Influence of Thickness and Number of Silver Layers in the Electrical and Optical Properties of ZnO/Ag/ZnO/Ag/ZnO ultra-Thin Films Deposited on the Glass for Low-Emissivity Applications
We report on transparent ZnO/Ag/ZnO and ZnO/Ag/ZnO/Ag/ZnO thin-films were deposited on the glass substrate by RF and DC sputtering for ZnO and Ag targets, respectively. The electrical and optical properties of the single and double Low Emissivity coatings were investigated with respect to the deposition time of Ag mid layer. The visible transmittance remains about 65% for single and 45% for double Low-E coatings as the Ag deposition time increases. Besides, the decrement of sheet resistance makes lower thermal emissivity of the coatings. In agreement with the optical performance, lower thermal emissivity can strongly increase NIR reflectance as the Ag layer thickness increases. The carrier concentration increases gradually as the sheet resistance decreases and the increase of the free carriers and conductivity of the coatings lead to a sharp rise of the NIR reflectance. The results show that the characteristics of Low-E coatings depend on both the continuity of the metal layer and the metal thickness.
M. Berginski, J. Hupkes, M. Schulte, G. Schöpe, H. Stiebig, B. Rech, M. Wuttig, The effect of front ZnO:Al surface texture and optical transparency on efficient light trapping in silicon thin-film solar cells, J. Appl. Phys., 101(2007), 1–11.
D.R. Sahu, S.Y Lin, J-L Huang, ZnO/Ag/ZnO multilayer films for the application of a very low resistance transparent electrode, Appl Surf Sci., 252(2006), 7509–7514.
E. Fortunato, D. Brida, I. Ferreira, H. Aguas, P. Nunes, R. Martins, Production and characterization of large area flexible thin film position sensitive detectors, Thin Solid Films, 383(2001), 310–313.
F.Faupel, V. Zaporojtchenko, T. Strunskus, M. Elbahri, Metal-polymer nano composites for functional applications, Adv. Eng. Mat., 12(2010), 1177-1190.
M. Rycenga, C.M. Cobley, J. Zeng, W. Li, C.H. Moran, Q. Zhang, D. Qin, Y. Xia, Controlling the synthesis and assembly of silver nanostructures for plasmonic applications, Chem. Rev., 111(2011), 3669-3712.
J. Chen, G. Qin, J. Wang, J. Yu, B. Shen, S. Li, Y. Ren, L. Zuo, W. Shen, B. Das, One-step fabrication of sub-10-nm plasmonic nanogaps for reliable SERS sensing of microorganisms, Biosens. Bioelectron., 44(2013), 191-197.
S. Chu, J. Zhao, Z. Zuo, J. Kong, L. Li, J. Liu, Enhanced output power using MgZnO/ZnO/MgZnO double hetero structure in ZnO homo junction light emitting diode, J. Appl. Phys., 109(2011), 123110.
G .Leftheriotis, P. Yianoulis, Glazing and coatings, Patras, Greece, (2012).
F. H. Hart, Low emissivity coating on transparent substrate, (1984) Patent No.US4462883.
J.M. Lemmer, Coated article with Low e coating including tin oxide interlayer, (2005) Patent No. US2005/0191502 A1.
A. Dietrich, B. Disteldorf, P. Kokot, A. Tokarz,, Coated article with Low e coating having absorbing layers for low film side reflectance and low visible transmission, (2014) Patent No. US 2014/0071524 A1.
K. W. Hartig, S. L. Larson, P. J. Lingle, Dual silver layer Low-E glass coating system and insulating glass units made there from, (1996) Patent No. US 5557462 A.
G. Leftheriotis, P. Yianoulis, D. Patrikios, Deposition and optical properties of optimized ZnS/Ag/ZnS thin films for energy saving applications, Thin Solid Films, 306(1997), 92-98.
M. Wang, J. Ji, S. Luo, L. Jiang, J. Ma, X. Xie,Y. Ping, J. Ge, Sol-gel-derived ZnO/Cu/ZnO multilayer thin films and their optical and electrical properties, Mater. Sci. Semicond. Process., 51(2016), 55–59.
A. Dhar, T. L. Alford, Optimization of Nb2O5/Ag/ Nb2O5 multilayers as transparent composite electrode on flexible substrate with high figure of merit, J. Appl. Phys., 112(2012), 103113.
G. Haacke, New figure of merit for transparent conductors, J. Appl. Phys., 47(1976), 4086–4089.
P. K. Chiu, B. H. Liou, C. N. Hsiao, J. R. Yang, D. Chiang, W. H. Cho, C. T. Lee, Investigation on optical and electrical properties of ZnO sandwich structure with metal interlayer, Jpn. J. Appl. Phys., 53(2014), 05FF05.
J. H. Kim, H. K. Lee, J. Y. Na, S. K. Kim, Y. Z. Yoo, T. Y. Seong, Dependence of optical and electrical properties on Ag thickness in TiO2/Ag/TiO2 multilayer films for photovoltaic devices, Ceram. Int., 41(2015), 8059–8063.
D.R. Sahu, J.L. Huang, Development of ZnO-based transparent conductive coatings, Sol. Energy Mater. Sol Cells, 93(2009), 1923–1927.
D. R. Sahu, J. L. Huang, Design of ZnO/Ag/ZnO multilayer transparent conductive films, Mater, Sci. Eng. B:Adv., 130(2006), 295–299.
J. H. Kim, Y. J. Moon, S. K. Kim, Y. Z. Yoo, T.Y. Seong, Al-doped ZnO/Ag/Al-doped ZnO multilayer films with a high figure of merit, Ceram. Int., 41(2015), 14805-14810.
Haratian Nezhad, E., Haratizadeh, H., & Mohammad Kari, B. (2019). Influence of Thickness and Number of Silver Layers in the Electrical and Optical Properties of ZnO/Ag/ZnO/Ag/ZnO ultra-Thin Films Deposited on the Glass for Low-Emissivity Applications. Progress in Color, Colorants and Coatings, 12(2), 83-91. doi: 10.30509/pccc.2019.81543
MLA
E. Haratian Nezhad; H. Haratizadeh; B. Mohammad Kari. "Influence of Thickness and Number of Silver Layers in the Electrical and Optical Properties of ZnO/Ag/ZnO/Ag/ZnO ultra-Thin Films Deposited on the Glass for Low-Emissivity Applications", Progress in Color, Colorants and Coatings, 12, 2, 2019, 83-91. doi: 10.30509/pccc.2019.81543
HARVARD
Haratian Nezhad, E., Haratizadeh, H., Mohammad Kari, B. (2019). 'Influence of Thickness and Number of Silver Layers in the Electrical and Optical Properties of ZnO/Ag/ZnO/Ag/ZnO ultra-Thin Films Deposited on the Glass for Low-Emissivity Applications', Progress in Color, Colorants and Coatings, 12(2), pp. 83-91. doi: 10.30509/pccc.2019.81543
VANCOUVER
Haratian Nezhad, E., Haratizadeh, H., Mohammad Kari, B. Influence of Thickness and Number of Silver Layers in the Electrical and Optical Properties of ZnO/Ag/ZnO/Ag/ZnO ultra-Thin Films Deposited on the Glass for Low-Emissivity Applications. Progress in Color, Colorants and Coatings, 2019; 12(2): 83-91. doi: 10.30509/pccc.2019.81543