Synthesis and Characterization of Indoline-based organic sensitizers for photoelectrochemical cells


Journal: Vol.10, No.1, Winter 2017 - Article 6   Pages :  43 Until 50



Article Code:
PCCC-2016-11-01-344

Authors:
M. Hosseinnezhad: Institute of Color Science and Technology - Department for Organic Colorants
S. Moradian: Amirkabir University of Technology - Faculty of Polymer and Color Engineering
K. Gharanjig: Institute for Color Science and Technology - Department of Organic Colorants


Article's abstract:

In this paper we designed and prepared three free-metal organic days Dye 1, Dye 2 and Dye 3 based on indoline with n-phenly substituents iminodibenzyl as the electron donor group. We used cyanoacrylic acid substituent as the electron acceptor anchoring group in organic dyes. The proposed dyes were prepared from iminodibenzyl as the starting material by standard reactions and characterized by different techniques such as melting point, FT-IR, 1HNMR, elemental analysis and UV-Visible spectroscopy after purification. Spectrophotometric measurements of the organic dyes in solution and on a photoanode substrate were carried out in order to assess changes in the status of the dyes. The wavelength of maximum absorption for Dye 1 to Dye 3 in solution are 416 nm, 421 nm and 409 nm and on photoanode substrate are 437 nm, 440 nm and 421 nm, respectively. Finally, the proposed dyes used as sensitizer in a photoelectrochemical cell structure and their photovoltaic properties investigated. The Conversion efficiency for Dye 1 to Dye 3 are 2.84 and 3.11 and 2.12, respectively.


Keywords:
Indoline, Dye-sensitized solar cells, Organic dyes, optical materials, Conversion efficiencies.

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