Hydrogen-free Cu: Amorphous-C: N Coating on TC4 Titanium Alloy: The Role of Gas Ratio on Mechanical and Antibacterial Potency

Document Type : Original Article

Authors

1 Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology (ICST), Tehran, Iran

2 Surface Coatings and Corrosion Department, Institute for Color Science and Technology (ICST),Tehran, Iran

Abstract

Ti-6Al-4V alloy, also called TC4, substrates are sputter-deposited by Cu: amorphous-C: N (Cu:a-C:N) thin coatings using planar magnetron sputtering physical vapor deposition device. Mixtures of argon and nitrogen at different ratios are selected as the sputtering atmosphere, and no hydrocarbon gas is used. Correlation of microstructure, morphology, surface properties, antibacterial characteristics, and mechanical performance of the coatings to the N2/Ar ratio are discussed. The outcomes from Raman spectroscopy confirm the construction of the DLC (Diamond Like Carbon) phase in the microstructure of the coatings. The thin coatings synthesized at higher N2/Ar ratios show more increased amount of sp 3 hybridization, improved wettability, higher internal stress, and enhanced mechanical properties, i.e., higher hardness. However, these are accompanied by lower antibacterial performance. Plastic hardness (H) value of the thin coatings increased from about 2 GPa to 13 GPa by increasing N2/Ar ratio. However, bacterial reduction percent of the thin coatings decreased from 100 to 65% as N2/Ar ratio increased. The resultant outcomes reveal the critical role of the N2/Ar ratio on tailoring the antibacterial properties of Cu: a-C: N thin coatings as well as mechanical ones.

Keywords

References

  1. E. Broitman, W. Macdonald, N. Hellgren, G. Radnoczi, A. Wennerberg, M. Jacobsson, L. Hultman, Carbon nitride films on orthopedic substrates, Diam. Relat. Mater., 9(2000), 1984–1991.
  2. P. Campbell, S. Ma, Y. H, Isolation of predominantly submicron-sized UHMWPE wear partick from periprosthetic tissues, J. Biomed. Mater. Res., 29(1995), 127–131.
  3. K. Bosdorf, I. Mollenhauer, G. Willmann, U. Boenick, Materials for hip joint prostheses - Alternatives to standard materials, Biomed. Tech., 40(1995), 356–362.
  4. M. Shinohara, H. Kawazoe, T. Inayoshi, T. aki Kawakami, Y. Matsuda, H. Fujiyama, Y. Nitta, T. Nakatani, Difference of deposition process of an amorphous carbon film due to source gases, Thin Solid Films, 518(2010), 3497–3501.
  5. T. T. Liao, T. F. Zhang, S. S. Li, Q. Y. Deng, B. J. Wu, Y. Z. Zhang, Y. J. Zhou, Y. B. Guo, Y. X. Leng, N. Huang, Biological responses of diamond-like carbon (DLC) films with different structures in biomedical application, Mater. Sci. Eng. C., 69(2016), 751–759.
  6. M. Azzi, P. Amirault, M. Paquette, J. E. Klemberg-Sapieha, L. Martinu, Corrosion performance and mechanical stability of 316L/DLC coating system: Role of interlayers, Surf. Coatings Technol., 204(2010), 3986–3994.
  7. M. R. Derakhshandeh, M. J. Eshraghi, M. M. Hadavi, M. Javaheri, S. Khamseh, M. G. Sari, P. Zarrintaj, M.R. Saeb, M. Mozafari, Diamond-like carbon thin films prepared by pulsed-DC PE-CVD for biomedical applications, Surf. Innov., 6(2018), 167–175.
  8.                 D. G. Liu, J. P. Tu, R. Chen, C. D. Gu, Microstructure, corrosion resistance and biocompatibility of titanium incorporated amorphous carbon nitride films, Surf. Coatings Technol., 206(2011), 165–171.
  9. A. Nemati, M. Saghafi, S. Khamseh, E. Alibakhshi, P. Zarrintaj, M.R. Saeb, Magnetron-sputtered TixNythin films applied on titanium-based alloys for biomedical applications: Composition-microstructure-property relationships, Surf. Coatings Technol., 349(2018), 251–259.
  10. Y. H. Chan, C. F. Huang, K. L. Ou, P. W. Peng, Mechanical properties and antibacterial activity of copper doped diamond-like carbon films, Surf. Coatings Technol., 206(2011), 1037–1040.
  11. M. Fedel, A. Motta, D. Maniglio, C. Migliaresi, Surface properties and blood compatibility of commercially available diamond- like carbon coatings for cardiovascular devices, J. Biomed. Mater. Res. Part B Appl. Biomater., 90B(2008), 338–349.
  12. M. Yoshida, S. Watanabe, T. Tanaka, T. Takagi, M. Shinohara, J.W. Lee, Investigation of diamond-like carbon formed on PET film by plasma-source ion implantation using C2H2 and CH4, Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms., 206(2003), 712–716.
  13. A. Erdemir, I. B. Nilufer, O. L. Eryilmaz, M. Beschliesser, G. R. Fenske, Friction and wear performance of diamond-like carbon films grown in various source gas plasmas, Surf. Coatings Technol., 120-121(1999), 589-593.
  14. D. Bootkul, B. Supsermpol, N. Saenphinit, C. Aramwit, S. Intarasiri, Nitrogen doping for adhesion improvement of DLC film deposited on Si substrate by Filtered Cathodic Vacuum Arc (FCVA) technique, Appl. Surf. Sci., 310(2014), 284-292.
  15. M. H. Ahmed, J. A. Byrne, Effect of surface structure and wettability of DLC and N-DLC thin films on adsorption of glycine, Appl. Surf. Sci., 258(2012), 5166-5174.
  16. N. Hellgren, M. Johansson, E. Broitman, L. Hultman, J. E. Sundgren, Role of nitrogen in the formation of hard and elastic CNx thin films by reactive magnetron sputtering, Phys. Rev. B., 59(1999), 5162-5169.
  17. E. C. Cutiongco, D. Li, Y. W. Chung, C. S. Bhatia, Tribological Behavior of Amorphous Carbon Nitride Overcoats for Magnetic Thin-Film Rigid Disks, J. Tribol., 118(1996), 543-548.
  18. A. Khurshudov, K. Kato, S. Daisuke, A. Khurshudov, K. Kato, S. Daisuke, Comparison of tribological properties of carbon and carbon nitride protective coatings over magnetic media, J. Vac. Sci. Technol. A Vacuum, Surfaces, Film., 14(1996), 2935-2939.
  19.                 I. Ivanov, J. E. Greene, E. Broitman, W. T. Zheng, H. Sjo, N. Instruments, Stress development during deposition of CNx thin films, Appl. Phys. Lett., 72(1998), 2532-2534.
  20. B. Pandey, P. P. P. Pal, S. Bera, S. K. K. Ray, A. K. K. Kar, Effect of nickel incorporation on microstructural and optical properties of electrodeposited diamond like carbon (DLC) thin films, Appl. Surf. Sci., 261(2012), 789-799.
  21. S. Khamseh, E. Alibakhshi, M. Mahdavian, M. R. Saeb, H. Vahabi, J.-S. Lecomte, P. Laheurte, High-performance hybrid coatings based on diamond-like carbon and copper for carbon steel protection, Diam. Relat. Mater., 80(2017), 84-92.
  22. S. Khamseh, E. Alibakhshi, M. Mahdavian, M. R. Saeb, H. Vahabi, N. Kokanyan, P. Laheurte, Magnetron-sputtered copper/diamond-like composite thin films with super anti-corrosion properties, Surf. Coatings Technol., 333(2018), 148-157.
  23. S. Khamseh, E. Alibakhshi, B. Ramezanzadeh, M.G. Sari, A.K. Nezhad, Developing a graphite like carbon:niobium thin film on GTD-450 stainless steel substrate, Appl. Surf. Sci., 511(2020), 145613.
  24. S. Khamseh, E. Alibakhshi, B. Ramezanzadeh, J. S. Lecomte, P. Laheurte, X. Noirefalize, F. Laoutid, H. Vahabi, Tailoring hardness and electrochemical performance of TC4 coated Cu/a-C thin coating with introducing second metal Zr, Corros. Sci., 172(2020), 108713.
  25. J. S. Chen, S. P. Lau, G. Y. Chen, Z. Sun, Y. J. Li, B. K. Tay, J. W. Chai, Deposition of iron containing amorphous carbon films by filtered cathodic vacuum arc technique, Diam. Relat. Mater., 10(2001), 2018-2023.
  26. N. Pasaja, S. Sansongsiri, S. Intarasiri, T. Vilaithong, A. Anders, Mo-containing tetrahedral amorphous carbon deposited by dual filtered cathodic vacuum arc with selective pulsed bias voltage, Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. Mater. Atoms., 259(2007), 867-870.
  27. A. T. T. Koh, J. Hsieh, D. H. C. Chua, Structural characterization of dual-metal containing diamond-like carbon nanocomposite films by pulsed laser deposition, Diam. Relat. Mater., 19(2010), 637-642.
  28. K. Page, I. P. Parkin, Antimicrobial surfaces and their potential in reducing the role of the inanimate environment in the incidence of hospital-acquired infections, J. Mater. Chem., 19(2009), 3819-831.
  29. K. Page, R. G. Palgrave, I. P. Parkin, M. Wilson, L. P. Savin, A. V Chadwick, Titania and silver-titania composite films on glass- potent antimicrobial coatings, J. Mater. Chem., 17(2007), 95-104.
  30. N. Dwivedi, S. Kumar, H. K. Malik, C. Sreekumar, S. Dayal, C. M. S. Rauthan, O. S. Panwar, Investigation of properties of Cu containing DLC films produced by PECVD process, J. Phys. Chem. Solids., 73(2012), 308-316.
  31. M. Grischke, K. Bewilogua, K. Trojan, H. Dimigen, Application-oriented modifications of deposition processes for diamond-like-carbon-based coatings, Surf. Coat. Technol., 74-75(1995), 739-745.
  32. F. Heidenau, W. Mittelmeier, R. Detsch, M. Haenle, F. Stenzel, A novel antibacterial titania coating : Metal ion toxicity and in vitro surface colonization, J. Mater. Sci. Med. J. Mater. Sci. Med., 6(2005), 883-888.
  33. A. Malesevic, R. Vitchev, K. Schouteden, A. Vanhulsel, C. Van Haesendonck, Synthesis of few-layer graphene via microwave plasma-enhanced chemical, Nanotechnol., 19(2008), 305604-305609.
  34. H. Hasan, V. Abdelsayed, A. Kheder, K. AbouZeid, J. Terner, M. El-Shall, S. Al-Resayes, A. El-Azhary, Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media, J. Mater. Sci., 19(2009), 3832-3837.
  35. L. Hultman, J. Neidhardt, N. Hellgren, H. Sjöström, J. E. Sundgren, Fullerene-like Carbon Nitride: A Resilient Coating Material, MRS Bull., 28(2003), 194-202.
  36. C. Zou, W. Xie, X. Tang, Further improvement of mechanical and tribological properties of Cr-doped diamond-like carbon nanocomposite coatings by N codoping, Jpn. J. Appl. Phys., 55(2016), 115501.
  37. E. Alibakhshi, E. Ghasemi, M. Mahdavian, B. Ramezanzadeh, Fabrication and characterization of layered double hydroxide/silane nanocomposite coatings for protection of mild steel, J. Taiwan Inst. Chem. Eng., 80(2017), 924-934.
  38. R. Samiee, B. Ramezanzadeh, E. Alibakhshi, Corrosion inhibition performance and healing ability of a hybrid silane coating in the presence of praseodymium (III) cations, J. Electrochem. Soc., 165(2018), 777-786.
  39. R. Samiee, B. Ramezanzadeh, M. Mahdavian, E. Alibakhshi, Assessment of the smart self-healing corrosion protection properties of a water-base hybrid organo-silane film combined with non-toxic organic/inorganic environmentally friendly corrosion inhibitors on mild steel, J. Clean. Prod., 220(2019), 340-356.
  40. J. H. Choi, H. S. Ahn, S. C. Lee, K. R. Lee, Stress reduction behavior in metal-incorporated amorphous carbon films : first-principles approach, J. Phys. Conf. Ser., 29(2006), 155-158.
  41. M. Y. Ming, X. Jiang, D. G. Piliptsou, Y. Zhuang, A. V. Rogachev, A. S. Rudenkov, A. Balmakou, Chromium-modified a-C films with advanced structural, mechanical and corrosive-resistant characteristics, Appl. Surf. Sci., 379(2016), 424-432.
  42. E. Broitman, W. T. Zheng, H. Sjöström, I. Ivanov, J. E. Greene, J. E. Sundgren, Stress development during deposition of CNx thin films, Appl. Phys. Lett., 72(1998), 2532-2534.
  43. P. Couvrat, M. Denis, M. Langer, S. Mitura, P. Niedzielski, J. Marciniak, The corrosion tests of amorphous carbon coatings deposited by r.f. dense plasma onto steel with different chromium contents, Diam. Relat. Mater., 4(1995), 1251-1254.
  44. C. T. Chuang, C. K. Chao, R. C. Chang, K. Y. Chu, Effects of internal stresses on the mechanical properties of deposition thin films, J. Mater. Process. Technol., 201(2008), 770-774.
  45. D. T. Quinto, A. T. Santhanam, P. C. Jindal, Mechanical properties, structure and performance of chemically vapor-deposited and physically vapor-deposited coated carbide tools, Mater. Sci. Eng., 105-106(1988), 443-452.
  46. J. Gunnars, A. Alahelisten, Thermal stresses in diamond coatings and their influence on coating wear and failure, Surf. Coatings Technol., 80(1996), 303-312.
  47. A. Mani, P. Aubert, F. Mercier, H. Khodja, C. Berthier, P. Houdy, Effects of residual stress on the mechanical and structural properties of TiC thin films grown by RF sputtering, Surf. Coatings Technol., 194(2005), 190-195.
  48. M. Bai, K. Kato, N. Umehara, Y. Miyake, Nanoindentation and FEM study of the effect of internal stress on micro r nano mechanical property of thin CNx films, Thin Films, 377-378(2000), 138-147.
  49. P. Kulu, R. Veinthal, M. Saarna, R. Tarbe, Surface fatigue processes at impact wear of powder materials, Wear, 263(2007), 463-471.
  50. P. Kulu, I. Hussainova, R. Veinthal, Solid particle erosion of thermal sprayed coatings, Wear., 258(2005), 488-496.
  51. J. Musil, H. Poláková, Hard nanocomposite Zr-Y-N coatings, correlation between hardness and structure, Surf. Coatings Technol., 127(2000), 99-106
Progress in Color, Colorants and Coatings
Volume 14, Issue 4
November 2021
Pages 281-291

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