Gravimetric and Density Functional Theory Investigations on 4-Amioantipyrin Schiff Base as an Inhibitor for Mild Steel in HCl Solution

Document Type : Original Article

Authors

1 Ashur University College, P.O. Box: 10001, Baghdad, Iraq

2 Production and Metallurgy Engineering Department, University of Technology, P.O. Box: 10001, Baghdad, Iraq

3 Department of Medical Instruments Engineering Techniques, Al-Farahidi University, P.O. Box: 10001, Baghdad, Iraq

4 Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Univerversiti Kebangsaan Malaysia, P.O. Box: 43600 UKM Bangi, Selangor, Malaysia

5 Energy and Renewable Energies Technology Center, University of Technology-Iraq, P.O. Box: 10001, Baghdad, Iraq

Abstract

Metal corrosion, in general, is a serious economic problem. One of the most effective ways to prevent corrosion on metal surfaces is to use corrosion inhibitors, especially green organics. Here, the effects of concentration, exposure time, and temperature on the antiproliferative ability of 4-aminoantipyrine derivative were investigated. The 4-aminoantipyrine derivative showed significant corrosion resistance to mild steel melting in a 1M hydrochloric acid environment, as observed from the weight loss method. At 303 K and a dose of 500 ppm, the maximum inhibitory efficacy of the 4-aminoantipyrine derivative was 96.1 %. Corrosion test results showed that the 4-aminoantipyrine derivative has an inhibitory effect of more than 88 % at the concentration of 400 ppm and inhibits corrosion through an adsorption mechanism. The inhibitory potency of the 4-aminoantipyrine derivative changed inversely with a long exposure time, while temperature affected it directly. The Langmuir model was used to control the physical and chemical adsorption of its 4-aminoantipyrine derivative as a corrosion inhibitor on metallic surfaces. Data from density functional theory simulations help bridge the gap between theoretical studies and experimental approaches. 

Keywords

Main Subjects

References

  1. G. E. Badr, The role of some thiosemicarbazide derivatives as corrosion inhibitors for C-steel in acidic media, Corros. Sci., 51(2009), 2529-2536. 
  2. M. Goyal, S. Kumar, I. Bahadur, C. Verma, E. Ebenso, Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review, J. Mol. Liq., 256(2018), 565-573.
  3. S. Ghareba, S. Omanovic, Interaction of 12-aminododecanoic acid with a carbon steel surface: towards the development of 'green' corrosion inhibitors, Corros. Sci., 52(2010), 2104-2113. 
  4. A. Yıldırım, M. Cetin, Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion inhibitors, Corros. Sci., 50(2008), 155-165.
  5. S. K. Saha, A. Dutta, P. Ghosh, D. Sukul, P. Banerjee, P. Novel Schiff-base molecules as efficient corrosion inhibitors for mild steel surface in 1 M HCl medium: experimental and theoretical approach, Phys. Chem. Chem. Phys., 18(2016), 17898-17911.
  6. X. Li, S. Deng, H. Fu, Three pyrazine derivatives as corrosion inhibitors for steel in 1.0 M H2SO4 solution, Corros. Sci., 53(2011), 3241-3247.
  7. M. Karelson, V. Lobanov, A. Katritzky Quantum-chemical descriptors in QSAR/QSPR studies, Chem. Rev., 96(1996), 1027-1044.
  8. J. Kumaran, S. Priya, J. Gowsika, N. Jayachandramani, S. Mahalakshmi, Synthesis, spectroscopic characterization, in silico DNA studies and antibacterial activites of Copper(II) and Zinc(II) complexes derived from thiazole based pyrazolone derivatives, Res. J. Pharm. Biol. Chem. Sci., 4(2013), 279-288.
  9. A.S.T.M. Standard, Standard practice for preparing, cleaning, and evaluating corrosion test specimens, American Society for Testing and Materials G1-03, (2011).
  10. Gaussian 09, Revision D.01, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, Ö. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, and D. J. Fox, Gaussian, Inc., Wallingford CT, (2009).
  11. T. Koopmans, Ordering of wave functions and eigenenergies to the individual electrons of an atom, Physica, 1(1933), 104-113.
  12. L. Larabi, Y. Harek, O. Benali, S. Ghalem, Hydrazide derivatives as corrosion inhibitors for mild steel in 1 M HCl, Prog. Org. Coat., 54(2005), 256-263.
  13. Lukovits, E. Kálmán, F. Zucchi, Corrosion inhibitors-correlation between electronic structure and efficiency, Corrosion, 57(2001), 3-12.
  14. A. Zarrouk, A. Dafali, B. Hammouti, H. Zarrok, S. Boukhris, M. Zertoubi, Synthesis, characterization and comparative study of functionalized quinoxaline derivatives towards corrosion of copper in nitric acid medium, Int. J. Electrochem. Sci., 5(2010), 46-53.
  15. A. Fiala, A. Chibani, A. Darchen, A. Boulkamh, K. Djebbar, Investigations of the inhibition of copper corrosion in nitric acid solutions by ketene dithioacetal derivatives, Appl. Surf. Sci., 253(2007), 9347.
  16. M. M. El-Naggar, Bis-aminoazoles corrosion inhibitors for copper in 40 M HNO3 solutions, Corros. Sci., 42(2000), 773.
  17. Lukovits, E. Kálmán, F. Zucchi, Corrosion inhibitors-correlation between electronic structure and efficiency, Corrosion, 57(2001), 11-23.
  18. O. Kikuchi, Systematic QSAR procedures with quantum chemical descriptors, Quant. Struct.-Act. Relat., 6(1987), 179.
  19. K. Al-Azawi, S. Al-Baghdadi, A. Mohamed, A. Al-Amiery, T. Abed, S. Mohammed, A. Kadhum, A. Mohamad, Synthesis, inhibition effects and quantum chemical studies of a novel coumarin derivative on the corrosion of mild steel in a hydrochloric acid solution, Chem. Central J., 10(2016), 1-9.
  20. A. Al-Amiery, A. Mohamad, A. Kadhum, l. Shaker, W. Isahak, M. Takriff, Experimental and theoretical study on the corrosion inhibition of mild steel by nonanedioic acid derivative in hydrochloric acid solution, Sci. Rep., 12(2022), 1-21.
  21. F. Ramadhani, E. Emriadi, S. Syukri, Theoretical study of xanthone derivative corrosion inhibitors using density functional theory (DFT), J. Kimia Valensi, 6(2020), 96-105.
  22. A. Singh, M. Quraishi, Effect of cefazolin on the corrosion of mild steel in HCl solution, Corros. Sci., 52(2010), 152-160.
  23. M. Ameer E. Khamis G. Al-Senani, Adsorption studies of the effect of thiosemicarbazides on the corrosion of steel in phosphoric acid, Adsorpt. Sci. Technol., 8(2000), 177-194. 
  24. A. Yaro A. Khadom, R. Wael, Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid, Alexandria Eng. J., 52(2013), 129-135. 
  25. B. Meroufel O. Benali M. Benyahia Y. Benmoussa M. Zenasni, Adsorptive removal of anionic dye from aqueous solutions by algerian kaolin: characteristics, isotherm, kinetic and thermodynamic studies, J. Mater. Environ. Sci., 3(2013), 482-491. 
  26. I. Ahamad, R. Prasad, M. Quraishi, Inhibition of mild steel corrosion in acid solution by Pheniramine drug: Experimental and theoretical study, Corr. Sci., 52(2010), 3033-3041.
  27. N. Kıcır, G. Tansuğ, M. Erbil, T. Tüken. Investigation of ammonium (2, 4-dimethylphenyl)-dithiocarbamate as a new, effective corrosion inhibitor for mild steel, Corr. Sci., 105(2016), 88-99.
  28. W. Li, Q. He, S. Zhang, C. Pei, B. Hou, Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium, J. Appl. Electrochem., 38(2008), 289-295. 
  29. S. Zhang, Z. Tao, S. Liao, F. Wu, Substitutional adsorption isotherms and corrosion inhibitive properties of some oxadiazol-triazole derivative in acidic solution, Corr. Sci., 52(2010), 3126-3132.
  30. A. Alamiery, Study of corrosion behavior of N'-(2-(2-oxomethylpyrrol-1-yl) ethyl) piperidine for mild steel in the acid environment, Biointerface Res. Appl. Chem., 12(2022), 3638-3646.
  31. A. Alamiery, A. Mohamad, A. Kadhum, S. Takriff, Comparative data on corrosion protection of mild steel in HCl using two new thiazoles, Data in Brief, 40(2022), 107838.
  32. A. M. Mustafa, F.F. Sayyid, N. Betti, L.M. shaker, M. M. Hanoon, A.A. Alamiery, A.A.H. Kadhum, M.S. Takriff, Inhibition of mild steel corrosion in hydrochloric acid environment by 1-amino-2-mercapto-5-(4-(pyrrol-1-yl)phenyl)-1,3,4-triazole, South African J. Chem. Eng., 39(2022), 42-51.
  33. A. Alamiery, Investigations on corrosion inhibitory effect of newly quinoline derivative on mild steel in HCl solution complemented with antibacterial studies, Biointerface Res. Appl. Chem., 12(2022), 1561-1568.
  34. A. Aziz, I.A. Annon, M. Abdulkareem, M. Hanoon, M. Alkaabi, L. Shaker, A. Alamiery, W. Wan Isahak, M. Takriff, Insights into corrosion inhibition behavior of a 5-Mercapto-1, 2, 4-triazole derivative for mild steel in hydrochloric acid solution: experimental and DFT studies, Lubricants, 9(2021), 122.
  35. A. Alamiery, W. Isahak, M. Takriff, Inhibition of mild steel corrosion by 4-benzyl-1-(4-oxo-4-phenylbutanoyl)thiosemicarbazide: gravimetrical, adsorption and theoretical studies, Lubricants, 9(2021), 93.
  36. M.A. Dawood, Z.M.K. Alasady, M.S. Abdulazeez, D.S. Ahmed, G.M. Sulaiman, A.A.H. Kadhum, L.M. Shaker and A.A. Alamiery, The corrosion inhibition effect of a pyridine derivative for low carbon steel in 1 M HCl medium: Complemented with antibacterial studies, Int. J. Corros. Scale Inhib., 10(2021), 1766-1782. 
  37. A. Alamiery, Corrosion inhibition effect of 2-N-phenylamino-5-(3-phenyl-3-oxo-1-propyl)-1,3,4-oxadiazole on mild steel in 1 M hydrochloric acid medium: Insight from gravimetric and DFT investigations, Mater. Sci. Energy Technol., 4(2021), 398-406.
  38. A. Alamiery, Short report of mild steel corrosion in 0.5 M H2SO4 by 4-ethyl-1-(4-oxo-4-phenylbutanoyl) thiosemicarbazide, J. Tribologi, 30(2021), 90-99.
  39. A. Alamiery, Anticorrosion effect of thiosemicarbazide derivative on mild steel in 1 M hydrochloric acid and 0.5 M sulfuric Acid: Gravimetrical and theoretical studies, Mater. Sci. Energy Technol., 4(2021), 263-273.
  40. A. Alamiery, W., Isahak, H. Aljibori, H. Al-Asadi, A. Kadhum, Effect of the structure, immersion time and temperature on the corrosion inhibition of 4-pyrrol-1-yl-n-(2,5-dimethyl-pyrrol-1-yl)benzoylamine in 1.0 m HCl solution, Int. J. Corros. Scale Inhib.,10(2021), 700-713. 
  41. A. Alamiery, E. Mahmoudi and T. Allami, Corrosion inhibition of low-carbon steel in hydrochloric acid environment using a Schiff base derived from pyrrole: gravimetric and computational studies, Int. J. Corros. Scale Inhib., 10(2021), 749-765. 
  42. A.J.M. Eltmimi, A. Alamiery, A.J. Allami, R.M. Yusop, A.H. Kadhum, T. Allami, Inhibitive effects of a novel efficient Schiff base on mild steel in hydrochloric acid environment, Int. J. Corros. Scale Inhib.,10(2021),634-648. 
  43. A. Alamiery, L. Shaker, A. Allami, A. Kadhum, M. Takriff, A study of acidic corrosion behavior of Furan-Derived schiff base for mild steel in hydrochloric acid environment: Experimental, and surface investigation, Mate. Today: Proceedings, 44(2021), 2337-2341.
  44. S. Al-Baghdadi, A. Al-Amiery, T. Gaaz, A. Kadhum, Terephthalohydrazide and isophthalo-hydrazide as new corrosion inhibitors for mild steel in hydrochloric acid: Experimental and theoretical approaches, Koroze Ochrana Materialu, 65(2021), 12-22.
  45. M. Hanoon, A. Resen, L. Shaker, A. Kadhum, A. Al-Amiery, Corrosion investigation of mild steel in aqueous hydrochloric acid environment using n-(Naphthalen-1yl)-1-(4-pyridinyl)methanimine complemented with antibacterial studies, Biointerface Res. Appl. Chem., 11(2021), 9735-9743.
  46. S. Al-Baghdadi, T. Gaaz, A. Al-Adili, A. Al-Amiery, M. Takriff, Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation, Intern. J. Low-Carbon Technol., 16(2021), 181-188.
  47. A. Al-Amiery, Anti-corrosion performance of 2-isonicotinoyl-n-phenylhydrazinecarbothioamide for mild steel hydrochloric acid solution: Insights from experimental measurements and quantum chemical calculations, Surface Rev. Letters, 28(2021), 2050058.
  48. M.S. Abdulazeez, Z.S. Abdullahe, M.A. Dawood, Z.K. Handel, R.I. Mahmood, S. Osamah, A.H. Kadhum, L.M. Shaker, A.A. Al-Amiery, Corrosion inhibition of low carbon steel in HCl medium using a thiadiazole derivative: weight loss, DFT studies and antibacterial studies, Int. J. Corros. Scale Inhib., 10(2021), 1812-1828. 
  49. A. Mustafa, F. Sayyid, N. Betti, M. Hanoon, A. Al-Amiery, A. Kadhum, M. Takriff, Inhibition evaluation of 5-(4-(1H-pyrrol-1-yl)phenyl)-2-mercapto-1,3,4-oxadiazole for the corrosion of mild steel in an acidic environment: thermodynamic and DFT aspects, Tribologia-Finnish J. Tribol., 38(2021), 39-47. 
  50. Y.M. Abdulsahib, A.J.M. Eltmimi, S.A. Alhabeeb, M.M. Hanoon, A.A. Al-Amiery, T. Allami, A.A.H. Kadhum, Experimental and theoretical investigations on the inhibition efficiency of N-(2,4-dihydroxytolueneylidene)-4-methylpyridin-2-amine for the corrosion of mild steel in hydrochloric acid, Int. J. Corros. Scale Inhib., 10(2021), 885-899. 
  51. A. Khudhair, A. Mustafa, M. Hanoon, A. Al-Amiery, L. Shaker, T. Gazz, A. Mohamad, A. Kadhum, M. Takriff, Experimental and theoretical investigation on the corrosion inhibitor potential of N-MEH for mild steel in HCl, Prog. Color Colorants Coat., 15(2021), 111-122. 
  52. D. Zinad, R. Salim, N. Betti, L. Shaker, A. AL-Amiery, Comparative investigations of the corrosion inhibition efficiency of a 1-phenyl-2-(1-phenylethylidene)hydrazine and its analog against mild steel corrosion in hydrochloric acid solution, Prog. Color Colorants Coat., 15(2021), 53-63
  53. R. Salim, N. Betti, M. Hanoon, A., Al-Amiery, 2-(2,4-Dimethoxybenzylidene)-N-phenylhydrazinecarbothioamide as an efficient corrosion inhibitor for mild steel in acidic environment, Prog. Color Colorants Coat., 15(2021), 45-52.
  54. A. Al-Amiery, L. Shaker, A.M. Takriff, Exploration of furan derivative for application as corrosion inhibitor for mild steel in hydrochloric acid solution: Effect of immersion time and temperature on efficiency, Mater. Today: Proc.,42(2021), 2968-2973.
  55. A.M. Resen, M.M. Hanoon, W.K. Alani, A. Kadhim, A.A. Mohammed, T.S. Gaaz4, A.A.H. Kadhum, A.A. Al-Amiery, M.S. Takriff, Exploration of 8-piperazine-1-ylmethylumbelliferone for application as a corrosion inhibitor for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib., 10(2021), 368-387. 
  56. M. Hanoon, A., Resen, A. Al-Amiery, A. Kadhum, T. Takriff, Theoretical and experimental studies on the corrosion inhibition potentials of 2-((6-Methyl-2-ketoquinolin-3-yl)Methylene) hydrazinecarbothioamide for mild steel in 1 M HCl, Prog. Color Colorants Coat., 15(2021), 21-33.
  57. F. Hashim, T. Salman, S. Al-Baghdadi, T. Gaaz, A. Al-Amiery, Inhibition effect of hydrazine-derived coumarin on a mild steel surface in hydrochloric acid, Tribologia, , 37(2020), 45–53
  58. A.M. Resen, M. Hanoon, R.D. Salim, A.A. Al-Amiery, L.M. Shaker, A.A.H. Kadhum, Gravimetrical, theoretical, and surface morphological investigations of corrosion inhibition effect of 4-(benzoimidazole-2-yl) pyridine on mild steel in hydrochloric acid, Koroze Ochrana Materialu, 64(2020), 122-130.
  59. A. Salman, Q. Jawad, K. Ridah, L. Shaker, A. Al-Amiery, Selected BIS-Thiadiazole: synthesis and corrosion inhibition studies on mild steel in HCl environment, Surf. Rev. Lett., 27(2020), 2050014
Progress in Color, Colorants and Coatings
Volume 16, Issue 3
July 2023
Pages 255-269

Files

Share

How to cite

Statistics