Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
08
19
Synthesis and Characterization of a Nonionic Urethane-Based Thickener
71
77
EN
F.
Najafi
Departments of Resin and Additives, Institute for Color Science and Technology
fnajafi@icrc.ac.ir
M.
Pishvaei
Departments of Resin and Additives, Institute for Color Science and Technology
pishvaei@icrc.ac.ir
10.30509/pccc.2011.75782
Hydrophobically modified ethoxylated urethanes have been synthesized using polyethylene glycol, hexamethylene diisocyanate and cetyl alcohol. These types of thickeners are categorized as nonionic associative thickeners. The HEURs were prepared in two steps. Initially an ethoxylated urethane prepolymer was synthesized through a reaction between a polyethylene glycol (Mn=6000) and hexamethylene diisocyanate using the step growth polymerization technique, then modification was carried out by reaction of cetyl alcohol with the obtained prepolymer. HEURs were characterized using 1H NMR, FTIR and GPC techniques. The rheological properties of incorporated samples in different media proved the considerable thickening efficiency of the produced HEUR.
Associative thickeners,HEUR,Rheology modifier,Step growth polymerization,Viscosity
https://pccc.icrc.ac.ir/article_75782.html
https://pccc.icrc.ac.ir/article_75782_6a267c45cb6b2ef0d5cb7bc4a5cc0aa1.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
08
01
Water Fast of Inkjet Print by Using Acrylic /Nano-Silver Ink
79
83
EN
A.
Soleimani-Gorgani
Department of Printing Science and Technology, Institute for Color Science and Technology
asoleimani@icrc.ac.ir
M.
Pishvaei
Departments of Resin and Additives, Institute for Color Science and Technology
pishvaei@icrc.ac.ir
10.30509/pccc.2011.75783
A colour ink jet printing with improved water fastness property was produced by using of special component in the ink’s formulation. In this study, the water fastness of ink jet prints which used acrylic/nano-silver resin nano-composite ink instead of conventional resin in ink’s formulation was examined. The nano composite resin was prepared via miniemulsion polymerization of acrylate monomers in the presence of silver nanoparticles. The water fastness properties of the prints were assessed by using the ASTM /F2292-03 water fastness test. The results indicated that acrylic/nano-silver resin increased impermeability of the printed paper and provided the water insoluble printed image on the paper. Also by adding acrylic/nano-silver resin, the hue of printed image was darker than conventional resin.
Nano,Silver,Ink jet,Printing,Acrylic,Water fastness,paper
https://pccc.icrc.ac.ir/article_75783.html
https://pccc.icrc.ac.ir/article_75783_941a09418fbe8f9c884fa349f530253e.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
11
06
Effect of various fuels on structure and photo-catalytic activity of TiO2 nano-crystalline prepared by microwave-assisted combustion method
85
94
EN
F.
Oshani
Department of Inorganic Pigment and Glazes, Institute for Color Science and Technology
oshani10@gmail.com
S. M.
Hashemi
Young Research Club, Islamic Azad University, Shahr-e-Ray Branch
shashemi33@gmail.com
10.30509/pccc.2011.75784
Nano-crystalline TiO2 were synthesized by combustion method using metal nitrate solution and urea, glycin and citric acid fuels. Microwave irradiation was used as heating source. X-ray diffraction, scanning electron microscope as well as Fourier transform infrared spectroscopy were performed to characterize the obtained samples. X-ray diffraction patterns revealed that in the case of citric acid a calcination step was needed to obtain the desired phases. Moreover, the ratio of rutile/anatase phases varied from 25/75 to 0/100 as the fuel type changes from urea to glycine and citric acid. The crystallite size of the as-synthesized samples calculated by Scherer formula was 8-15 nm. From scanning microscopy images thick and thin flaky particles were detected for citric acid and urea samples and porous spongy morphology for glycine sample. Due to a well-crystallized mixed crystalline structure 75 anatase - 25 rutile, the urea sample seemed to be a better candidate for photo-catalytic functions.
Nano,crystalline TiO2,Combustion,fuel type,photo,Catalytic activity
https://pccc.icrc.ac.ir/article_75784.html
https://pccc.icrc.ac.ir/article_75784_79b6268407a7f66789915571e0fcb11e.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
12
08
Representing Spectral data using LabPQR color space in comparison to PCA method
95
106
EN
S.
Gorji Kandi
Polymer Engineering and Color Technology Departmen, Amirkabir University of Technology
s.gorji@aut.ac.ir
10.30509/pccc.2011.75781
In many applications of color technology such as spectral color reproduction it is of interest to represent the spectral data with lower dimensions than spectral space’s dimensions. It is more than half of a century that Principal Component Analysis PCA method has been applied to find the number of independent basis vectors of spectral dataset and representing spectral reflectance with lower dimensions. Recently, a new Interim Connection Space ICS named LabPQR was introduced, which contains three colorimetric dimensions and additional black metamer space. In the present study, the performance of PCA method in comparison to LabPQR was investigated for representation of spectral reflectance. For this end, different color datasets including Munsell, Glossy Munsell, GretagMacbethColorChecker, Esser test chart and two printing datasets were evaluated. The results show that, the performance of PCA and LabPQR, depends on the applied dataset. Based on spectral metrics such as RMS and GFC values, PCA has better results than LabPQR. Considering color difference errors, LabPQR is a better space even based on the color difference under second illuminant. Moreover, the used dataset for obtaining PQR vectors affects the representation results. For some datasets, the PQR components of the other sets perform better. However, obtaining PQR bases from the same data source, gives better results. Comparing Cohen and Kappauf based and unconstrained LabPQR methods showed that Cohen and Kappauf-based performs better for all the datasets.
Principal component analysis,LabPQR,spectral representation,metameric black
https://pccc.icrc.ac.ir/article_75781.html
https://pccc.icrc.ac.ir/article_75781_13d43b2117b49b40dc10b3006243da7e.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
12
01
A Kinetic study on the dissolution of two naphthalimide based synthesized disperse dyestuffs in the presence of dispersing agents
107
112
EN
A.
Khosravi
Department of Polymer Engineering and Color Technology , Amirkabir University of Technology
a.khosravi@aut.ac.ir
K.
Gharanjig
0000-0002-0115-3557
Center of Excellence for Color Science and Technology,Department of Organic Colorants, Institute for Color Science and Technology
gharanjig@icrc.ac.ir
S.
Moradian
Faculty of Polymer and Color Engineering,Amirkabir University of Technology, Center of Excellence for Color Science and Technology,Institute for Color Science and Technology
moradian@aut.ac.ir
M.
Hosseinnezhad
0000-0003-3351-0157
Center of Excellence for Color Science and Technology,Department of Organic Colorants, Institute for Color Science and Technology
hosseinnezhad-mo@icrc.ac.ir
10.30509/pccc.2011.75785
The controlling kinetics of the water solubility of two synthesized mono azo naphthalimide based disperse dyestuffs in the presence of two different dispersing agents namely Irgasol DAM and lyoprint EV agents at various temperatures were investigated. An exponential rate equation was found to describe the dissolution process. The addition of Irgasol DAM and Lyoprint EV dispersing agents increased the rate of the dissolution of both synthesized dyestuffs. The dissolution of the methyl naphthalimide derived dyestuff in water as expected was more than the propylnaphthalimide derivative. The depth of dyeing and the leveling properties were also higher for the methyl derivative than the propyl derivative.
Disperse dyestuffs,Dispersing agents,Dissolution Kinetics,Naphthalimide,Solubility
https://pccc.icrc.ac.ir/article_75785.html
https://pccc.icrc.ac.ir/article_75785_bea2573b98e47a52a41f842dde97d064.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
12
12
Design and synthesis of new symmetrical Schiff bases
113
120
EN
N.
Mahmoodi
Department of Chemistry, University of Guilan
mahmoodi@guilan.ac.ir
N.
Naseri
Department of Chemistry, University of Guilan
nahidnaseri45@yahoo.com
E.
Asadollahi
Department of Chemistry, University of Guilan
elham.asadollahi@yahoo.com
B.
Ghalami Choobar
Department of Chemistry, University of Guilan
R.
H. Sajedi
Department of Biology, University of Guilan
sajedi-r@guilan.ac.ir
10.30509/pccc.2011.75787
A series of symmetric multidentate Schiff base ligands 1–13 based on the N‚N′-4‚4′-ethylenebiphenylbis-3-methoxysalicylideneimine for used to bind various transition metals detection of K, AgI‚ CuII, Sr II Co II and NiII at trace levels in real-world samples has been synthesized purified and their structures was characterized.
Symmetrical Schiff base,N‚N′,(4‚4′,ethylenebiphenyl)bis,3,methoxysalicylideneimine,Electrochemical sensors
https://pccc.icrc.ac.ir/article_75787.html
https://pccc.icrc.ac.ir/article_75787_99b4f050796af8d53f24a7ada08891bc.pdf
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
4
2
2011
12
12
Aggregation of an anionic azo dye with conventional cationic surfactants in premicellar region: A conductometric study
121
128
EN
S.
Javadian Farzaneh
Department of Physical Chemistry, Tarbiat Modares University
javadian_s@modares.ac.ir
F.
Hooshmand
Department of Physical Chemistry, Payame Noor University, Urmiah Branch
f_hooshmand@yahoo.com
A.
Asadzadeh Shahir
Department of Physical Chemistry, Tarbiat Modares University
savalan_366@yahoo.com
10.30509/pccc.2011.75786
The interaction of Congo Red CR with a series of Alkyltrimethylamoniumbromide CnTAB, N-hexadecylpyridinium bromide CPB and N-hexadecylpyridinium CPC were investigated using conductometry technique. It was observed that the formation of dye-surfactant ion pairs takes place at surfactant concentration far below the critical micelle concentration of the individual surfactants. Aggregation was reflected by the appearance of a break point at conductometry plots. The equilibrium constant and other thermodynamic parameters for the ion pair formation were calculated on the basis of a theoretical model using the data obtained by conductometry. The reaction between dye and surfactants was revealed to be an enthalpy-driven reaction which is highly dependent on temperature and the structures of both dye and surfactant.
Congo red,cationic surfactant,Dye,surfactant ion pair,Conductometry,Equilibrium constant
https://pccc.icrc.ac.ir/article_75786.html
https://pccc.icrc.ac.ir/article_75786_a57bfd698091ab7076d1da5517ee53dc.pdf