Comparative Investigations of the Corrosion Inhibition Efficiency of a 1-phenyl-2-(1-phenylethylidene)hydrazine and its Analog Against Mild Steel Corrosion in Hydrochloric Acid Solution

Document Type : Original Article

Authors

1 Department of Applied Science, University of Technology, Baghdad, Iraq

2 College of Electrical Engineering Technical, Middle Technical University, Baghdad, Iraq

3 Department of Production Engineering and Metallurgy, University of Technology, Baghdad, Iraq

Abstract

The corrosion inhibition performance of 1-phenyl-2-(1-phenylethylidene) hydrazine (PPEH) and 1-(1-(4-methoxyphenyl)ethylidene)-2-phenylhydrazine (MPEH) for mild steel (MS) in (1.0 M) hydrochloric acid was investigated based on weight loss measurements. Conditions that affect the corrosion inhibition efficiency, such as concentration, immersion time, the chemical structure of  Schiff bases, and solution temperature, were possessed in the current study.The experimental findings demonstrated that PPEH is less than MPEH. In addition, (0.005 M) PPEH protected the tested surface by (83.8%) at (30 oC), while (0.004 M) MPEH afforded (87.2%) protection.The inhibition efficiencies of PPEH and MPEH are (83.8%) and (95.1%), respectively, at a concentration of (0.005 M) at (5 h), exposure time.The efficiency of corrosion inhibition of MPEH is greater than PPEH in the hydrochloric acid environment due to the electron-donating group (methoxy group) substituted to the para-position of the phenyl ring of MPEH. The desorption process of both studied inhibitors upon the (MS) surface follows the Langmuir adsorption isotherm. Scanning electron microscopy (SEM) photographs proved the protective layer's formation upon the (MS) surface.

Keywords

Main Subjects

References

  1. S. Pinchuk, S. Gubenko, E. Belaya, Correlation between electrochemical corrosion and structural state of steel by simulation of operation conditions of railway wheels, Chem. Chem. Techn., 4(2010), 151-158.
  2. A. Gajek, T. Zakroczymski, V. Romanchuk, P. Topilnytsky, Protective properties and spectral analysis of nitrogen- and oxygen-containing corrosion inhibitors for oil fquipment, Chem. Chem. Techn., 6(2012), 209-217.
  3. D. de la Fuente, I. Diaz, J. Simancas, B. Chico, M. Morcillo, Long-term atmospheric corrosion of mild steel, Corros. Sci., 53(2011), 604-617.
  4. S.B. Ulaeto, U.J. Ekpe, M.A. Chidiebere, E.E. Oguzie, Corrosion inhibition of mild steel in hydrochloric acid by acid extracts of eichhornia crassipes, Int. J. Mater. Chem., 2(2012), 158-164.
  5. K. F. Khaled, New synthesized guanidine derivative as a green corrosion inhibitor for mild steel in acidic aolutions, Int. J. Electrochem. Sci., 3(2008), 462-475.
  6. M. Lebrini, A. Lagrenee, A. Traisnel, L. Gengembre, H. Vezin, F. Bentiss, Enhanced corrosion resistance of mild steel in normal sulfuric acid medium by 2,5-bis(nthienyl)-1,3,4-thiadiazoles: rlectrochemical, X-ray photoelectron spectroscopy and theoretical studies, Appl. Surf. Sci., 253(2007), 9267-9276.
  7. D. Guzman-Lucero, O. Olivares-Xometl, R. Martinez-Palou, N.V. Likhanova, M.A. Dominguez-Aguilar, V. Garibay-Febles, Synthesis of selected vinylimidazolium ionic liquids and their effectiveness as corrosion inhibitors for carbon steel in aqueous sulfuric acid, Ind. Eng. Chem. Res., 50(2011), 7129–7140.
  8. E. E. Ebenso, T. Arslan, F. Kandemirli, I. Love, C.O. Gretir, M. Saracoglu, S.A. Umoren, Theoretical studies of some sulphonamides as corrosion inhibitors for mild steel in acidic medium, Int. J. Quant. Chem., 110(2010), 2614–2636.
  9. A. Ehsani, M.G. Mahjani, R. Moshrefi, H. Mostaanzadeha, J.S. Shayehb, Electrochemical and DFT study on the inhibition of 316L stainless steel corrosion in acidic medium by 1-(4-nitrophenyl)-5-amino-1H-tetrazole, RSC Adv., 4(2014), 20031–20037.
  10. L. C. Murulana, A.K. Singh, S.K. Shukla, M.M. Kabanda, E.E. Ebenso, Experimental and quantum chemical studies of some bis(trifluoromethyl-sulfonyl) imide imidazolium-based ionic liquids as corrosion inhibitors for mild steel in hydrochloric acid solution, Ind. Eng. Chem. Res., 51(2012), 13282–13299.
  11. H. Keles, M. Keles, I. Dehri, O. Serinda, Adsorption and inhibitive properties of aminobiphenyl and its Schiff base on mild steel corrosion in 0.5 M HCl medium, Colloids Surf. A 320(2008), 138−145.
  12. K. C. Emregul, E. Duzgun, O. Atakol, The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media, Corros. Sci., 48(2006), 3243−3260.
  13. E. Bayol, T. Gurten, A. A. Gürten, M. Erbil, Interactions of some Schiff base compounds with mild steel surface in hydrochloric acid solution, Mater. Chem. Phys., 112(2008), 624−630.
  14. A. Yurt, O. Aykın, Diphenolic Schiff bases as corrosion inhibitors for aluminium in 0.1 M HCl: Potentiodynamic polarisation and EQCM investigations, Corros. Sci., 53(2011), 3725−3732.
  15. S. Issaadi, T. Douadi, A. Zouaoui, S. Chafaa, M. A. Khan, G. Bouet, Novel thiophene symmetrical Schiff base compounds as corrosion inhibitor for mild steel in acidic media, Corros. Sci., 53(2011), 1484−1488.
  16. M. Behpour, S. M. Ghoreishi, N. Mohammadi, N. Soltani, M. Salavati-Niasari, Investigation of some Schiff base compounds containing disulfide bond as HCl corrosion inhibitors for mild steel, Corros. Sci., 52(2010), 4046−4057.
  17. R. Hasanov, M. Sadıkoglu, S. Bilgic, Electrochemical and quantum chemical studies of some Schiff bases on the corrosion of steel in H2SO4 solution, Appl. Surf. Sci., 253(2007), 3913−3921.
  18. R. A. Prabhu, T. V. Venkatesha, A. V. Shanbhag, G.M. Kulkarni, R.G. Kalkhambkar, Inhibition effects of some Schiff’s bases on the corrosion of mild steel in hydrochloric acid solution, Corros. Sci., 50(2008), 3356-3362.
  19. S. Bilgic, N. Caliskan, The effect of N-(1-toluidine) salicylaldimine on the corrosion of austenitic chromium-nickel steel, Appl. Surf. Sci., 152(1999), 107-114.
  20. M. A. Hegazy, H. M. Ahmed, A. S. El-Tabei, Investigation of the inhibitive effect of p-substituted 4-(N,N,N-dimethyldodecylammonium bromide) benzylidene- benzene-2-yl-amine on corrosion of carbon steel pipelines in acidic medium, Corros. Sci., 53(2011), 671-678.
  21. T. A. Salman, D. S. Zinad, S. H. Jaber, M. Al-Ghezi, A. Mahal, M.S. Takriff, A. Al-Amiery, Effect of 1,3,4-thiadiazole scafold on the corrosion inhibition of mild steel in acidic medium: an experimental and computational study, J. BioTribo-Corrosion, 5(2019), 1-11.
  22. H. J. Habeeb, H. M. Luaibi, R. M. Dakhil, A. A. H. Kadhum, A. Al-Amiery, T. S. Gaaz, Development of new corrosion inhibitor tested on mild steel supported by electrochemical study, Results Phys., 8(2018), 1260-1269.
  23. A. Al-Amiery, A. Kadhim, A. Mohamad, A. Musa, C. Li, Electrochemical study on newly synthesized chlorocurcumin as an inhibitor for mild steel corrosion in hydrochloric acid, Materials, 6(2013), 5466-5472
  24. K. R. Ansari, M. A. Quraishi, A. Singh, Pyridine derivatives as corrosion inhibitors for N80 steel in 15% HCl: Electrochemical, surface and quantum chemical studies. Measurement, 76(2015), 136-147.
  25. S. Junaedi, A. Kadhim, A. Al-Amiery, A. Mohamad, M. Takriff, Synthesis and characterization of novel corrosion inhibitor derived from oleic acid: 2-Amino5-Oleyl1,3,4-Thiadiazol (AOT), Int. J. Electrochem Sci., 7(2012), 3543-3556.
  26. A. Kadhim, A. Al-Okbi, D. M. Jamil, A. Qussay, A. Al-Amiery, T. Gaaz, A. Kadhum, A. Mohamad, M.H. Nassir, Experimental and theoretical studies of benzoxazines corrosion inhibitors, Results Phys., 7(2017), 4013-4022.
  27. K. F. Al-Azawi, I. M. Mohammed, S. B. Al-Baghdadi, T. A. Salman, H. A. Issa, A. Al-Amiery, T. Gaaz, A. Kadhum, Experimental and quantum chemical simulations on the corrosion inhibition of mild steel by 3-((5-(3,5-dinitrophenyl)-1,3,4- thiadiazol-2-yl)imino)indolin-2-one, Results Phys., 9(2018), 278-283.
  28. S. B. Al-Baghdadi, F. G. Hashim, A. Q. Salam, T. K. Abed, T. S. Gaaz, A. Al-Amiery, A. A. H. Kadhum, K. S. Reda, W. K. Ahmed, Synthesis and corrosion inhibition application of NATN on mild steel surface in acidic media complemented with DFT studies, Results Phys., 8(2018), 1178-1183.
  29. A. H. M. J. Al-Obaidy, A. Kadhum, S. B. Al-Baghdadi, A. Al-Amiery, A. A. H. Kadhum, A. B. Mohamad, E. Yousif, Eco-friendly corrosion inhibitor: experimental studies on the corrosion inhibition performance of creatinine for mild steel in HCl complemented with quantum chemical calculations, Int. J. Electrochem Sci., 10(2015), 3961-3969.
  30. A. Al-Amiery, A. A. H. Kadhum, A. B. Mohamad, S. Junaedi, A novel hydrazinecarbothioamide as a potential corrosion inhibitor for mild steel in HCl, Materials, 6(2013), 1420-1428.
  31. M. H. O. Ahmed, A. Al-Amiery, Y. K. Al-Majedy, A. A. H. Kadhum, A. B. Mohamad, T. S. Gaaz, Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid, Results Phys., 8(2018), 728-739.
  32. T. A. Salman, A. A. Al-Amiery, L. M. Shaker, A. Kadhum, M. S. A. Takriff, A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl)thiazole-5-carbohydrazide, Int. J. Corros. Scale Inhib., 8(2019), 1035-1042.
  33. T. A. Salman, Q. A. Jawad, M. A. Hussain, A. A. Al-Amiery, L. M. Shaker, A. Kadhum, M. S. Takriff, Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects, Int. J. Corros. Scale Inhib., 8(2019), 1123-1136.
  34. S. S. Al-Taweel, K. W. S. Al-Janabi, H. M. Luaibi, A. A. Al-Amiery, T. S. Gaaz, Evaluation and characterization of the symbiotic effect of benzylidene derivative with titanium dioxide nanoparticles on the inhibition of the chemical corrosion of mild steel, Int. J. Corros. Scale Inhib., 8(2019), 1149-1156.
  35. D. S. Zinad, Q. A. Jawad, M. A. M. Hussain, A. Mahal, L. M. Shaker, A. A. Al-Amiery, Adsorption, temperature and corrosion inhibition studies of a coumarin derivatives corrosion inhibitor for mild steel in acidic medium: gravimetric and theoretical investigations, Int. J. Corros. Scale Inhib.,9(2020), 134-145.
  36. M. G. Mohamed, S. W. Kuo, A. Mahdy, I. M. Ghayd, K. I. Aly, Bisbenzylidene cyclopentanone and cyclohexanone-functionalized polybenzoxazine nanocomposites: Synthesis, characterization, and use for corrosion protection on mild steel, Mater. Today Commun., 25(2020), 101418.
  37. K. I. Aly, A. Mahdy, M. A. Hegazy, N.S. Al-Muaikel, S.W. Kuo, M. Gamal Mohamed, Corrosion resistance of mild steel coated with phthalimide-functionalized polybenzoxazines, Coatings, 10(2020), 1114-1126.
  38. K. I. Aly, M. G. Mohamed, O. Younis, M.H. Mahross, M. Abdel-Hakim, M. M. Sayed, Salicylaldehyde azine-functionalized polybenzoxazine: synthesis, characteri-zation, and its nanocomposites as coatings for inhibiting the mild steel corrosion, Prog. Org. Coat., 138(2020), 105385.
  39. K. I. Aly, O. Younis, M. H. Mahross, E. A. Orabi, M. Abdel-Hakim, O. Tsutsumi, M.G. Mohamed, M.M. Sayed, Conducting copolymers nanocomposite coatings with aggregation-controlled luminescence and efficient corrosion inhibition properties, Prog. Org. Coat., 135(2019), 525-535.
  40. ASTM G1. Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens; ASTM, 1999.
  41. S. A. Umoren, M.M. Solomon, S.A. Ali, H.D. M. Dafalla, Synthesis, characterization, and utilization of a diallylmethylamine-based cyclopolymer for corrosion mitigation in simulated acidizing environment, Mater. Sci. Eng., 100(2019), 897-914.
  42. Y. Yaocheng, Y. Caihong, A. Singh, Y. Lin, Electrochemical study of commercial and synthesized green corrosion inhibitors for N80 steel in acidic liquid, New J. Chem., 43(2019), 16058-16070.
  43. M. Lebrini, M. Lagrenée, H. Vezin, M. Traisnel, F. Bentiss, Experimental and theoretical study for corrosion inhibition of mild steel in normal hydrochloric acid solution by some new macrocyclic polyether compounds, Corros. Sci., 49(2007), 2254-2269.
  44. O. Redlich, D. L. Peterson, A useful adsorption isotherm, J. Phys. Chem., 63(1959), 1024-1039.
  45. K. Y. Foo, B. H. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J., 156(2010), 2-10.
  46. A. E. A. E. S. Fouda, A. Hussein, Role of some phenylthiourea derivatives as corrosion inhibitors for carbon steel in HCl solution, J. Korean Chem. Soc., 56(2012), 264-273.
  47. M. Hosseini, S. F. L. Mertens, M. Ghorbani, M. R. Arshadi, Asymmetrical schiff bases as inhibitors of mild steel corrosion in sulphuric acid media, Mater. Chem. Phys., 78(2003), 800-808.
  48. L. B. Richardson, The adsorption of carbon dioxide and ammonia by charcoal, J. Am. Chem. Soc., 39(1917), 1828-1848.
  49. T. Zhao, G. Mu, The adsorption and corrosion inhibition of anion surfactants on aluminium surface in hydrochloric acid, Corros. Sci., 41(1999), 1937-1944.
  50. M. Gopiraman, N. Selvakumaran, D. Kesavan, I. S. Kim, R. Karvembu, Chemical and physical interactions of 1-benzoyl-3,3-disubstituted thiourea derivatives on mild steel surface: corrosion inhibition in acidic media, Ind. Eng. Chem. Res., 51(2012), 7910-7922.
  51. A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum, A.B. Mohamad, New coumarin derivative as an eco-friendly inhibitor of corrosion of mild steel in acid medium, Molecules, 20( 2015), 366-375.
  52. A. Y. I. Rubaye, A.A. Abdulwahid, S.B. Al-Baghdadi, A. Al-Amiery, A.A.H. Kadhum, A.B. Mohamad, Cheery sticks plant extract as a green corrosion inhibitor complemented with LC-EIS/MS spectroscopy, Int. J. Electrochem Sci., 10(2015), 8200-8211.
  53. A. Mohamad, A. Kadhum, A. Al-Amiery, L. Ying, A. Musa, Synergistic of a coumarin derivative with potassium iodide on the corrosion inhibition of aluminum alloy in 1.0 M H2SO4, Met. Mater. Int., 20(2014), 459-468.
  54. D.S. Zinad, M. Hanoon, R.D. Salim, S.I. Ibrahim, A. Al-Amiery, M.S. Takriff, A.A.H. Kadhum, A new synthesized coumarin-derived Schiff base as a corrosion inhibitor of mild steel surface in HCl medium: gravimetric and DFT studies, Int. J. Corros. Scale Inhib., 9(2020), 228-236.
  55. A.A.H. Kadhum, A.B. Mohamad, L.A. Hammed, A. Al-Amiery, N.H. San, A.Y. Musa, Inhibition of mild steel corrosion in hydrochloric acid solution by new coumarin, Materials 7(2014), 4335-4342.
  56. Q. A. Jawad, D. S. Zinad, R. D. Salim, A. Al-Amiery, T. S. Gaaz, M. S. Takriff, A. Kadhum, Synthesis, characterization, and corrosion inhibition potential of novel thiosemicarbazone on mild steel in sulfuric acid environment, Coatings, 9(2019), 729-736.
  57. E. Sheet, J. Yamin, H. AL-Salihi, A. Salam, K. S. Reda, W. K. Ahmed, M. T. Mahdi, A.A. Al-Amiery, N-(3-nitrobenzylidene)-2-aminobenzothiazole as new locally available corrosion inhibitor for Iraqi oil, J. Balk. Tribol. Assoc., 26(2020), 194-217.
  58. J. A. A. Yamin, E. Sheet, A. Al-Amiery, Statistical analysis and optimization of the corrosion inhibition efficiency of a locally made corrosion inhibitor under different operating variables using RSM, Int. J. Corros. Scale Inhib., 9(2020), 502-512.
  59. D. M. Jamil, A.K. Al-Okbi, S.B. Al-Baghdadi, A. Al-Amiery, A. Kadhim, T. Gaaz, Experimental and theoretical studies of Schiff bases as corrosion inhibitors, Chem. Cent. J., 12(2018), 7-19.
  60. R. D. Salim, Q. A. Jawad, K. S. Ridah, L. M. Shaker, A. Al-Amiery, A. A. H. Kadhum, M. S. Takriff, Corrosion inhibition of thiadiazole derivative for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib., 9(2020), 550-563.
  61. A. Al-Amiery, L. M. Shaker, A. A. H. Kadhum, M. S. Takriff, Corrosion inhibition of mild steel in strong acid environment by 4-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)amino)benzenesulfonamide, Tribol. Ind., 42(2020), 89-96.
  62. A. A. Al-Amiery, T. A. Salman, K. F. Alazawi, L. M. Shaker, A. Kadhum, M.S. Takriff, Quantum chemical elucidation on corrosion inhibition efficiency of Schiff base: DFT investigations supported by weight loss and SEM techniques, Int. J. Low-Carbon Technol., 15(2020), 202-209.
  63. A. Al-Amiery, L. M. Shaker, A. A. H. Kadhum, M. S. Takriff, Synthesis, characterization and gravimetric studies of novel triazole-based compound, Int. J. Low-Carbon Technol., 15(2020), 164-170.
  64. H. E. Jamil, M. F. Montemor, R. Boulif, A. Shriri, M. G. S. Ferreira, An electrochemical and analytical approach to the inhibition mechanism of an amino-alcohol-based corrosion inhibitor for reinforced concrete, Electrochim Acta., 48(2003), 3509-3518.
Progress in Color, Colorants and Coatings
Volume 15, Issue 1
February 2022
Pages 53-63

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