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Gholamhosseinzadeh, M., Farrahi-Moghaddam, R. (2019). Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel. Progress in Color, Colorants and Coatings, 12(1), 15-23.
M.R. Gholamhosseinzadeh; R. Farrahi-Moghaddam. "Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel". Progress in Color, Colorants and Coatings, 12, 1, 2019, 15-23.
Gholamhosseinzadeh, M., Farrahi-Moghaddam, R. (2019). 'Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel', Progress in Color, Colorants and Coatings, 12(1), pp. 15-23.
Gholamhosseinzadeh, M., Farrahi-Moghaddam, R. Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel. Progress in Color, Colorants and Coatings, 2019; 12(1): 15-23.

Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel

Article 2, Volume 12, Issue 1, Winter 2019, Page 15-23  XML PDF (778.63 K)
Authors
M.R. Gholamhosseinzadeh* 1, 2; R. Farrahi-Moghaddam3
1Department of Chemistry, Kerman Branch, Islamic Azad University, P.O. Box: 7635131167, Kerman, Iran
2Young Researchers and Elite Club, Kerman Branch, Islamic Azad University, P.O. Box: 7635131167, Kerman, Iran.
3Department of Chemistry, Kerman Branch, Islamic Azad University, P.O. Box: 7635131167, Kerman, Iran.
Abstract
In this paper, the effect of penicillin G benzathine (PGB) drug as a green corrosion inhibitor on mild steel in 1.0 M hydrochloric acid solution has been investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency (IE) was found to increase with increasing inhibitor concentration. Potentiodynamic polarization measurements indicated that PGB is a mixed type inhibitor. The results of potentiodynamic polarization and EIS measurements demonstrated that the adsorption of PGB on mild steel in 1.0 M HCl follows Langmuir isotherm. The calculated values of free energy indicated that both physical and chemical adsorption take place. The IE values obtained from EIS measurements show a reasonable agreement with those obtained from potentiodynamic polarization method.
Keywords
Penicillin G benzathine; Inhibition Efficiency; Potentiodynamic Polarization; Electrochemical Impedance Spectroscopy
References
  1. M. Mahdavian, M. M. Attar, Electrochemical assessment of Imidazole derivatives as corrosion inhibitors for mild steel in 3.5% NaCl solution, Prog. Color Colorants Coat., 8(2015), 177-196.
  2. M. M. Saleh, Inhibition of mild steel corrosion by hexadecylpyridinium bromide in 0.5 M H2SO4, Mater. Chem. Phys., 98(2006), 83-89.
  3. A. Mohammadi, S. M. A. Hosseini, M. J. Bahrami, M. Shahidi, Corrosion inhibition of mild steel in acidic solution by apricot gum as a green inhibitor, Prog. Color Colorants Coat., 9(2016), 117-134.
  4. I. Ahamad, M. A. Quraishi, Mebendazole: New and efficient corrosion inhibitor for mild steel in acid medium, Corros. Sci., 52(2010), 651-656.
  5. A. S. Fouda, H. M. El-Abbasy, Inhibitive Action of ampicillin and benzyl penicillin drugs for corrosion of type 304 stainless steel in 1 M HCl solution, Corrosion, 68(2012), 1-9.
  6. G. Gece, Review, Drugs: A review of promising novel corrosion inhibitors, Corros. Sci., 53(2011), 3873-3898.
  7. Y. Liang, C. Wang, J. Li, L. Wang, J. Fu, The Penicillin derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution: experimental and theoretical studies, Int. J. Electrochem. Sci., 10(2015), 8072-8086.
  8. G. Golestani, M. Shahidi, D. Ghazanfari, Electrochemical evaluation of antibacterial drugs as environment-friendly inhibitors for corrosion of carbon steel in HCl solution, Appl. Surf. Sci., 308(2014), 347-362.
  9. F. Soltaninejad, M. Shahidi, Investigating the effect of penicillin G as environment-friendly corrosion inhibitor for mild steel in H3PO4 solution, Prog. Color Colorants Coat., 11(2018), 137-147.
  10. P. Singh, D. S. Chauhan, K. Srivastava, V. Srivastava, M. A. Quraishi, Expired atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution, Int. J. Industrial Chem. (2017).
  11. M. Srivastava, P. Tiwari, S. K. Srivastava, R. Prakash, G. Ji, Electrochemical investigation of Irbesartan drug molecules as an inhibitor of mild steel corrosion in 1M HCl and 0.5 M H2SO4 solutions, J. Mol. Liq., 236 (2017), 184-197.
  12. P. Singh, D. S. Chauhan, K. Srivastava, V. Srivastava, M. A. Quraishi, Expired atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution, Int. J. Industrial Chem. (2017).
  13. H. K. S, D. S. Karthikeyan, Inhibition of mild steel corrosion in hydrochloric acid solution by cloxacillin drug, 2012.
  14. K. Raja, P. A. Jeeva, D. S. Karthikeyan, Reduction of hydrogen embrittlement and green inhibition of stainless steel pipes in acid environment, International J. ChemTech Res. 7(2015), 2425-2431.
  15. I. Ahamad, R. Prasad, M. A. Quraishi, Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions, Corros. Sci., 52(2010), 933-942.
  16. S. Hari Kumar, S. Karthikeyan, Torsemide and Furosemide as Green Inhibitors for the Corrosion of Mild Steel in Hydrochloric Acid Medium, Indust. Eng. Chem. Res. 52(2013), 7457-7469.
  17. G. Achary, Y. A. Naik, S. V. Kumar, T. V. Venkatesha, B. S. Sherigara, An electroactive co-polymer as corrosion inhibitor for steel in sulphuric acid medium, Appl. Surf. Sci., 254(2008), 5569-5573.
  18. M. G. Hosseini, M. Ehteshamzadeh, T. Shahrabi, Protection of mild steel corrosion with Schiff bases in 0.5M H2SO4 solution, Electrochim. Acta, 52(2007), 3680-3685.
  19. D. A. Lopez, S. N. Simison, S. R. d. Sanchez, The influence of steel microstructure on CO2 corrosion. EIS studies on the inhibition efficiency of benzimidazole, Electrochim. Acta, 48(2003), 845-854.
  20. F. Bentiss, M. Lebrini, M. Lagrenee, Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in mild steel/ 2,5-bis(n-thienyl)-1,3,4-thiadiazoles/hydrochloric acid system, Corros. Sci., 47(2005), 2915-2931.
  21. E. A. Noor, A. H. Al-Moubaraki, Thermodynamic study of metal corrosion and inhibitor adsorption processes in mild steel/1-methyl-4[4 (-X)-styryl pyridinium iodides/hydrochloric acid systems, Mater. Chem. Phys., 110(2008), 145-154.

 

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