A Comparative Study for the Removal of Methylene Blue Dye from Aqueous Solution by Novel Activated Carbon Based Adsorbents

Document Type : Original Article

Authors

1 Department of Environmental Health Engineering, School of Health, Hamadan University of Medical Sciences, Hamadan, Iran

2 Department of Environmental Health, Khalkhal University of Medical Sciences, Khalkhal, Iran

3 Department of Pathology and Anatomy, Ardabil University of Medical Sciences, Ardabil, Iran

4 Department of Dental, Ardabil University of Medical Sciences, Ardabil, Iran

5 Department of Environmental Health School of Health, Ardabil University of Medical Sciences, Ardabil, Iran

6 Department of Public Health, Khalkhal University of Medical Sciences, Khalkhal, Iran

Abstract

This study was conducted to assess the ability of the studied adsorbent, i.e. raw oak fruit hulls and the activated carbon prepared from oak fruit hull for removing the Methylene blue (MB) from aqueous solution. This study was conducted under various effective parameters, e.g., contact time, pH, MB concentration, adsorbent concentration. The optimum amount of each parameter was determined and the isotherm and kinetic studies were also carried out. The results revealed that the best results for MB removal efficiency are observed using the activated carbon prepared from oak fruit hulls. It was also observed that increasing the contact time, pH and adsorbent concentration provides better condition to enhance the dye removal efficiency and increasing the MB, hence reducing the removal efficiency. Furthermore, the results also clarified that the best models to describe the MB adsorption onto the raw oak fruit hulls and activated carbon are the Langmuir model 1 (R2=0.9971) and Langmuir 2 (R2=0.7631), respectively. In addition, the adsorption of MB onto the raw oak fruit hulls and activated carbon are better fitted to pseudo-second-order model and zero-order model, respectively. Finally, it can be concluded that the activated carbon prepared from the raw oak fruit hulls is more valuble than the raw oak fruit hull for removing the MB. 

Keywords


  1. R. M. Novais, A. P. Caetano, M. P. Seabra, J. A. Labrincha, R. C. Pullar, Extremely fast and efficient methylene blue adsorption using eco-friendly cork and paper waste-based activated carbon adsorbents, J. Clean. Prod., 197(2018), 1137-1147.
  2. M. Peydayesh, A. Rahbar-Kelishami, Adsorption of methylene blue onto Platanus orientalis leaf powder: kinetic, equilibrium and thermodynamic studies, J. Indust. Eng. Chem., 21(2015), 1014-1019.
  3. N. M. Mahmoodi, B. Hayati, H. Bahrami, M. Arami, Dye adsorption and desorption properties of Mentha pulegium in single and binary systems, J. Appl. Poly. Sci., 122(2011), 1489-1499.
  4. M. A. Zazouli, Z. Yousefi, J. Yazdani-Charati, Y. Mahdavi, Application of AzollaFiliculoides Biomass in Acid Black 1 Dye Adsorption from Aqueous Solution, Iranian J. Health Sci., 2(2014), 24-32.
  5. A. Anouzla, Y. Abrouki, S. Souabi, M. Safi, H. Rhbal, Colour and COD removal of disperse dye solution by a novel coagulant: application of statistical design for the optimization and regression analysis, J. Hazar. Mater., 166(2009), 1302-1306.
  6. M. Rahnamay, M. Mahdavi, A. A. Shekarchi, P. Zare, M.A.H. Feizi, Cytotoxic and apoptosis inducing effect of some pyrano [3, 2-c] pyridine derivatives against MCF-7 breast cancer cells, Acta Biochim. Polonica, 65(2018), 397–402-397–402.
  7. A. Zahrim, C. Tizaoui, N. Hilal, Coagulation with polymers for nanofiltration pre-treatment of highly concentrated dyes: a review, Desalination, 266(2011), 1-16.
  8. A. Stolz, Basic and applied aspects in the microbial degradation of azo dyes, Appl. Microbiol. Biotechnol., 56(2001), 69-80.
  9. V. Garg, R. Gupta, A.B. Yadav, R. Kumar, Dye removal from aqueous solution by adsorption on treated sawdust, Bioresource Technol., 89(2003), 121-124.
  10. D. Pathania, S. Sharma, P. Singh, Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast, Arabian J. Chem., 10(2017), S1445-S1451.
  11. S. Dawood, T.K. Sen, C. Phan, Performance and dynamic modelling of biochar and kaolin packed bed adsorption column for aqueous phase methylene blue (MB) dye removal, Environ. Technol., (2018), 1-35.
  12. X. Xiao, F. Zhang, Z. Feng, S. Deng, Y. Wang, Adsorptive removal and kinetics of methylene blue from aqueous solution using NiO/MCM-41 composite, Phys. E: Low-dimensional System Nanostruct., 65(2015), 4-12.
  13. D. Balarak, J. Jaafari, G. Hassani, Y. Mahdavi, I. Tyagi, S. Agarwal, V.K. Gupta, The use of low-cost adsorbent (Canola residues) for the adsorption of methylene blue from aqueous solution: Isotherm, kinetic and thermodynamic studies, Colloid Interf. Sci. Commun., 7(2015), 16-19.
  14. A. Haghi, A. Vahedi, A. Shekarchi, A. Kamran, Correlation of serum intercellular adhesion molecule 1 and vascular endothelial growth factor with tumor grading and staging in breast cancer patients, J. Cancer Res. Therapeut., 13(2017), 18-29.
  15. Z. Aksu, A.İ. Tatlı, Ö. Tunç, A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters, Chem. Eng. J., 142(2008), 23-39.
  16. B. H. Hameed, Spent tea leaves: a new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions, J. Hazar. Mater., 161 2009), 753-759.
  17. F. Deniz, S. Karaman, Removal of Basic Red 46 dye from aqueous solution by pine tree leaves, Chem. Eng. J., 170(2011), 67-74.
  18. O. Baytar, Ö. Şahin, C. Saka, S. Ağrak, Characterization of microwave and conventional heating on the pyrolysis of pistachio shells for the adsorption of Methylene Blue and Iodine, Anal. Lett., 55(2018), 1-16.
  19. A. Al-Sabagh, Y. Moustafa, A. Hamdy, H. Killa, R. Ghanem, R. Morsi, Preparation and characterization of sulfonated polystyrene/magnetite nanocomposites for organic dye adsorption, Egyptian J. Petrol., 27(2018), 403-413.
  20. B. Hayati, N.M. Mahmoodi, A. Maleki, Dendrimer–titania nanocomposite: synthesis and dye-removal capacity, Res. Chem. Intermed., 41(2015), 3743-3757.
  21. M. Toor, B. Jin, Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye, Chem. Eng. J., 187(2012), 79-88.
  22. A. Tor, Y. Cengeloglu, Removal of congo red from aqueous solution by adsorption onto acid activated red mud, J. Hazar. Mater., 138(2006), 409-415.
  23. V. Gupta, A. Agarwal, M. Singh, N. Singh, Removal of Red RB dye from aqueous solution by belpatra bark charcoal (BBC) adsorbent, J. Mater. Environ. Sci, 8(2017), 3654-3665.
  24. B. Hayati, M. Arami, A. Maleki, E. Pajootan, Thermodynamic properties of dye removal from colored textile wastewater by poly (propylene imine) dendrimer, Desalination Water Treat., 56(2015), 97-106.
  25. M. A. Islam, M. Ahmed, W. Khanday, M. Asif, B. Hameed, Mesoporous activated coconut shell-derived hydrochar prepared via hydrothermal carbonization-NaOH activation for methylene blue adsorption, J. Environ. Manag., 203(2017), 237-244.
  26. H. Rezakhani Moghaddam, H. Allahverdipour, H. Matlabi, Barriers to women’s participation: experiences of volunteers and community healthcare authorities, Social Work Public Health, 33(2018), 237-249.
  27. S. M. Miraboutalebi, S. K. Nikouzad, M. Peydayesh, N. Allahgholi, L. Vafajoo, G. McKay, Methylene blue adsorption via maize silk powder: kinetic, equilibrium, thermodynamic studies and residual error analysis, Proc. Safety Environ. Prot., 106(2017), 191-202.
  28. B. Hayati, M. Arami, A. Maleki, E. Pajootan, Application of dendrimer/titania nanohybrid for the removal of phenol from contaminated wastewater, Desalination Water Treat., 57(2016), 6809-6819.
  29. M. A. Islam, S. Sabar, A. Benhouria, W. A. Khanday, M. Asif, B.H. Hameed, Nanoporous activated carbon prepared from karanj (Pongamia pinnata) fruit hulls for methylene blue adsorption, J. Taiwan Instit. Chem. Eng., 74(2017), 96-104.
  30. R. Elmoubarki, M. Taoufik, A. Moufti, H. Tounsadi, F. Mahjoubi, Y. Bouabi, S. Qourzal, M. Abdennouri, N. Barka, Box-Behnken experimental design for the optimization of methylene blue adsorption onto Aleppo pine cones, J. Mater. Environ. Sci., 8(2017), 2184-2191.
  31. B. Hayati, A. Maleki, F. Najafi, H. Daraei, F. Gharibi, G. McKay, Adsorption of Pb2+, Ni2+, Cu2+, Co2+ metal ions from aqueous solution by PPI/SiO2 as new high performance adsorbent: Preparation, characterization, isotherm, kinetic, thermodynamic studies, J. Mol. Liquids, 237(2017), 428-436.
  32. R. Ebrahimi, B. Hayati, B. Shahmoradi, R. Rezaee, M. Safari, A. Maleki, K. Yetilmezsoy, Adsorptive removal of nickel and lead ions from aqueous solutions by poly (amidoamine)(PAMAM) dendrimers (G4), Environ. Technol. Innovation, 12(2018), 261-272.
  33. A. Behnamfard, M.M. Salarirad, Equilibrium and kinetic studies on free cyanide adsorption from aqueous solution by activated carbon, J. Hazar. Mater., 170(2009), 127-133.
  34. D. Savova, E. Apak, E. Ekinci, F. Yardim, N. Petrov, T. Budinova, M. Razvigorova, V. Minkova, Biomass conversion to carbon adsorbents and gas, Biomass Bioenergy, 21(2001), 133-142.
  35. C. Arunlertaree, W. Kaewsomboon, A. Kumsopa, P. Pokethitiyook, P. Panyawathanakit, Removal of lead from battery manufacturing wastewater by egg shell, Songklanakarin J. Sci. Technol, 29(2007), 857-868.
  36. R. Han, L. Zhang, C. Song, M. Zhang, H. Zhu, L. Zhang, Characterization of modified wheat straw, kinetic and equilibrium study about copper ion and methylene blue adsorption in batch mode, Carbohydrate Poly., 79(2010), 1140-1149.
  37. B. Hayati, A. Maleki, F. Najafi, F. Gharibi, G. McKay, V. K. Gupta, S. H. Puttaiah, N. Marzban, Heavy metal adsorption using PAMAM/CNT nanocomposite from aqueous solution in batch and continuous fixed bed systems, Chem. Eng. J., 346(2018), 258-270.
  38. C. Yan, C. Wang, J. Yao, L. Zhang, X. Liu, Adsorption of methylene blue on mesoporous carbons prepared using acid-and alkaline-treated zeolite X as the template, Colloids Surf. A., 333(2009), 115-119.
  39. B. Hameed, A. M. Din, A. Ahmad, Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies, J. Hazar. Mater., 141(2007), 819-825.
  40. N. M. Mahmoodi, J. Abdi, M. Taghizadeh, A. Taghizadeh, B. Hayati, A. A. Shekarchi, M. Vossoughi, Activated carbon/metal-organic framework nanocomposite: Preparation and photocatalytic dye degradation mathematical modeling from wastewater by least squares support vector machine, J. Environ. Manag., 233(2019), 660-672.
  41. T. K. Sen, S. Afroze, H. Ang, Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata, Water Air Soil Pollution, 218(2011), 499-515.
  42. M. A. M. Salleh, D. K. Mahmoud, W. A. W. A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, 280(2011), 1-13.
  43. A. Regti, M. R. Laamari, S.-E. Stiriba, M. El Haddad, Use of response factorial design for process optimization of basic dye adsorption onto activated carbon derived from Persea species, Microchem. J., 130(2017), 129-136.
  44. S. Wang, Y. Boyjoo, A. Choueib, Z. Zhu, Removal of dyes from aqueous solution using fly ash and red mud, Water Res., 39(2005), 129-138.
  45. M. A. El-Latif, A. M. Ibrahim, M. El-Kady, Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using biopolymer oak sawdust composite, J. Am. Sci., 6(2010), 267-283.
  46. T. Tarawou, M. Horsfall Jr, Adsorption of methylene blue dye on pure and carbonized water weeds, Bioremediation J., 11(2007), 77-84.
  47. S. Senthilkumaar, P. Varadarajan, K. Porkodi, C. Subbhuraam, Adsorption of methylene blue onto jute fiber carbon: kinetics and equilibrium studies, J. Colloid Interface Sci., 284(2005), 78-82.
  48. A. E. Ofomaja, Sorptive removal of Methylene blue from aqueous solution using palm kernel fibre: Effect of fibre dose, Biochem. Eng. J., 40(2008), 8-18.
  49. A. Nasrullah, H. Khan, A.S. Khan, Z. Man, N. Muhammad, M.I. Khan, N.M. Abd El-Salam, Potential biosorbent derived from Calligonum polygonoides for removal of methylene blue dye from aqueous solution, Scientific World J., 2015(2015), 32-41.
  50. A. Dada, A. Olalekan, A. Olatunya, O. Dada, Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk, IOSR. J. Appl. Chem., 3(2012), 38-45.
  51. J. Ghogomu, T. Noufame, M. Ketcha, N. Ndi, Removal of Pb (II) ions from aqueous solutions by Kaolinite and Metakaolinite materials, Methodology, 32(2012), 78-86.
  52. O. Gulnaz, A. Sahmurova, S. Kama, Removal of Reactive Red 198 from aqueous solution by Potamogeton crispus, Chem. Eng. J., 174(2011), 579-585.
  53. S. Zhu, H. Hou, Y. Xue, Retracted: Kinetic and isothermal studies of lead ion adsorption onto bentonite, Elsevier, 2008.
  54. A. Del Río, J. Fernández, J. Molina, J. Bonastre, F. Cases, Electrochemical treatment of a synthetic wastewater containing a sulphonated azo dye. Determination of naphthalenesulphonic compounds produced as main by-products, Desalination, 273(2011), 428-435.
  55. M. S. Khazravi, M. Bahmaei, M. E. Olya, M. Etezad, Application of a New Self-Cleaning Filter for Colored Wastewaters Treatment Using Laccase Enzyme Immobilized on Activated CARBON powder and fiber, Prog. Color Colorant Coat., 12(2019), 39-56.
  56. N. Caner, I. Kiran, S. Ilhan, C.F. Iscen, Isotherm and kinetic studies of Burazol Blue ED dye biosorption by dried anaerobic sludge, J. Hazar. Mater., 165(2009), 279-284.