Theoretical and Experimental Studies on the Corrosion Inhibition Potentials of 2-((6-Methyl-2-Ketoquinolin-3-yl)Methylene) Hydrazinecarbothioamide for Mild Steel in 1 M HCl

Document Type : Original Article

Authors

1 Production Engineering and Metallurgy, University of Technology, Baghdad, Iraq

2 Applied Science Department, University of Technology, Baghdad, Iraq.

3 Department of Chemical and Process Engineering, University Kebangsaan Malaysia (UKM), Bangi, Selangor

Abstract

Novel modified coumarin bearing thiosemicarbazide pendant moiety prepared by the reaction of 3-(6-methyl-2-ketoquinoline)methanal with thiosemicarbazide through a condensation reaction. The synthesized coumarin namely 2-((6-methyl-2-ketoquinoline-3-yl)methylene) hydrazinecarbo-thioamide (MKMHCT) was characterized using spectroscopic techniques (proton and carbon 13 nuclear magnetic resonance and Fourier transform infrared). The corrosion inhibition of mild steel in 1 M hydrochloric acid solution by MKMHCT was investigated using the gravimetric method, scanning electron microscopy, and quantum chemical calculations. The obtained findings indicated that MKMHCT can inhibit the mild steel corrosion in a hydrochloric acid environment. The highest inhibition efficiency obtained from gravimetric techniques was 95.84% at the inhibitor concentration of 0.005 M. The adsorption of the studied inhibitor molecules on the mild steel surface was found to obey the Langmuir adsorption isotherm. Density functional theory (DFT) revealed an excellent correlation with experimental inhibitive performance. The frontier molecular orbital energies, i.e., Highest Occupied Molecular Orbital (HOMO), Lowest Unoccupied Molecular Orbital (LUMO), and other parameters were in harmony with methodological findings. Mulliken charges indicated that the inhibitor molecules are adsorbed on the surface of mild steel via coordination bonds between the iron atoms on the mild steel surface and the pairs of electrons of the nitrogen, oxygen and sulfur atoms.

Keywords

References

  1. Al-Amiery, Y. Al-Majedy, A. Kadhum, Hydrogen peroxide scavenging activity of novel coumarins synthesized using different approaches, PLoS On3, 10(2015), 0132175.
  2. Al-Amiery, R. Al-Bayati, K. Saour, M. Radi, Cytotoxicity, antioxidant and antimicrobial activities of novel 2-quinolone derivatives derived from coumarins. Res.Chem. Intermed., 38(2012), 559-69.
  3. Al-Amiery, Y. Al-Majedy A, Kadhum, A. Mohamad. Novel macromolecules derived from coumarin: synthesis and antioxidant activity, Sci Rep., 5(2015), 11825
  4. Al-Amiery, Y. Al-Majedy, D. Al-Duhaidahawi, A. Kadhum, A.B. Mohamad, Green antioxidants: synthesis and scavenging activity of coumarin-thiadiazoles as potential antioxidants complemented by molecular modeling studies, Free Rad. Antioxid., 6(2016), 173-7.
  5. Al-Amiery, Y. Al-Majedy, A. Kadhum, A. Mohamad, New coumarin derivative as an eco-friendly inhibitor of corrosion of mild steel in acid medium, Molecules, 29(2014), 366-83.
  6. Al-Amiery, Y. Al-Majedy, A. Kadhum, A. Mohamad, Synthesis of new coumarins complemented by quantum chemical studies, Res. Chem. Intermed., 42(2016), 3905-3918.
  7. A. A. Al-Amiery, A. A. H. Kadhum, A. A. Mohamad, Antifungal activities of new coumarins, Molecules, 17(2012), 5713-23.
  8. Y. Al-Majedy, A. Al-Amiery, A. Kadhum, Efficient catalyst one-pot synthesis of 3 7-(aryl)-10,10-dimethyl-10,11-dihydrochromeno[4,3-b] 4 chromene-6,8(7H,9H)- dione derivatives 5 complemented by antibacterial activity, Bio. Med. Res. Inter., 2016(2016), 1-7
  9. Y. Al-Majedy, A. Al-Amiery, A. Kadhum, A synthesis and characterization of some new 4-Hydroxy-coumarin derivatives, Molecules, 19(2014), 11791-11799
  10. Y. Al-Majedy, A. Al-Amiery, A. Kadhum, Mohama, Antioxidant activities of 4-methylumbelliferone derivatives, PLoS One., 11(2016), 1-13.
  11. Y. Al-Majedy, D. Al-Duhaidahawi, K. Al-Azawi, A. Al-Amiery, A. Kadhum, A. Mohamad, Coumarins as potential antioxidant agents complemented with suggested mechanisms and approved by molecular modeling studies, Molecules, 21(2016), 135-45.
  12. T. A. Salman, D. S. Zinad, S. H. Jaber, M. Al-Ghezi, A. Mahal, M. S. Takriff, A. Al-Amiery, Effect of 1,3,4-thiadiazole scafold on the corrosion inhibition of mild steel in acidic medium: an experimental and computational study, J. BioTribo-Corr., 5(2019), 1-10.
  13. H. J. Habeeb, H. M. Luaibi, R. M. Dakhil, A. A. H. Kadhum, A. Al-Amiery, T.S. Gaaz, Development of new corrosion inhibitor tested on mild steel supported by electrochemical study, Results Phys., 8(2018), 1260.
  14. A. Al-Amiery, A. Kadhim, A. Mohamad, A. Musa, and C. Li, Electrochemical study on newly synthesized chlorocurcumin as an inhibitor for mild steel corrosion in hydrochloric acid, Materials, 6(2013), 5466.
  15. S. Junaedi, A. Kadhim, A. Al-Amiery, A. Mohamad and M. Takriff, Synthesis and characterization of novel corrosion inhibitor derived from oleic acid: 2-Amino5-Oleyl1,3,4-Thiadiazol (AOT), Int. J. Electrochem Sci., 7(2012), 3543.
  16. A. Kadhim, A. Al-Okbi, D. M. Jamil, A. Qussay, A. Al-Amiery, T. S. Gaaz, A. A. H. Kadhum, A. B. Mohamad, M. H. Nassir, Experimental and theoretical studies of benzoxazines corrosion inhibitors, Results Phys., 7(2017), 4013.
  17. K. F., Al-Azawi, I. M. Mohammed, S. B. Al-Baghdadi, T. A. Salman, H. A. Issa, A. Al-Amiery, T. S. Gaaz, A. A. H. Kadhum, Experimental and quantum chemical simulations on the corrosion inhibition of mild steel by 3-((5-(3,5-dinitrophenyl)-1,3,4-thiadiazol-2-yl)imino) indolin-2-one, Results Phys., 9(2018), 278.
  18. A. Al-Amiery, L. M. Shaker Corrosion inhibition of mild steel using novel pyridine derivative in 1 M hydrochloric acid, Koroze a ochrana materiálu, 64(2020), 59-64.
  19. J. Braihi, A. J. Jawad, A. A. Kadhum, H. S. Aljibori, A. A. Al-Amiery, Chemical resistance of NR/SBR rubber blends for surfaces corrosion protection of metallic tanks in petrochemical industries, Koroze a ochrana materiálu, 64(2020), 65-71
  20. Al-Amiery, A.A.H. Kadhum, A.B. Mohamad, S. Junaedi, A novel hydrazinecarbothioamide as a potential corrosion inhibitor for mild steel in HCl, Materials, 6(2013), 1420.
  21. M. H. O. Ahmed, A. Al-Amiery, Y. K. Al-Majedy, A. A. H. Kadhum, A. B. Mohamad, T. S. Gaaz, Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid, Results Phys., 8(2018), 728.
  22. T. A. Salman, A. Al-Amiery, L. M. Shaker, A. Kadhum and M. S. Takriff, A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl)thiazole-5-carbohydrazide, Int. J. Corros. Scale Inhib., 8(2019), 1035.
  23. T. A. Salman, Q. A. Jawad, M. A. Hussain, A. Al-Amiery, L. M. Shaker, A. Kadhum and M. S. Takriff, Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects, Int. J. Corros. Scale Inhib., 8(2019), 1123.
  24. S. S. Al-Taweel, K. W. S. Al-Janabi, H. M. Luaibi, A. Al-Amiery, T. S. Gaaz, Evaluation and characterization of the symbiotic effect of benzylidene derivative with titanium dioxide nanoparticles on the inhibition of the chemical corrosion of mild steel, Int. J. Corros. Scale Inhib., 8(2019), 1149.
  25. D. S. Zinad, Q. A. Jawad, M. A. M. Hussain, A. Mahal, L. M. Shaker, A. Al-Amiery, Adsorption, temperature and corrosion inhibition studies of a coumarin derivatives corrosion inhibitor for mild steel in acidic medium: gravimetric and theoretical investigations, Int. J. Corros. Scale Inhib., 9(2020), 134.
  26. A. Al-Amiery, Y. K. Al-Majedy, A. A. H. Kadhum, A. B. Mohamad, New coumarin derivative as an eco-friendly inhibitor of corrosion of mild steel in acid medium, Molecules, 20(2015), 366.
  27. A. Y. I. Rubaye, A. A. Abdulwahid, S. B. Al-Baghdadi, A. Al-Amiery, A. A. H. Kadhum, A. B. Mohamad, Cheery sticks plant extract as a green corrosion inhibitor complemented with LC-EIS/MS spectroscopy, Int. J. Electrochem Sci., 10,(2015), 8200.
  28. A. H. M. J. Al-Obaidy, A. Kadhum, S. B. Al-Baghdadi, A. Al-Amiery, A. A. H. Kadhum, A. B. Mohamad, E. Yousif, Eco-friendly corrosion inhibitor: experimental studies on the corrosion inhibition performance of creatinine for mild steel in HCl complemented with quantum chemical calculations, Int. J. Electrochem Sci., 10(2015), 3961.
  29. A. Kadhum, A. Mohamad, A.A.H. Kadhum, A.B. Mohamad, L.A. Hammed, A. Al-Amiery, N.H. San, A.Y. Musa, Inhibition of mild steel corrosion in hydrochloric acid solution by new coumarin, Materials, 7(2014), 4335.
  30. Q. A. Jawad, D. S. Zinad, R. D. Salim, A. Al-Amiery, T. S. Gaaz, M. S. Takriff, A. Kadhum, Synthesis, Characterization, and corrosion inhibition potential of novel thiosemicarbazone on mild steel in sulfuric acid environment, Coatings, 9(2019), 729.
  31. A. Mohamad, A. Kadhum, A. Al-Amiery, L. Ying and A. Musa, Synergistic of a coumarin derivative with potassium iodide on the corrosion inhibition of aluminum alloy in 1.0 M H2SO4, Met. Mater. Int., 20(2014), 459.
  32. D.S. Zinad, M. Hanoon, R.D. Salim, S.I. Ibrahim, A. Al-Amiery, M.S. Takriff, A.A.H. Kadhum, A new synthesized coumarin-derived Schiff base as a corrosion inhibitor of mild steel surface in HCl medium: gravimetric and DFT studies, Int. J. Corros. Scale Inhib., 9(2020), 228.
  33. E. Yousif, Y. Win, A. Al-Hamadani, A. Al-Amiery, A. Kadhum, A. Mohamad, Furosemi as an environmental friendly inhibitor of corrosion of zinc metal in acid medium experimental and theoretical studies, Int. J. Electrochem Sci., 10(2015), 1708.
  34. D. M. Jamil, A. K. Al-Okbi, S. B. Al-Baghdadi, A. Al-Amiery, A. Kadhim and T. S. Gaaz, Experimental and theoretical studies of Schiff bases as corrosion inhibitors, Chem. Cent. J., 12(2018), 1-10.
  35. J. A. A. Yamin, E. Ali Eh Sheet, A. Al-Amiery, Statistical analysis and optimization of the corrosion inhibition efficiency of a locally made corrosion inhibitor under different operating variables using RSM, Int. J. Corros. Scale Inhib., 9(2020), 502.
  36. R. D. Salim, Q. A. Jawad, K. S. Ridah, L. M. Shaker, A. Al-Amiery, A. A. H. Kadhum, M. S. Takriff, Corrosion inhibition of thiadiazole derivative for mild steel in hydrochloric acid solution, Int. J. Corros. Scale Inhib., 9(2020), 550.
  37. A. Al-Amiery, L. M. Shaker, A. A. H. Kadhum, M. S. Takriff, Corrosion Inhibition of Mild Steel in Strong Acid Environment by 4-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)amino)benzenesulfonamide, Tribology Indust., 42(2020), 89-97.
  38. S. B. Al-Baghdadi, F. G. Hashim, A. Q. Salam, T.K. Abed, T. S. Gaaz, A. Al-Amiery, A. A. H. Kadhum, K. S. Reda, W. K. Ahmed, Synthesis and corrosion inhibition application of NATN on mild steel surface in acidic media complemented with DFT studies, Results Phys., 8(2018), 1178.
  39. A. Al-Amiery, T. Salman, K. Alazawi, L. Shaker, A. Kadhum, M. Takriff, Quantum chemical elucidation on corrosion inhibition efficiency of Schiff base: DFT investigations supported by weight loss and SEM techniques, Inter. J. Low-Carbon Technol., 15(2020), 202–209.
Progress in Color, Colorants and Coatings
Volume 15, Issue 1
February 2022
Pages 11-23

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