ORIGINAL_ARTICLE
Tranexamic Acid as Novel Corrosion Inhibitor for X60 Steel in Oil Well Acidizing Fluids: Surface Morphology, Gravimetric and Electrochemical Studies
The corrosion inhibition of API 5L X60 pipeline steel in oil well acidizing fluid stimulated with 1.0 M HCl by Tranexamic Acid (TXA) was investigated using potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS) and the conventional gravimetric or weight loss (WL) techniques at temperatures ranging from 303 to 323 K. Surface morphological analysis was carried out using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDX). The compound showed high inhibition activity with 98.9% inhibition efficiency at 3.0 g/L concentration of TXA. Polarization analysis indicates that TXA acts as mixed-type inhibitor. The observed decrease in double layer capacitance and an increase in charge transfer resistance obtained from EIS analysis confirmed that TXA performed well as a corrosion inhibitor for X60 steel in 1.0 M HCl medium, ascribed to the adsorption of Tranexamic Acid molecules onto the X60 steel surface. Weight loss analysis showed that inhibition efficiency is increased with the increase of TXA concentration and exposure time while decreased with temperature rise. The adsorption of TXA onto the surface of the X60 steel obeys Langmuir adsorption isotherm. SEM-EDX analysis affirmed the formation of protective adsorbed film of Tranexamic Acid onto the steel surface.
https://pccc.icrc.ac.ir/article_81663_0b1acc052de09d9f8c8de8d6809e9bf1.pdf
2021-02-01
1
11
10.30509/pccc.2021.81663
Inhibition
X60 pipeline steel
Tranexamic acid
Surface morphology
Langmuir adsorption isotherm
N. B.
Iroha
irohanb@fuotuoke.edu.ng
1
Electrochemistry and Material Science Unit, Department of Chemistry, Federal University, Otuoke, Bayelsa State, Nigeria
LEAD_AUTHOR
L. A.
Nnanna
lebennanna@yahoo.com
2
Department of Physics, Michael Okpara University of Agriculture, Umudike, Abia State, Nigeria
AUTHOR
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41
ORIGINAL_ARTICLE
DFT Study of Aromatization on Azo-Linked Cyclopentadienides
he aromatic behavior of the azo-linked cyclopentadienide derivatives have been revealed in various natural compounds. In Tthis research, density functional theory (DFT) calculations at the B3LYP level are used to optimize the geometry of the compounds. In addition, we were interested in the evaluation of the aromaticity of the selected compounds using nucleus independent chemical shifts NICS (0), NICS (0.5), NICS (1), NICS (1.5) and NICS (2), bond lengths and bond angles.
https://pccc.icrc.ac.ir/article_81672_b546de5140220efd1132e3ae49491919.pdf
2021-02-01
13
26
10.30509/pccc.2021.81672
Cyclopentadienide
DFT
Nucleus independent chemical shift
Aromaticity
M.
Moayeri
m.moayeri@yahoo.com
1
Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran.
AUTHOR
M.
Nikpassand
nikpassand@iaurasht.ac.ir
2
Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran.
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21
ORIGINAL_ARTICLE
Morphological, Color Impact and Spectroscopic Studies of New Schiff Base Derived From 1,2,4-Triazole Ring
This paper investigates the synthesis of novel Schiff base having 1,2,4-triazole segment and its mixture with low concentrations of polystyrene to make a homogenous matrix. The EDX (energy dispersive X-ray) technique have shown that the major component for both blank and blend polystyrene films is carbon atom. However, it has been demonstrated the appearance of new band related to oxygen, nitrogen, and sulfur for polystyrene/base blend film. This is because of the presence of Schiff base within the polymeric film. The morphological images, after irradiation by UV light, for polystyrene (blank) film proved the formation of cotton-like fibrous material. Micrographs showed the formation of crescent-like material after the irradiation of polystyrene-Schiff base film by UV light for 300 h. This was due to the existence of polystyrene-Schiff base with polystyrene which increased the photo stability of the polymeric film.
https://pccc.icrc.ac.ir/article_81664_661e2cb3f80b9bd5fb3ac00f2bc629af.pdf
2021-02-01
27
34
10.30509/pccc.2021.81664
Polystyrene film
1
2
4-triazole
irradiation
EDX
cotton-like
A. A.
Ahmed
ahmedahmedalazawi@gmail.com
1
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq
AUTHOR
M. H.
Al-mashhadani
mo_chemical@yahoo.com
2
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq
LEAD_AUTHOR
H.
Hashim
hassan.albattat@gmail.com
3
Department of Physics, College of Science, Al-Nahrain University, Baghdad, Iraq
AUTHOR
D. S.
Ahmed
dinasaadi86@gmail.com
4
Department of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad, Iraq
AUTHOR
E.
Yousif
emad_yousif@hotmail.com
5
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq
LEAD_AUTHOR
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30
ORIGINAL_ARTICLE
Green Dyeing of Woolen Yarns with weld and Madder natural Dyes in the Presences of Biomordant
Nowadays, using sustainable dyeing process has become a necessity, but does not meet performance requirements. Application of biomordants was recommended to enhance the quality of dyeing. In order to design a green dyeing process, oak extract as bio-mordants and madder and weld luteola as natural dyes were used. The FTIR-ATR spectra of the washed wool yarn, mordanted wool yarn and mordanted dyed wool yarns confirmed bonding of wool yarns to the green mordant and dyes through a comparing chemical structure. The effective linkage between yarn, mordant and dye molecules removes the C-N peaks in FTIR-ATR spectra. After dyeing process, fastness and colorimetric attributes of dyed wool yarns were investigated. The K/S values of dyed wool yarns with extracted madder and weld luteola was quantified; properties including light, wash, and rubbing fastnesses were defined as per ISO standard methods.
https://pccc.icrc.ac.ir/article_81678_07b017915d50e2b54996419e4a4d8e8e.pdf
2021-02-01
35
45
10.30509/pccc.2021.81678
Bio-mordant
Green Dyeing
Oak
wool
Colorimetric properties
M.
Hosseinnezhad
hosseinnezhad-mo@icrc.ac.ir
1
Department of Organic Colorants, Institute for Color Science and Technology, Tehran, Iran
LEAD_AUTHOR
K.
Gharanjig
gharanjig@icrc.ac.ir
2
Department of Organic Colorants, Institute for Color Science and Technology, Tehran, Iran
AUTHOR
R.
Jafari
jafari-ra@icrc.ac.ir
3
Department of Color Physics, Institute for Color Science and Technology, Tehran, Iran
AUTHOR
H.
Imani
imani@yahoo.com
4
Tehran University of Art, Department of Carpet, Tehran, Iran
AUTHOR
L. J. Rather, S. Ul-Islam, M. Shabbir, M. N. Bukhari, F. Mohammad, M. A. Khan, Adhatodavasica in conjunction with binary combinations of metal salts and biomordants as an effective textile dye to produce novel shades on wool, J. Nat. Fibers, 15(2018), 611-623.
1
L. J. Rather, S. Ul-Islam, M. Shabbir, M. N. Bukhari, M. Shahid, M. A. Khan, F. Mohammad, Ecological dyeing of woolen yarn with adhatodavasica natural dye in the presence of biomordants as an alternative copartner to metal mordants, J. Environ. Chem. Eng., 4(2016), 3041-3049.
2
M. Hosseinnezhad, K. Gharanjig, S. Belbasi, S. H. SeiedSaadati, Green dyeing of silk fabrics in the presence of pomegranate extract as natural mordant, Prog. Color Colorants Coat., 10(2017), 129-133.
3
S. Islam, F. Mohammad, Natural colorants in the presence of anchors so-called mordants as promising coloring and antimicrobial agents for textile materials, ACS Sustain. Chem. Eng., 3(2015), 2361–75.
4
M. Hosseinnezhad, K. Gharanjig, S. Belbasi, S. H. SeiedSaadati, M.R. Saeb, The use of sumac as a natural mordant in green production of Iranian carpet, Fiber Polym., 19(2018), 1908-1912.
5
M. Yusuf, A. Ahmed, M. Shahid, M. I. Khan, S. A. Khan, N. Manzoor, F. Mohammad, Assessment of colorimetric antibacterial and antifungal properties of woolen yarn dyed with the extract of leaves of henna (lawsoniainermis), J. Clean Prod., 27(2014), 42-50.
6
L. Chakrabory, P. Pandit, S. R. Maulik, Acacia auriculiformis-a natural dye used for simultaneous coloration and functional finishing on textiles, J. Cleaner. Prod., accepted manuscript, 2019, https://doi.org/10.1016/j.jclepro.2019.118921.
7
Y. Yin, J. Jia, T. Wang, C. Wang, Optimization of natural anthocyanin efficient extracting from purple sweet potato for silk fabric dyeing, J. Cleaner Prod., 149(2017), 673-679.
8
N.F. Ali, R.S.R. El-Mohamedy, Eco-friendly and protective natural dye from red prickly pear (OpuntiaLasiacantha Pfeiffer) plant, J. Saudi Chem., 15(2011), 257-261.
9
K. H. Prabhu, M. D. Teli, N. G. Waghmare, Eco-Friendly Dyeing Using Natural Mordant Extracted from Emblicaofficinalis G. Fruit on Cotton and Silk Fabrics with Antibacterial Activity, Fiber Polym., 12(2011), 753-759.
10
S. Adeel, M. Salman, S. A. Bukhari, K. Kareem, F. Rehman, A. Hassan, M. Zuber, Eco-friendly food products as source of natural colorant for wool yarn dyeing, J. Nat. Fiber., doi.org/10.1080/15440478.2018.1521762, 2018.
11
K. M. Zia, S. Adeel, F. Rehman, H. Aslam, M. K. Khosa, M. Zuber, Influence of ultrasonic radiation on extraction and green dyeing of mordanted cotton using neem bark extract, J. Indust. Eng. Chem., 77(2019), 317-322.
12
A. Haji, M. Nasiriboroumand, S. S. Qavamnia, Cotton Dyeing and Antibacterial Finishing Using Agricultural Waste by an Eco-friendly Process Optimized by Response Surface Methodology, Fiber Polym., 19(2018), 2359-2364.
13
M. Zuber, S. Adeel, F. Rehman, M. A. Bdullah, K. M. Zia, Influence of microwave radiation on dyeing of bio-mordanted silk fabric using neem bark (azadirachtaindica)-based tannin natural dye, J. Nat. Fiber., doi.org/10.1080/15440478.2019.1576569, 2019.
14
S. Adeel, K. M. Zia, M. Abdullah, F. Rehman, M. Salman, M. Zuber, Ultrasonic assisted improved extraction and dyeing of mordanted silk fabric using neem bark as source of natural colourant, J. Nat. Proud. Res., 33(2019), 2060-2072.
15
S. Adeel, F. Rehman, M. U. Iqbal, N, Habib, S. Kiran, M. Zuber, K.M. Zia, A. Hameed, Ultrasonic assisted sustainable dyeing of mordanted silk fabric using arjun (Terminaliaarjuna) bark extracts, Environ, Prog. Sustain. Energy, 38 (2019), 5331-5339.
16
N. Amin, F. Rehman, S. Adeel, T. Ahamd, M. Munner, A. Haji, Sustainable application of cochineal-based anthraquinone dye for the coloration of bio-mordanted silk fabric, Environ. Sci. Poll. Res., 27(2020), 6851-6860.
17
G. Singh, P. Mathur, N. Singh, J. Sheikh, Functionalization of wool fabric using kapok flower and bio-mordant, Sustain. Chem. Pharm., 14(2019), 100184.
18
S. Kadam, A. Sharma, S. Salam, I. Bramhecha, J. Sheikh, Utilization of Rice Straw as a source of biomolecules for sustainable multifunctional finishing vis a vis dyeing of wool, J. Nat. Fiber., 2019, doi.org/10.1080/15440478.2019.1581120.
19
J. Sheikh, As. Agrawal, H. Garg, A. Agarwal, P. Mathur, Functionalization of wool fabric using pineapple peel extract (PPE) as a natural dye, AATCC J. Res., 6(2019), 16-20.
20
L. Ford, C. M. Rayner, R. S. Blackburn, Degradation of lucidin: new insights into the fate of this natural pigment present in dyers madder (rubiatinctorum L.) during the extraction of textile artefacts, Dye Pigm., 154(2018), 290-295.
21
M. L. Vazquez, Molecular evolution of the internal transcribed spacers in red oak (quercus sect Lobatae), Comput. Biol. Chem., 83(2019), 107117-107122.
22
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R. McDonald, Color physics for industry, Dyers company publication trust, Bradford, 1997.
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M.D. Fairchild, Color Appearance Models, Wiley & Sons Ltd., Chichester, 2005.
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M. Hosseinnezhad, K. Gharanjig, N. Razani, H. Imani, Green dyeing of wool fibers with madder: study of combination of two biomordant on K/S and fastness, Fiber Polym., 10.1007/s12221.
33
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34
M. Yusuf, S. A. Khan, M. Shabbir, F. Mohammad,Developing a shade range on wool by madder (Rubiacordifolia) root extract with gallnut (quercusinfectoria) as biomordant, J. Nat. Fiber, 14(2017), 597-607.
35
Y. Yin, J. Jia, T. Wang, Optimization of natural anthocyanin efficient, J. Cleaner Prod., 149(2017), 673-679.
36
M. Yusuf, F. Mohammad, M. Shabbir, M. A. Khan,Eco-dyeing of wool with Rubiacordifolia root extract: Assessment of the effect of Acacia catechu as biomordant on color and fastness properties, Textile Cloth. Sustain., 2(2016), 10-16.
37
H. Gharanjig, K. Gharanjig, M. Hosseinnezhad, S.M. Jafari, Development and optimization of complex coacervates based on zedo gum, cress seed gum and gelatin, Int. J. Biol. Macromol., 148(2020), 31-40.
38
ORIGINAL_ARTICLE
The Effect of Antisolvent Dropping Delay Time on The Morphology and Structure of the Perovskite Layer in the Hole Transport Material Free Perovskite Solar Cells
Antisolvent-assisted one-step spin coating approach has been investigated as an effective method for the preparation of perovskite solar cells (PSC) under ambient conditions. The influence of antisolvent dropping delay time on the final morphology was investigated. The photovoltaic device with FTO/TiO2 block/TiO2-mp/CH3NH3PbI3/Au structure was fabricated, and the impact of different delay times on the morphology of CH3NH3PbI3 layers were examined. The hole transport materials (HTM) free PSC with optimal antisolvent dropping delay time exhibited open-circuit voltage (Voc) of 0.76 V with power conversion efficiency (PCE) of 3.54 %, which were much higher than those of the PSC fabricated without antisolvent treatment (Voc of 0.64 V and PCE of 1.51 %). Scanning electron microscopy and X-ray diffraction were used to study the morphology and structure of the CH3NH3PbI3 films. Photocurrent-voltage curves were plotted to investigate the photoelectric properties, carrier transfer, and recombination process in the fabricated perovskite solar cells. Our findings indicated that the proposed antisolvent-assisted one-step spin coating approach can provide a high-performance atmospheric method for fabrication of low-cost HTM-free perovskite solar cells.
https://pccc.icrc.ac.ir/article_81671_6721c11a7387bf64b1f2165f8e6ba7d9.pdf
2021-02-01
47
54
10.30509/pccc.2021.81671
Optimal delay time
Antisolvent
Hole transport materials (HTM)
Perovskite solar cell
E.
Maleki
elham.maleki754@gmail.com
1
Department of Chemistry, Kashan University, Kashan, Iran
AUTHOR
M.
Ranjbar
marandjbar@irost.ir
2
Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran
LEAD_AUTHOR
S. A.
Kahani
kahani@kashanu.ac.ir
3
Department of Chemistry, Kashan University, Kashan, Iran
AUTHOR
M. Hosseinnezhad, M. Ghahari, H. Shaki, J. Movahedi, Investigation of DSSCs performance: the effect of 1,8-naphthalimide dyes and Na-doped TiO2, Prog. Color Colorants Coat., 13(2020), 177-185.
1
J. Movahedi, M. Hosseinnezhad, H. Haratizadeh, N. Falah, Synthesis and investigation of photovoltaic properties of new organic dye in solar cells devices, Prog. Color Colorants Coat., 12(2019), 33-38.
2
M. Hosseinnezhad, H. Shaki, Investigation of photovoltaic properties of 1,8-naphthalimide dyes in dye-sensitized solar cells, Prog. Color Colorants Coat., 11(2018), 253-258.
3
M. A. Green, A. Ho-baillie, H. J. Snaith, The emergence of perovskite solar cells. Nat photonic., 8(2014), 506-514.
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A. Miyata, A.Mitioglu, P. Plochocka, O. Portugall, J. W. Wang, S. D. Stranks, H. J. Snaith, R. J. Nicholas, Direct measurement of the exciton binding energy and effective masses for charge carriers in organic-inorganic tri-halide perovskites. Nat Phys., 11(2015), 582-587.
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S. D. Stranks, G. E. Eperon, G. Grancini, C. Menelaou, M.J. Alcocer, T. Leijtens, L.M. Herz, A. Petrozza, H.J. Snaith, Electron-hole diffusion lengths exceeding 1micrometer in an organometal trihalide perovskite absorber, Science,342(2013), 341-344.
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G. E. Eperon, S. D. Stranks, C. Menelaou, M. B. Johnston, L.M. Herz, H.J. Snaith, Environmental science formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells, Energy Environ Sci., 7(2014), 982-988.
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M. M. Lee, J. Teuscher, T. Miyasaka, T.N. Murakami, H. J. Snaith, Efficient hybrid solar cells based on meso-Superstructured organometal halide perovskites, Science, 338(2012), 643-647.
8
J. Burschka1, N. Pellet1, S. J. Moon, R. Humphry-Baker, P. Gao, M.K. Nazeeruddin, M. Grätzel, Sequential deposition as a route to high-performance perovskite-sensitized solar cells, Nature, 499(2013), 316-319.
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M. Xiao, F. Huang, W. Huang, Y. Dkhissi, Y. Zhu, J. Etheridge, A. Gray‐Weale, U. Bach, Y.B. Cheng, L. Spiccia, A fast deposition-crystallization procedure for highly efficient lead iodide perovskite thin-film solar cells, Angew. Chemie. Int Ed., 126(2014), 10056-10061.
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N. J. Jeon, J. H. Noh, Y. C. Kim, W. S. Yang, S. Ryu, S. I. Seok, Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells, Nat Mater., 13(2014), 897-903.
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Q. Chen, H. Zhou, Z. Hong, S. Luo, H. S. Duan, H. H. Wang, Y. Liu, G. Li, Y. Yang, Planar heterojunction perovskite solar cells via vapor-assisted solution process, J. Am. Chem. Soc., 136(2013), 622-623.
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M. M. Tavakoli, L. Gu, Y. Gao, C. Reckmeier, J. He, A.L. Rogach, Y. Yao, Z. Fan, Fabrication of efficient planar perovskite solar cells using a one-step chemical vapor deposition method, Sci. Rep., 5(2015), 1-9.
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S. Sanchez, X. Hua, N. Phung, U. Steiner, A. Abate, Flash infrared annealing for antisolvent-free highly efficient perovskite solar cells, Adv. Energy Mater., 8(2018), 1-7.
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M. Konstantakou, D. Perganti, P. Falaras, T. Stergiopoulos, Anti-solvent crystallization strategies for highly efficient perovskite solar cells, Crystals, 291(2017), 1-21.
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P. W. Liang, C.Y. Liao, C.C. Chueh, F. Zuo, S.T. Williams, X. K. Xin, J. Lin, A. K.Y. Jen, Additive enhanced crystallization of solution-processed perovskite for highly efficient planar-heterojunction solar cells, Adv. Mater., 26(2014), 3748-3754.
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R. Surabhi, K. Bhat, A. Batra, A. Chilvery, M. Aggarwal, Synthesis, purification, crystal growth and characterization of Lead Iodide (PbI2) purified by a low-temperature technique, Adv. Sci. Eng. Med., 6(2014), 1269-1273.
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L. Etgar, P. Gao, Z. Xue, Q. Peng, A.K. Chandiran, B. Liu, Mesoscopic CH3NH3PbI3 /TiO2 heterojunction solar cells, J. Am. Chem. Soc., 134(2012), 17396-17399.
18
K. Kara, D. A. Kara, C. Kırbıyık, M. Ersoz, O. Usluer, A. L. Brisenog, M. Kus, Solvent washing with toluene enhances efficiency and increases reproducibility in perovskite solar cells, RSC Adv., 6(2016), 26606-26611.
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J. W. Jung, S. T. Williams, A. K. Y. Jen. Low-temperature processed high-performance flexible perovskite solar cells via rationally optimized solvent washing treatments. RSC Adv., 4(2014), 62971-62977.
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J. Zhang, G. Zhai, W. Gao, C. Zhang, Z. Shao, F. Mei, J. Zhang, Y. Yang, X. Liu, B. Xu, Accelerated formation and improved performance of CH3NH3PbI3-based perovskite solar cells via solvent coordination and anti-solvent extraction, J. Mater. Chem. A, 5(2017) 4190-4198.
21
M. Xiao, L. Zhao, M. Geng, Y. Li, B. Dong, Z. Xu, L. Wan, W. Liab, S. Wang, Selection of anti-solvent of efficient and stable cesium-containing triple cation planar perovskite solar cells, Nanoscale, 10(2018), 12141-12148.
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X. Guo, C. Mccleese, C. Kolodziej, A. C. S. Samia, Y. Zhao, C. Burda, Identification and characterization of the intermediate phase in hybrid organic-inorganic MAPbI3 perovskite, Dalton Trans., 45(2016), 3806-3813.
23
M. Saliba, T. Matsui, J. Y. Seo, K. Domanski, J. P. Correa-Baena, M.K. Nazeeruddin, S.M. Zakeeruddin, W. Tress, A. Abate, A. Hagfeldt, M. Grätzel, Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency, Energy Environ. Sci., 9(2016), 1989-1997.
24
W. Nie, H. Tsai, R. Asadpour, J. C. Blancon, A. J. Neukirch, G. Gupta, J. J. Crochet, M. Chhowalla, S. Tretiak, M. A. Alam, H. L. Wang, A. D. Mohite, High-efficiency solution-processed perovskite solar cells with millimetre-scale grains, Science, 347(2015), 522-526.
25
ORIGINAL_ARTICLE
An Electrospun Zein/Graphene Oxide Nanofibrous Composite: Typical Application as a New Biopolymeric Adsorbent in Removal of Methylene Blue and Malachite Green Dyes from Aqueous Media
In this study, for the first time, an electrospun nanofibrous (Nfs) composite was prepared from Zein biopolymer and graphene oxide (Ze-GONfs). The effective parameter in electrospining preparation of zrin-GO nanofiber was the amount of zein. Highly mechanical stable membranes were obtained using 30% w/v in glacial acetic acid. The fiber diameter distribution was in the range of 41–50 nm (zein), 31–40 nm (0.5% GO), 29–39 nm (1.0% GO), and 28–37 nm (1.5% GO). The structural morphology of the nanofibrous composites were characterized using Fourier transform infrared, scanning electron microscope (SEM) and X-ray diffractometer. As an application of the prepared biopolymeric nanofibrous, the removal of malachite green (MG) and methylene blue (MB) (as cationic industrial dyes) from aqueous medium using Ze-GONfs was investigated as a model. The effect of various parameters such as solution pH, adsorbent dosage, dye concentration, time and temperature were evaluated by the Ze-GONfs. Detailed analysis of the adsorption kinetics showed that the adsorption process followed a pseudo-second-order model. The adsorption isotherm was best fitted by the Langmuir model. The thermodynamic results showed that MB and MG adsorption onto the Ze-GONfs was endothermic and spontaneous.
https://pccc.icrc.ac.ir/article_81679_01b126a89a91ede22493b3a340bb43b6.pdf
2021-02-01
55
65
10.30509/pccc.2021.81679
Electrospinning
Nanofibers Membranes
biopolymer
Adsorption
Kinetic
A.
Soraya Keshtiban
azamsorayya@yahoo.com
1
Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran.
AUTHOR
S. M.
Seyedahmadian
seyedahmadian@azaruniv.ac.ir
2
Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran.
AUTHOR
B.
Habibi
biuckhabibi_a@yahoo.com
3
Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran.
AUTHOR
Kh.
Farhadi
khalil.farhadi@yahoo.com
4
Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, P.O. Box: 165‐5715944931, Urmia, Iran
LEAD_AUTHOR
D. Pooja, P. Kumar, P. Singh, Sensors in water pollutants monitoring: role of material advanced functional materials and sensors, Springer Verlag, Singapore, 2020, 21-41.
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B. Lellis, C. Z. Fávaro-Polonio, J. A. Pamphile, J. C. Polonio, Effects of textile dyes on health and the environment and bioremediation potential of living organisms, Biotechnol. Res. Innov., 3(2019), 275–290.
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P. Vitale, P. B. Ramos, V. Colasurdo, M. B. Fernandez, G. N. Eyler, Treatment of real wastewater from the graphic industry using advanced oxidation technologies: Degradation models and feasibility analysis, J. Clean. Prod., 206(2019), 1041–1050.
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ORIGINAL_ARTICLE
Transmission and Absorption Properties in the Novel Ultra-optical TiO2-Bi2O3-PbO Glass System
Glasses with ultra-optical properties are most favored in all-optical communication devices, e.g. switches. Heavy polarizable Bi2O3 and PbO, in their high contents, have achieved the most high index of refraction and dispersion in oxide glasses, particularly in cooperation with relatively heavy glass conditional former, such as, TiO2. In this research, transmission and absorption properties of novel TiO2-Bi2O3-PbO (TBP) glass system were characterized by the spectrophotometry techniques in the near infera-red (2.5-10 µm) and ultraviolet/visible (0.25-1 µm) regions. The corresponding traces were explored with respect to the glass compositions. The Taus plot (method) was executed for the absorption coefficient (attenuation) measurements, and the subsequent related predictions in the uv/visible regions. Results indicated that TBP glasses claimed relatively appreciable absorption around, 7µm due to Ti-O bonds. Addition of TiO2 shifted transmission cut off and the related absorption peaks to higher wavelengths and broadened the absorption region. In the uv/visible region, addition of TiO2, as a conventional glass former, widened the transmission window in all by shifting attenuation to shorter wavelengths, where steeper absorption tails were observed. The overall attenuation in TBP glasses were more affected by Bi2O3 than PbO.
https://pccc.icrc.ac.ir/article_81682_0e5cfa1bac8e2b5bb323942df2d4a7b3.pdf
2021-02-01
67
78
10.30509/pccc.2021.81682
Attenuation
near infera-red
uv/visible
Spectroscopy
ultra-optical
H.
Ahmadi Moghaddam
ahmadi@icrc.ac.ir
1
Department of Inorganic Pigments and Glazers, Institute for Color Science and Technology,Tehran, Iran.
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