El-Nahas AM. Effect of structural properties of acid dyes on their adsorption behaviour from aqueous solutions by amine modified silica. J Hazard Mater. 2019; 161(2):1544-1550. https://doi.org/10.1016/j.jhazmat. 2008.05.042.
  4. Asouhidou D, Triantafyllidis KS, Lazaridis NK, Matis KA. Adsorption of remazol red 3bs from aqueous solutions using APTES- and cyclodextrin-modified HMS-type mesoporous silicas. Colloids Surf A Physicochem Eng Asp. 2009;346(1):83-90. https://doi. org/10 .1016/j.colsurfa.2009.05.029.
  5. Taguchi A, Schüth F. Ordered mesoporous materials in catalysis. Micropor Mesopor Mater. 2014;77(1):1-45. https://doi.org/10.1016/j.micromeso. 2004.06.030.
  6. Xiao X, Zhang F, Feng Z, Deng S, Wang Y. Adsorptive removal and kinetics of methylene blue from aqueous solution using NiO/MCM-41 composite. Physica E Low Dimens Syst Nanostruct. 2015;6(5):4-12. https://doi. org/10.1016 /j.physe. 2014. 08.006.
  7. Michniewicz A, Ledakowicz S, Ullrich R, Hofrichter M. Kinetics of the enzymatic decolorization of textile dyes by laccase from Cerrena unicolor. Dyes Pigm. 2008;77 (2): 295-302. https://doi.org/10.1016/j.dyepig.2007.05. 015.
  8. Sanchez M, de Asua I, Ruano D, Diaz K. Direct synthesis, structural features, and enhanced catalytic activity of the Basolite F300-like semi amorphous Fe-BTC framework. Cryst Growth Des. 2015;15:4498. https://doi.org/10.1021/ /acs.cgd.5b00755.
  9. Castañeda Ramírez AA, Garcia Rojas E, Medina RL, Contreras Larios JL, Suárez Parra R, Maubert Franco AM. Selective adsorption of aqueous diclofenac sodium, naproxen sodium, and ibuprofen using a stable Fe3O4–FeBTC metal–organic framework. Materials. 2021; 14:2293. https://doi.org/10.3390/ma 14092293.
  10. Hou H, Zhou R, Wu P, Wu L. Removal of Congo red dye from aqueous solution with hydroxyapatite/ chitosan composite. Chem Eng J. 2012;211:336-342. https://doi. org/10.1016/j.cej .2012.09.100.
  11. Greluk M, Hubicki Z. Efficient removal of Acid Orange 7 dye from water using the strongly basic anion exchange resin Amberlite IRA-958. Desalination. 2011; 278(1):219-226. https://doi.org/10.1016/j.desal.2011. 05. 024.
  12. Shahbazi A, Younesi H, Badiei A. Synthesis of organic-inorganic hybrid amine based on nano-structured silicate materials and its application for removal of heavy metal ions from aqueous solution. Water Wastewater. 2013;23(84):13-21.
  13. Greluk M, Hubicki Z. Kinetics, isotherm and thermodynamic studies of reactive black 5 removal by acid acrylic resins. Chem Eng J. 2010;162(3):919-26. https://doi.org/10.1016/j.cej.2010.06.043.
  14. Moussavi SP, Emamjomeh MM, Ehrampoush MH, Behvari M, Jamshidi S. Removal of Acid Orange 7 dye from synthetic textile wastewater by single-walled carbon nanotubes: adsorption studies, isotherms and kinetics. J Rafsanjan Univ Med Sci. 2013;12(11):907-18. Dor:20.1001.1.17353165.1392.12.11.4.8.
  15. Paul M, Pal N, Bhaumik A. Selective adsorption and release of cationic organic dye molecules on meso-porous borosilicates. Mater Sci Eng C. 2012;32 (6): 1461-8.https://doi.org/10.1016/j.msec.2012.04.026.
  16. Bao C, Qu J, Zhou X, Xiang X, Zheng C, Zhang H, Zhou X. Adsorption behavior of Azo Dye CI Acid Red 14 in aqueous solution on surface soils. J Environ Sci. 2018; 20(6):704-9. https://doi.org/10.1016/S1001-0742 (08) 62116-6.
  17. Chen Z, Zhou L, Zhang F, Yu C, Wei Z. Multi-carboxylic hyperbranched polyglycerol modified SBA-15 for the adsorption of cationic dyes and copper ions from aqueous media. Appl Surf Sci. 2012; 258 (13): 5291-8. https://doi.org/ 10.1016/j.apsusc.2012. 02.021.
  18. Chen Z, Zhou L, Zhang F, Yu C, Wei Z. Multi carboxylic hyper branche polyglycerol modified SBA-15 for the adsorption of cationic dyes and copper ions from aqueous media. Appl Surf Sci. 2012;258 (13): 5291-8. https://doi.org /10.1016/j.apsusc.2012.02.021.
  19. Sheshmani S, Ashori A, Hasanzadeh S. Removal of Acid Orange 7 from aqueous solution using magnetic graphene/chitosan: a promising nano-adsorbent. Int J Biol Macromol. 2014;68:218-24. https://doi.org/ 10. 1016/ j.ijbiomac.2014.04.057
  20. Daneshvar N, Rasoulifard MH, Khataee AR, Hosseinzadeh F. Removal of CI Acid Orange 7 from aqueous solution by UV irradiation in the presence of ZnO nanopowder. J Hazard Mater. 2007;143(1-2):95-101. https://doi.org/ /10.1016/j.jhazmat.2006.08.072
  21. Yanjing Y, Bai Y, Fengqi Z, Erbang Y, Jianhua Y, Chunlei X, et al. Effects of metal organic framework Fe-BTC on the thermal decomposition of ammonium perchlorate. RSC Adv. 2016;6(71):67308-14. https:// doi.org/ 10.1039/C6RA12634K.
  22. Hosseine Z, Amirhandeh S, Salem A, Salem Sh. Adsorption of chromium iii species from colorant tannery wastewater by silica nano-particles. J Stud Color World. 2023;13(3):237-52. https://dor1.net/dor/20.1001. 1.22517278.1402.13.3.1.7 [In Persian]
  23. Navai Diva T. Various adsorbents for removal of rhodamine B dye: A review. J Stud Color World. 2023;12(4):387-404. https://dor1.net/dor/20.1001.1.22 517278.1401.12.4.6.7 [In Persian].
  24. Tabaraki R, Sadeghinejad N, Poorajam H. Study of dyes removal from binary system by hazelnut husk as agricultural waste by Response surface methodology. J Stud Color World. 2020;14:13-23. https://dor1.net/ dor/ 20.1001.1.17358779. 1399.14.1.2.0 [In Persian]
  25. Haque FZ, Nandanwar R, Singh P. Optik. 2016; 128:191.https://doi.org/10.1016/j.ijleo.2016.10.025.
  26. Ren S, et al. Recent progress and future prospects of laccase immobilization on MOF supports for industrial applications. Appl Biochem Biotechnol. 2023;196(3):1-16. https://doi.org/10.1007/s12010-023- 0467-6.
  27. Feng Y, et al. Recent advances in enzyme immo-bilization based on novel porous framework materials and its applications in biosensing. Coord Chem Rev. 2022;459:214414. https://doi.org/10.1016/j.ccr.2022. 214414.
  28. Férey G, Mellot-Draznieks C, Serre C, Millange F. Crystallized frameworks with giant pores: Are there limits to the possible? Acc Chem Res. 2005; 38(4):217-25. https://doi.org/10 .1021/ar040163i.
  29. Zhu L, Liu XQ, Jiang HL, Sun LB. Metal–organic frameworks for heterogeneous basic catalysis. Chem Rev.2017;117(12):8129-8176. https://doi.org/10.1021/ acs.chemrev.7b00091.
Progress in Color, Colorants and Coatings
Volume 19, Issue 4 - Serial Number 63
October 2026
Pages 507-517

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