A Kinetic and Thermodynamic Study of CI Fluorescent Brightener 113 on Cotton

Document Type : Original Article

Authors

1 Department of Chemical Engineering, Rajamangala University of Technology Krungthep, P.O. Box: 10120, Bangkok, Thailand

2 Department of Textile Chemistry, Rajamangala University of Technology Phra Nakhon, P.O. Box: 10300, Bangkok, Thailand

3 Department of Research and development, Worldtext Commercial Co., Ltd., P.O.Box: 10160, Bangkok, Thailand

Abstract

Fluorescent brightening agents are dyestuffs in which adsorption is the primary mechanism involved in the dyeing process. They are commonly used to improve the brightness in various industrial products, especially textiles. FBA 113 is widely used in the dyeing process for cotton. This study aims to evaluate the optimum dyeing process of FBA 113 on cotton to assess the dyeing behavior, the adsorption isotherm model, and thermodynamic parameters. The study examined various parameters, including dyeing times, dyeing temperature, the amount of dye, and auxiliary. Variations in conditions were observed to define the dyeing equilibrium time, the Langmuir and Freundlich adsorption isotherm, the pseudo-first-order, pseudo-second-order dyeing kinetic model, and the thermodynamic parameters, such as enthalpy (DH0), entropy (DS0), and Gibb's energy (DG0). The results show that the appropriate dyeing was FBA 113 0.25 % owf with 20 g/L KCl as an auxiliary, the best dyeing temperature was 323 K, and the equilibrium time was 120 min. This dyeing reflected an adsorption behavior that displayed multilayer adsorption that corresponded to the Freundlich isotherm. Also, the adsorption model had a pseudo-second-order of 0.9874 using linear regression. The dyeing reaction was exothermic, with DH0 -26.58 kJ/mol, DS0 34.19 J/mol, and the spontaneous process had a negative DG0 value. The fiber and dye interacted physically. The study can enhance our understanding of FBA 113 dyeing behavior and identify situations in which it can be used in other dyeing process models, which will help optimize further dyeing studies.

Keywords

Main Subjects

References

  1. T. Kristensen, S. S. Donau, M. G. Madsen, Subs. Opt. Bright. Agent Indust. Text., MUDP report, (2018), 5-27.
  2. Tiki, A. Amin, A. Kanwal, Chemistry of optical brighteners and uses in textile industries, PTJ, 33(2010), 42-43.
  3. K. Rouette, Encyclopedia of Textile Finishing Vol. 2, Woodhead Publishing, 2000, 92-98.
  4. Sampl, S. Eyley, W. Thielemans, Real-time adsorption of optical brightening agents on cellulose thin films, Carbohydr. Polym., 261(2021), 117826.
  5. F. Esteves, A. C. Noronha, R. M. Marinho, Optical brighteners effect on white and color textiles, World Textile Conference- 4th AUTEX Conference, Roubaix, France, (2004), 1-6.
  6. P. G. Gohl, L. D. Vilensky, Textile science, CBS Publishers & Distributors PVT.LTD., 2nd ed., (2005). 78-106.
  7. Tang, K.Gao, Q. Ou, Calculation extinction cross sections and molar attenuation coefficient of small gold nanoparticles and experimental observation of their UV–vis spectral properties. Spectrochim. Acta, Part A, 191(2018), 513-520.
  8. Wang, S. Chen, J. Caceres, Chromatography-based methods for determining molar extinction coefficients of cytotoxic payload drugs and drug antibody ratios of antibody drug conjugates, J. Chromatogr. A, 1455(2016), 133-139.
  9. Shi, L. Xiang, Y. Shang, Effective extraction of fluorescent brightener 52 from foods by in situ formation of hydrophobic deep eutectic solvent, J. Food Chem., 311(2020), 125870.
  10. Dewangan, U. Gaikwad, Comparative evaluation of a novel fluorescent marker and environmental surface cultures to assess the efficacy of environmental cleaning practices at a tertiary care hospital, J. Hosp. Infect., 104(2020), 261-268.
  11. Klosterhaus, Methodology for the Assessment of colorants, Cradle to Cradle Products Innovation Institute, (2019), 9-25.
  12. Pipatpanyanugul, Quality control for dyeing, printing in textile process preparation, Technology Promotion Association (Thailand-Japan), 2nd ed., (1998), 137-142.
  13. L. F. A. De Castro, M. L. B. Abad, D. A. G. Sumalinog, Adsorption of Methylene Blue dye and Cu(II) ions on EDTA-modified bentonite: Isotherm, kinetic and thermodynamic studies. Sustainable Environ. Res., 28(2018),197-205.
  14. Ooi, L.Y. Lee, B. Y. Z. Hiew, Assessment of fish scales waste as a low cost and eco-friendly adsorbent for removal of an azo dye: Equilibrium, kinetic and thermodynamic studies. Bioresour. Technol., 245(2017), 656–664.
  15. S. Al-Kadhi, The kinetic and thermodynamic study of the adsorption Lissamine Green B dye by micro-particle of wild plants from aqueous solutions, Egypt. J. Aquat. Res., 45(2019), 231-238.
  16. Mohammadi, A.A.Karimi, H.F.Moafi, Adsorption and photocatalytic properties of surface-modified TiO2 nanoparticles for methyl orange removal from aqueous solutions, Prog. Color Colorants Coat. 9(2016), 249-260.
  17. Tang, Y. Yao, W. Chen, Kinetics of dyeing natural protein fibers with silver nanoparticles, Dyes Pig.,148(2018), 224-235.
  18. Ghibate, O. Senhaji, R. Taoui, Kinetic and thermodynamic approaches on Rhodamine B adsorption onto pomegranate peel, J.CSCEE, 3(2021), 100078.
  19. M. Etezad, M.Sadeghi-Kiakhani, Decolorization of malachite green dye solution by bacterial biodegradation, Prog. Color Colorants Coat., 14 (2021), 79-87
  20. A. Moneer, N.M. El-Mallah, M.M. El-Sadaawy, Kinetics, thermodynamics, isotherm modeling for removal of reactive Red 35 and disperse yellow 56 dyes using batch bi-polar aluminum electrocoagulation, J. Alex Eng., 60(2021), 4139-4154.
  21. Chairat, S. Rattanaphani, J.B. Bremner, et al., An adsorption and kinetic study of lac dyeing on silk, Dyes Pigm., 64(2005), 231-241.
  22. Chairat, Thermodynamics study on lac dyeing of silk yarn coated with chitosan, Walailak J. Sci. Technol., 6 (2009), 93-107.
  23. Rattanaphani, M. Chairat, J. B. Bremnar, An adsorption and thermodynamic study of lac dyeing on cotton pretreated with chitosan, Dyes Pigm., 72(2007), 88-96.
  24. M. Aljeboree, A. N. Alshirifi, A. F. Alkaim, Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon, Arabian J. Chem., 10(2017), 3381-3393.
  25. S. Boroujeny, N. Zaghian, Kinetic Study of Electrochemical Deposition of Nickel from Chloride Baths in the Presence of Saccharin, Prog. Color Colorants Coat., 14(2021), 149-160.
  26. R. Kulkarni, T. Revanth, A. Acharya, Removal of crystal violet dye from aqueous solution using water hyacinth: Equilibrium, kinetics and thermodynamics study, Res Eff Tech., 3(2017), 71-77.
  27. Sh. Kasmaei, M. K. Rofouei, M. E. Olya, Kinetic and thermodynamic studies on the reactivity of hydroxyl radicals in wastewater treatment by advanced oxidation processes, Prog. Color Colorants Coat., 13(2020), 1-10.
  28. A. Giwa, A. I. Bello, A. B. Olabintan, Kinetic and thermodynamic studies of fenton oxidative decolorization of methylene blue, J.Heliyon, 6(2020), e04454.
  29. Raghunath, K. Anand, R. M. Gengan, Sorption isotherms, kinetic and optimization process of amino acid proline based polymer nanocomposite for the removal of selected textile dyes from industrial wastewater, J. Photochem. Photobio.B:Bio., 165(2016), 189-201.
  30. Ali, S.Bibi, N.Ali, Sorptive removal of malachite green dye by activated charcoal: Process optimization, kinetic, and thermodynamic evaluation, J.CSCEE, 2(2020), 100025.
  31. Rahmani, B. Zeynizadeh, S.Karam, Removal of cationic methylene blue dye using magnetic and anioniccationic modified montmorillonite: kinetic, isotherm and thermodynamic studies, Appl. Clay Sci., 184(2020), 105391.
  32. Shore, Colorants and Auxiliaries: Organic Chemistry and Application Properties, Society of Dyers and Colourists, 2nd ed., 2002, 780-820.
  33. Michael, M. D. Mohning, P. Gregory, Chapter 3 - Mechanisms of Fibrosis, Idiopathic Pulmonary Fibrosis, (2019), 9-31.
  34. Radei, F. J. Carrion-Fite, M. Ardanuy, Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries, Polym., 10(2018), 102.
  35. Benjelloun, Y. Miyah, G. A. Evrendilek, Recent advances in adsorption kinetic models: their application to dye types. Arabian J. Chem.,14(2021), 103031.
  36. Takam, E. Acayanka, G.Y. Kamgang et al., Enhancement of sorption capacity of cocoa shell biomass modified with non-thermal plasma for removal of both cationic and anionic dyes from aqueous solution. Environ. Sci. Pollut. Res., 24(2017), 16958–16970.
  37. Z. Wu, X. Wei, Y. Xue, et al., Removal effect of atrazine in co-solution with bisphenol A or humic acid by different activated carbons. Mater., 11(2018), 2558. 

Files

Share

How to cite

Statistics