Corrosion Inhibitor Release from Zn-Al-[PO43-]-[CO32-] Layered Double Hydroxide Nanoparticles


Journal: Vol.9, No.4, autumn 2016 - Article 3   Pages :  233 Until 248



Article Code:
PCCC-2016-08-19-334

Authors:
E. Alibakhshi: Institute for Color Science and Technology - Department of Surface Coating and Corrosion
E. Ghasemi: Institute for Color Science and Technology - Department of Inorganic Pigment and Glazes
M. Mahdavian: Institute for Color Science and Technology - Department of Surface Coating and Corrosion
B. Ramezanzadeh: Institute for Color Science and Technology - Department of Surface Coating and Corrosion


Article's abstract:

Zn-Al layered double hydroxide (LDH) nanoparticles with carbonate as the charge balancing anion in the interlayer space were synthesized using co-precipitation method. Then, the carbonate base Zn-Al LDH nanoparticles were doped with phosphate ion via anion-exchange reaction to synthesize Zn-Al-[PO43-]-[CO32-]. The structure and composition were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and thermal gravimetric-differential thermal analysis (TG-DTA). Inductively coupled plasma-optical emission spectrometer (ICP-OES) was employed to measure the phosphate release ability of Zn-Al-[PO43-]-[CO32-] in the 3.5 wt% NaCl solution. Results showed that zinc cation can release along with phosphate anion during ion exchange process. Then, the corrosion inhibition of phosphate anion and zinc cation on mild steel specimens was assessed by electrochemical impedance spectroscopy (EIS) and polarization. Field emission-scanning electron microscopy (FE-SEM) was used to study the surface morphology of the mild steel specimens after exposure to the test solutions. The results indicated the significant impact of zinc and phosphorus concentration in test solution on the corrosion inhibition properties. Prog. Color Colorants Coat. 9 (2016), 231-246© Institute for Color Science and Technology.


Keywords:
Layered Double Hydroxide, Ion Exchange, Phosphate, Corrosion Inhibition.

References:
1. E. Alibakhshi, E. Ghasemi, M. Mahdavian, A comparison study on corrosion behavior of zinc phosphate and potassium zinc phosphate anticorrosive pigments, J. Prog. Color Color. Coat., 5 (2012), 91–99. 2. E. Alibakhshi, E. Ghasemi, M. Mahdavian, Optimization of potassium zinc phosphate anticorrosion pigment by Taguchi experimental design, Prog. Org. Coatings., 76 (2013), 224–230. 3. M.F. Montemor, Functional and smart coatings for corrosion protection: A review of recent advances, Surf. Coatings Technol., 258 (2014), 17–37. 4. A.C. Bastos, M.G. Ferreira, A.M. Simões, Corrosion inhibition by chromate and phosphate extracts for iron substrates studied by EIS and SVET, Corros. Sci., 48 (2006) 1500–1512. 5. F. Askari, E. Ghasemi, B. Ramezanzadeh, M. Mahdavian, Synthesis and characterization of the fourth generation of zinc phosphate pigment in the presence of benzotriazole, Dye. Pigment., 124 (2016), 18–26. 6. R. Naderi, M.M. Attar, The role of zinc aluminum phosphate anticorrosive pigment in Protective Performance and cathodic disbondment of epoxy coating, Corros. Sci., 52 (2010), 1291–1296. 7. E. Alibakhshi, E. Ghasemi, M. Mahdavian, Sodium zinc phosphate as a corrosion inhibitive pigment, Prog. Org. Coatings., 77 (2014), 1155–1162. 8. E. Alibakhshi, E. Ghasemi, M. Mahdavian, Evaluation of corrosion inhibition performance of synthesized potassium zinc phosphate pigments in two different conditions during immersion time, J. Color Sci. Tech., 9 (2015), 113–123. 9. E. Alibakhshi, E. Ghasemi, M. Mahdavian, The influence of surface modification of lithium zinc phosphate pigment on corrosion inhibition of mild steel and adhesion strength of epoxy coating, J. Sol-Gel Sci. Technol., 72 (2014), 359–368. 10. E. Alibakhshi, E. Ghasemi, M. Mahdavian, Corrosion inhibition by lithium zinc phosphate pigment, Corros. Sci., 77 (2013), 222–229. 11. Y. Shao, C. Jia, G. Meng, T. Zhang, F. Wang, The role of a zinc phosphate pigment in the corrosion of scratched epoxy-coated steel, Corros. Sci., 51 (2009), 371–379. 12. M.F. Montemor, D.V. Snihirova, M.G. Taryba, S.V. Lamaka, I.A. Kartsonakis, A.C. Balaskas, et al., Evaluation of self-healing ability in protective coatings modified with combinations of layered double hydroxides and cerium molibdate nanocontainers filled with corrosion inhibitors, Electrochim. Acta., 60 (2012), 31–40. 13. A. Yabuki, K. Okumura, Self-healing coatings using superabsorbent polymers for corrosion inhibition in carbon steel, Corros. Sci., 59 (2012), 258–262. 14. M. Serdechnova, S. Kallip, M.G.S. Ferreira, M.L. Zheludkevich, Active self-healing coating for galvanically coupled multi-material assemblies, Electrochem. Commun., 41 (2014), 51–54. 15. E. Alibakhshi, E. Ghasemi, M. Mahdavian, B. Ramezanzadeh, Characterization of inhibitor release from hydrotalcite pigment, 6th Int. Color Coat. Congr., (2015). 16. J. Tedim, S.K. Poznyak, A. Kuznetsova, D. Raps, T. Hack, M.L. Zheludkevich, et al., Enhancement of active corrosion protection via combination of inhibitor-loaded nanocontainers., ACS Appl. Mater. Interfaces., 2 (2010), 1528–35. 17. M.L. Zheludkevich, J. Tedim, M.G.S. Ferreira, Smart coatings for active corrosion protection based on multi-functional micro and nanocontainers, Electrochim. Acta., 82 (2012), 314–323. 18. J.-H. Syu, J.-Y. Uan, M.-C. Lin, Z.-Y. Lin, Optically transparent Li–Al–CO3 layered double hydroxide thin films on an AZ31 Mg alloy formed by electrochemical deposition and their corrosion resistance in a dilute chloride environment, Corros. Sci., 68 (2013), 238–248. 19. J. Tedim, A. Kuznetsova, A.N. Salak, F. Montemor, D. Snihirova, M. Pilz, et al., Zn–Al layered double hydroxides as chloride nanotraps in active protective coatings, Corros. Sci., 55 (2012) 1–4. 20. T. Ishizaki, N. Kamiyama, K. Watanabe, A. Serizawa, Corrosion resistance of Mg(OH)2/Mg-Al layered double hydroxide composite film formed directly on combustion-resistant magnesium alloy AMCa602 by steam coating, Corros. Sci., 92 (2015), 76–84. 21. J. Chen, Y. Song, D. Shan, E.-H. Han, Study of the corrosion mechanism of the in situ grown Mg–Al–CO3 hydrotalcite film on AZ31 alloy, Corros. Sci., 65 (2012), 268–277. 22. S.K. Poznyak, J. Tedim, L.M. Rodrigues, A.N. Salak, M.L. Zheludkevich, L.F.P. Dick, et al., Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications., ACS Appl. Mater. Interfaces., 1 (2009), 2353–62. 23. T.T.X. Hang, T.A. Truc, N.T. Duong, N. Pebre, M.G. Olivier, Layered double hydroxides as containers of inhibitors in organic coatings for corrosion protection of carbon steel, Prog. Org. Coatings., 74 (2012), 343–348. 24. V. Shkirskiy, P. Keil, H. Hintze-Bruening, F. Leroux, P. Vialat, G. Lefèvre, et al., Factors Affecting MoO 4 2– Inhibitor Release from Zn 2 Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings, ACS Appl. Mater. Interfaces. 7 (2015) 25180–25192. 25. E. Alibakhshi, E. Ghasemi, M. Mahdavian, B. Ramezanzadeh, S. Farashi, Fabrication and Characterization of PO 4 3− Intercalated Zn-Al- Layered Double Hydroxide Nanocontainer, J. Electrochem. Soc., 163 (2016), C495–C505. 26. J. Das, B.S. Patra, N. Baliarsingh, K.M. Parida, Adsorption of phosphate by layered double hydroxides in aqueous solutions, Appl. Clay Sci., 32 (2006), 252–260. 27. M. Mamat, K. Halim, K. Bulat, M. Aidil, A. Abdullah, A. Rahman, Zinc aluminium carbonate layered double hydroxide: syntheses and characterization, J. Ultra Chem., 7 (2011), 430–435. 28. R. Frost, A. Musumeci, T. Kloprogge, M. Adebajo, M. Wayde, Raman spectroscopy of hydrotalcites with phosphate in the interlayer implications for the removal of phosphate from water. Journal of Raman Spectroscopy., 37 (2006), 733–741. 29. J. Liu, J. Song, H. Xiao, L. Zhang, Y. Qin, D. Liu, et al., Synthesis and thermal properties of ZnAl layered double hydroxide by urea hydrolysis, Powder Technol., 253 (2014), 41–45. 30. R. Anbarasan, W.D. Lee, S. Im, Adsorption and intercalation of anionic surfactants onto layered double hydroxides : XRD study, Bull. Mater. Sci., 28 (2005), 145–149. 31. P. Ding, B. Qu, Synthesis and characterization of exfoliated polystyrene/ZnAl layered double hydroxide nanocomposite via emulsion polymerization., J. Colloid Interface Sci., 291 (2005), 13–18. 32. M. Badreddine, A. Legrouri, A. Barroug, A. De Roy, J.P. Besse, Ion exchange of different phosphate ions into the zinc–aluminium–chloride layered double hydroxide, Mater. Lett., 38 (1999), 391–395. 33. A. Legrouri, M. Badreddine, A. Barroug, A. Deroy, Besse, Influence of pH on the synthesis of the Zn – Al – nitrate layered double hydroxide and the exchange of nitrate by phosphate ions, J. Mater. Sci. Lett., 8 (1999), 1077–1079. 34. S.P. V Mahajanam, R.G. Buchheit, Characterization of inhibitor release from Zn-Al- [ V10 O28 ] 6– hydrotalcite pigments and corrosion protection from hydrotalcite pigmented epoxy coatings, Corrosion., 64 (2008), 230–240. 35. M. a. Woo, T.W. Kim, M.J. Paek, H.W. Ha, J.H. Choy, S.J. Hwang, Phosphate-intercalated Ca–Fe-layered double hydroxides: Crystal structure, bonding character, and release kinetics of phosphate, J. Solid State Chem., 184 (2011), 171–176. 36. M.L. Zheludkevich, S.K. Poznyak, L.M. Rodrigues, D. Raps, T. Hack, L.F. Dick, et al., Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor, Corros. Sci., 52 (2010), 602–611. 37. B. Hirschorn, M.E. Orazem, B. Tribollet, V. Vivier, I. Frateur, M. Musiani, Determination of effective capacitance and film thickness from constant-phase-element parameters, Electrochim. Acta., 55 (2010), 6218–6227. 38. F. Simescu, H. Idrissi, Effect of zinc phosphate chemical conversion coating on corrosion behaviour of mild steel in alkaline medium: protection of rebars in reinforced concrete, Sci. Technol. Adv. Mater., 9 (2008), 045009. 39. M. Zubielewicz, W. Gnot, Mechanisms of non-toxic anticorrosive pigments in organic waterborne coatings, Prog. Org. Coatings., 49 (2004), 358–371. 40. M. Mahdavian, R. Naderi, Corrosion inhibition of mild steel in sodium chloride solution by some zinc complexes, Corros. Sci., 53 (2011), 1194–1200.


Article's file
Page view: 1420
Article's download quantity : 44


Article System Login
Introduction

Manager-in-Chief:
Prof. Zahra Ranjbar
Editor-in-Chief:
Dr. Farahnaz Nourmohammadian
Assistant Editor:
Dr. Mozhgan Hosseinnezhad
ISSN:
2008-2134
ISSN (online):
2383-1790
Publisher:
Institute for Color Science and Technology (ICST)

Quick Access
Publications
E-Vote
What is your opinion about the manuscript subscription system of PCCC website?
Excellent
Good
Fair
Poor
Website Statistics
Page view:1,421
Online Visitors:13