Impact of Chitosan-poly(amidoamine) Dendreimer Hybrid Treatment on Dyeing and Color Fastness Properties of Wool Yarn with Madder Natural Dye

Document Type : Original Article

Authors

1 Department of Organic Colorants, Institute for Color Science and Technology, Tehran, Iran.

2 Faculty of Carpet, Tabriz Islamic Art University, Tabriz, Iran

Abstract

In recent years, chitosan and its different derivatives have been extensively used in surface modification and functional finishing of textiles. In this study, wool yarns used in handmade carpet were treated with different concentrations of chitosan-poly (amidoamine) dendrimer hybrid (Ch-PAMAM) and characterized by scanning electron microscope (SEM), and their dyeing properties were investigated through dyeing with madder as natural dye. SEM images showed that Ch-PAMAM was almost evenly grafted on the wool surface which resulted in significant improvement in dyeing characteristics with madder. Indeed, treated wool exhibited lower optimal dyeing temperature and dyeing time and required lower amount of madder dye to achieve a desired color strength, as compared to raw wool. Moreover, due to its “bio-mordant” role, Ch-PAMAM was replaced with metal mordant and acid auxiliary in wool dyeing with natural dye. In addition, rub and light fastness of dyed treated wool was improved to some extent. The results of this study confirmed that Ch-PAMAM can be effectively used as alternative bio-mordant in eco-friendly dyeing of wool with madder dye.

Keywords


  1. T. Bechtold, R. Mussak, Handbook of natural colorants, John Wiley & Sons, West Sussex, 2009, ISBN 978-0-470-51199-2.
  2. M. R. Shahparvari, M, Safi, S. Safapour, K. Gharanjig, Compatibility of natural dyes on aluminum pre-mordanted woolen yarns by determination of diffusion coefficient, Fibers Polym., 19(2018), 1663-1669.
  3. M. B. Kasiri, S. Safapour, Natural dyes and antimicrobials for green treatment of textiles, Environ. Chem. Let., 12(2014), 1-13.
  4. M. B. Kasiri, S. Safapour, Exploring and Exploiting Plants Extracts as the Natural Dyes/Antimicrobials in Textiles Processing, Prog. Color Colorants Coat., 8 (2015), 87-114.
  5. S. Adeel, M. Zuber, F. Rehman, K.M. Zia, Microwave-assisted extraction and dyeing of chemical and bio-mordanted cotton fabric using harmal seeds as a source of natural dye, Environ. Sci. Pollut. R., 25(2018), 11100-11110.
  6. B. Glover, J. H. Pierce, Are natural colorants good for your health?, J. Soc. Dyers Colour. 109(1993), 5-7.
  7. M. Shahid, F. Mohammad, Recent advancements in natural dye applications: a review, J. Clean. Prod., 53(2013), 310-331.
  8. S. Mirnezhad, S. Safapour, M. Sadeghi-Kiakhani, Dual-mode adsorption of cochineal natural dye on wool fibers: kinetic, equilibrium, and thermodynamic studies, Fibers Polym., 18(2017), 1134-1145.
  9. M. Sadeghi-Kiakhani, S. Safapour, S. Mirnezhad, Thermodynamic and kinetic studies on the adsorption behavior of natural dye cochineal on polyamide 66, Color. Technol., 134(2018), 308-314.
  10. S. Safapour, M. Sadeghi-Kiakhani, S. Eshaghloo-Galugahi, Extraction, Dyeing, and antibacterial properties of crataegus elbursensis fruit natural dye on wool yarn, Fibers Polym., 19(2018), 1428-1434.
  11. A. Haji, M. Nasiriboroumand, S. S. Qavamnia, Cotton dyeing and antibacterial finishing using agricultural waste by an eco-friendly process optimized by response surface methodology. Fibers Polym., 19(2018), 2359-2364.
  12. N. Arivithamani, S.A. Mary, Kumar MS, V.R. Giri Dev, Keratin hydrolysate as an exhausting agent in textile reactive dyeing process. Clean Technol. Environ. Policy, 16(2014), 1207-1215.
  13. Holme, Challenge and change in wool dyeing and finishing. Rev. Prog. Color, 33(2003), 85-92.
  14. D. Enescu, Use of Chitosan in surface modification of textile materials, Roumanian Biotechnol Lett., 13(2008), 4037-4048.
  15. S. Safapour, M. Sadeghi-Kiakhani, S. Doustmohammadi, Chitosan-cyanuric chloride hybrid as an efficient novel bio-mordant for improvement of cochineal natural dye absorption on wool yarns, J. Text. I., 110(2019), 81-88.
  16. P. E. Froehing, Dendrimers and dyes-A review, Dyes Pigm., 48(2001), 187-195.
  17. M. Sadeghi-Kiakhani, S. Safapour, Eco-friendly dyeing of treated wool fabrics with reactive dyes using chitosan poly(propylene imine)dendreimer hybrid, Clean Technol. Environ. Policy, 17(2015), 1019-1027.
  18. L. Mehrparvar, S. Safapour, M. Sadeghi-Kiakhani, K. Gharanjig, A cleaner and eco-benign process for wool dyeing with madder, Rubia tinctorum L., root natural dye, Int. J. Environ. Sci. Technol., 13(2016), 2569-2578.
  19. L. Mehrparvar, S. Safapour, M. Sadeghi-Kiakhani, Kamaladin Gharanjig, Chitosan-polypropylene imine dendrimer hybrid: a new ecological biomordant for cochineal dyeing of wool, Environ. Chem. Lett., 14(2016), 533-539.
  20. M. Sadeghi-Kiakhani, S. Safapour, Salt-free reactive dyeing of the cotton fabric modified with chitosan- poly(propylene imine) dendrimer hybrid, Fiber Polym., 16(2015), 1075-1081.
  21. M. Sadeghi-Kiakhani, S. Safapour, Salt-free dyeing of cotton fabric modified with prepared chitosan-poly(propylene) imine dendrimer using direct dyes. Prog. Color Colorants Coat., 11(2018), 21-32.
  22. M. Sadeghi-Kiakhani, S. Safapour, Improvement of dyeing and antimicrobial properties of nylon fabrics modified using chitosan-poly(propylene imine) dendreimer hybrid, J. Ind. Eng. Chem., 33(2016), 170-177.
  23. S. Aryabadie, M. Sadeghi-Kiakhani, M. Arami, Antimicrobial and dyeing studies of treated cotton fabrics by prepared chitosan-PAMAM dendrimer/Ag Nano-emulsion, Fiber Polym., 16(2015), 2529-2537.
  24. S. Adeel, F. Rehman, M.U. Iqbal, N. Habib, S. Kiran, M. Zuber, K.M. Zia, Ultrasonic assisted sustainable dyeing of mordanted silk fabric using arjun (Terminalia arjuna) bark extracts, Environ Prog Sustain Energy., 38(2019), S331-S339.
  25. S. Adeel, K.M. Zia, M. Abdullah, F. Rehman, M. Salman, M. Zuber, Ultrasonic assisted improved extraction and dyeing of mordanted silk fabric using neem bark as source of natural colourant, Nat. Prod. Res., 8(2018), 1-13
  26. M. Sadeghi-Kiakhani, S. Safapour, Functionalization of polyamidoamine dendrimers-based nano-architectures using a naphthalimide derivative and their fluorescent, dyeing and antimicrobial properties on wool fibers, Luminescence: J. Biological Chem. Luminescence, 31(2016), 1005-1012.
  27. M. Sadeghi-Kiakhani, S. Safapour, Improvement of the dyeing and fastness properties of a naphthalimide fluorescent dye using poly(amidoamine) dendrimer. Color. Technol., 131(2015), 142-148.