Effect of Fluorination Treatment on Cotton Wettability, Dyeability and Mechanical Properties and Characterization of Surface Changes by XPS

Journal: Vol.7, No.2, Spring 2014 - Article 2   Pages :   Until 

Article Code:

Shahla Shekarriz: Amirkabir University of Technology - Color and Polymer Research Centre
Zahra Shariatinia: Amirkabir University of Technology - Chemistry Department

Article's abstract:

Cotton fabric was treated with fluorine gas in a nitrogen atmosphere. The effect of fluorination treatments on wettability, whiteness index, dyeability and mechanical properties of cotton fabrics were assessed. Kawabata analysis shows that fluorination treatment increases shear stiffness G, shear hysteresis 2HG5, bending stiffness B and overall fabric stiffness Koshi on cotton fabric. Fluorination increases hydrophilicity of cotton by reducing the wetting time to less than 10 seconds for fluorinated cotton. In addition, the uniformity of wetting improves for the fluorinated samples. Fluorinated cotton dyed with two different direct dyes shows a slightly decreased exhaustion rate and colour yield. X-ray Photoelectron Spectroscopy XPS was used to characterize untreated and fluorinated cotton. XPS indicates that oxidation, fluorination and formation bonds - COO and –CHF at 289.5eV occurred on the fluorinated cotton surface.

fluorination Treatment; direct dyes; cotton; x-ray photoelectron spectroscopy; wettability; Kawabata analysis; dyeability

1. M. Ueda, S. Tokino, Physico-chemical modifications of fibers and their effect on coloration and finishing, Rev. Prog. Color. Relat. Top., 26(1996), 9-19.#2. S. Perincek, I. Bahtiyari, A. Korlu, K. Duran, New techniques in cotton finishing, Text. Res. J., 79(2009), 121-128.#3. J. P. Hobbs, P. B. Henderson, M. R. Pascolini, Assisted permeation through surface fluorinated polymers, J. Fluorine Chem., 104(2000), 87-95.#4. P. A. B. Carstens, S. A. Marais, C. J. Thompson, Improved and novel surface fluorinated products, J. Fluorine Chem., 104(2000), 97-107.#5. J. Maity, P. Kothary, E. A. O’Rear, C. Jacob, Preparation and comparison of hydrophobic cotton fabric obtained by direct fluorination and admicellar polymerization of fluoromonomers, Ind. Eng. Chem. Res., 49(2010), 6075-6079.#6. K. J. Dodd, C. M. Carr, B. Kidd, K. Byrne, Fluorination-a novel pretreatment for wool to impart shrink resistance, J. Soc. Dyers Color., 111(1995), 63-66.#7. B. M. Mueller, Adsorbable organic halogens in textile effluents, Rev.Prog. Coloration, 22(1992), 14-21.#8. E. Finnimore, Instrumental assessment of fabric softness, part 1 correlation of instrumental measurement and manual assessment, Melliand Textilber., 67(1986), 514-516.#9. C. D. Wagner, Sensitivity of detection of the elements by photoelectron spectrometry, Anal. Chem., 44(1972), 1050-1053.#10. K. Siegbahn, C. Nordling, A. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johnansson, R. Bergmark, S. E. Karlson, I. Lindgren, B. Lindberg, Atomic molecular and solid-state structure studied by means of electron spectroscopy, Nova Acta Regiae Soc. Sci. Ups., 20(1967), 208-282.#11. S. Shekarriz, P. Cohen, C. M. Carr, R. Mictchell, C. Jones, Surface chemical analysis of 1,2,3,4 butane tetracarboxyic acid modified cotton, J. Mater. Sci., 38(2003), 2945-2951.#12. Technical data: Solophenyl dyes, dyeing methods, CIBA-GIEGY.#13. S. Gorji Kandi, F. Ameri, N. Khalili, Instrument dependency of Kubelka-Munk theory in computer color matching, Prog. Color Colorants Coat., 5(2012), 85-90.#14. W. J. Thorsen, Temporary and permanent fiber-friction increases induced by corona treatment, Text. Res. J., 41(1971), 331-336.#15. A. E. Pavlath, K. S. Lee, Pretreatment of textiles under plasma conditions, Proc 5th Int Wool Text. Res. Conf. Aachen, 3(1975), 263.#16. J. Verschuren, P. Kiekens, C. Leys, Textile-specific properties that influence plasma treatment, effect creation and effect characterization, Text. Res. J., 77(2007), 727-733.#17. W. J. Thorsen, Modification of the cuticle and primary wall of cotton by corona treatment, Text. Res. J., 6(1974), 422-429.#18. J. Shao, Surface modification of wool by novel dry finishing to impart shrink resistance, improved dyeability and printability, PhD Thesis, UMIST, 1998.#19. T. Wakida, M. Lee, Y. Sato, S. Ogasawara, S. Niu, Dyeing properties of oxygen low-temperature plasma-treated wool and nylon 6 fibers with acid and basic dyes, J. Soc. Dyers Color., 112(1996), 233-236.#20. L. J. Hayes, D. D. Dixon, Direct fluorination of polyamide, J. Fluorine Chem., 10(1977), 17-28.#21. K. J. Dodd, C. M. Carr, B. Kidd, K. Byrne, Fluorination-a novel pretreatment for wool to impart shrink resistance, J. Soc. Dyers Color., 111(1995), 63-66.#22. L. J. Hayes, D D. Dixon, Direct fluorination of polyamide, J. Fluorine Chem., 10(1977), 17-28.#23. L. J. Hayes, D. D. Dixon, Direct fluorination of polyester and related compounds, J. Fluorine Chem., 10(1977), 1-16.#24. A. P. Kharitonov, G. V. Simbirtseva, V. M. Bouznik, M. G. Chepezubov, M. Dubois, K. Guerin, A. Hamwi, H. Kharbache, F. Masin, Modification of ultra-high-molecular weight polyethylene by various fluorinating routes, J. Polym. Sci., part A: polymer chemistry, 49(2011), 3559-3573.

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