eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
1
14
10.30509/pccc.2019.80303
80303
مقاله پژوهشی
Control over Power Conversion Efficiency of BHJ Solar Cells: Learn more from Less, with Artificial Intelligence
A. Ashtiani Abdi
ashtiani-aa@icrc.ac.ir
1
F. Nourmohammadian
2
Y. Mohammadi
3
M. R. Saeb
4
Department of Organic Colorants, Institute for Color Science and Technology, Tehran, Iran
Department of Organic Colorants, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
Petrochemical Research and Technology Company (NPC-rt), National Petrochemical Company (NPC), Tehran, Iran
Department of Resin and Additives, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
Harvesting the energy from the sun through the bulk heterojunction (BHJ) solar cells need materials with specific electronic characteristics. However, any promising material if cast improperly in cells will end into low or even null power conversion efficiency (PCE). Cell casting optimization is a time/material consumable step in any photovoltaic manufacturing practice. In this study, we showed that how the artificial intelligence (AI) could help to find optimum values of device preparation variables. For this purpose, an in-house code will catch the input variables (donor: acceptor ratio, spin casting rate, annealing temperature); learn the trends by the hybrid artificial neural network (ANN), genetic algorithm (GA) and optimize the output results simultaneously. The results showed that ANN/GA is capable to learn the trends of relatively small size dataset without over-fitting. This study highlights that how implementing the suggested AI model can help to learn more information and find the optimum recipe from less number of experiments with the highest precision.
https://pccc.icrc.ac.ir/article_80303_debe705fb42781717acde6bcf47d2708.pdf
bulk heterojunction solar cells
Artificial Neural Network
Genetic Algorithm
Multi-Objective Optimization
eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
15
23
10.30509/pccc.2019.80628
80628
Electrochemical Investigation of The Effect of Penicillin G Benzathine as a Green Corrosion Inhibitor For Mild Steel
M.R. Gholamhosseinzadeh
1
R. Farrahi-Moghaddam
2
Department of Chemistry, Kerman Branch, Islamic Azad University, P.O. Box: 7635131167, Kerman, Iran
Department of Chemistry, Kerman Branch, Islamic Azad University, P.O. Box: 7635131167, Kerman, Iran.
In this paper, the effect of penicillin G benzathine (PGB) drug as a green corrosion inhibitor on mild steel in 1.0 M hydrochloric acid solution has been investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency (IE) was found to increase with increasing inhibitor concentration. Potentiodynamic polarization measurements indicated that PGB is a mixed type inhibitor. The results of potentiodynamic polarization and EIS measurements demonstrated that the adsorption of PGB on mild steel in 1.0 M HCl follows Langmuir isotherm. The calculated values of free energy indicated that both physical and chemical adsorption take place. The IE values obtained from EIS measurements show a reasonable agreement with those obtained from potentiodynamic polarization method.
https://pccc.icrc.ac.ir/article_80628_9ebebad33b6644e6562f8eafc7f899a6.pdf
Penicillin G benzathine
Inhibition Efficiency
potentiodynamic polarization
electrochemical impedance spectroscopy
eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
25
32
10.30509/pccc.2019.80586
80586
مقاله پژوهشی
Interpretation of Electrochemical Noise Signals Arising from Symmetrical and Asymmetrical Electrodes Made of Polypyrrole Coated Mild Steel
H. Arabzadeh
1
M. Shahidi Zandi
2
M.M. Foroughi
3
Department of Chemistry, Kerman Branch, Islamic Azad University, P. O. Box: 7635131167, Kerman, Iran.
Department of Chemistry, Kerman Branch, Islamic Azad University, P. O. Box: 7635131167, Kerman, Iran.
Department of Chemistry, Kerman Branch, Islamic Azad University, P. O. Box: 7635131167, Kerman, Iran.
This article applies the standard deviation of partial signal (SDPS) plots of electrochemical noise (EN) current signals originating from corrosion events on the symmetrical and asymmetrical electrodes made of uncoated and polypyrrole (PPy)-coated mild steel alloy in 4000 ppm NaCl+1000 ppm NaNO2 solution. Signal recording was performed after 30, 60, 90 min and 24 h from immersion time. Two types of symmetrical electrodes were made from uncoated (Bare-Bare) and PPy coated (PPy-PPy) mild steel electrodes. The asymmetrical electrodes (PPy-Bare) prepared from a difference in the coating between two working electrodes which are otherwise identical. The time records and the corresponding SDPS plots obtained from the three types of systems show an increase in the amplitude and the time width of EN current transients with movement from Bare-Bare to PPy-PPy. Therefore, the corrosion severity increases with movement from Bare-Bare to PPy-PPy. Over time from 30 min to 24 hours‚ the PPy coating in the Bare-PPy configuration is early insulated compared to the PPy-PPy. It seems that the symmetrical configuration (Bare-PPy) is the suitable system for evaluating the corrosion protection of PPy coatings by EN technique.
https://pccc.icrc.ac.ir/article_80586_f1f2c51d9552f0ef0d4402fec955a814.pdf
Electrochemical noise
Symmetrical and asymmetrical cells
wavelet analysis
Standard deviation of partial signal (SDPS) plot
Polypyrrole
Mild steel
eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
33
38
10.30509/pccc.2019.81271
81271
مقاله پژوهشی
Synthesis and Investigation of Photovoltaic Properties of New Organic Dye in Solar Cells Device
J. Movahedi
1
M. Hosseinnezhad
hosseinnezhad-mo@icrc.ac.ir
2
H. Haratizadeh
3
N. Falah
4
Department of Physics, Shahrood University of Technology, Shahrood, Iran
Department of Organic Colorants, Institute for Color Science and Technology, Tehran, Iran
Department of Physics, Shahrood University of Technology, Shahrood, Iran
Department of Physics, Shahrood University of Technology, Shahrood, Iran
In this paper, we designed and synthesized free-metal dyes based on indoline. The proposed dyes were synthesized from phenothiazine as the starting material by standard reactions. The chemical structure of the synthesized dye was confirmed using FT-IR, 1HNMR and DSC techniques. Spectrophotometric measurements of the organic dyes in acetonitrile and on a TiO2 substrate were carried out in order to assess the changes in the dye. Maximum absorption wavelength for organic dye in solution is 453 nm and on TiO2 film is 467 nm. Finally, the proposed dyes were used as sensitizer in a dye solar cell structure and their photovoltaic properties were investigated. The Conversion efficiency for the synthesized dye is 0.92%.
https://pccc.icrc.ac.ir/article_81271_eb7aa573e254d6e751c56f8f5fe69adf.pdf
Dye-sensitized solar cells
Organic dyes
Photovoltaic materials
Power conversion efficiencies
Indoline
eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
39
56
10.30509/pccc.2019.81492
81492
مقاله پژوهشی
Application of a New Self-Cleaning Filter for Colored Wastewaters Treatment Using Laccase Enzyme Immobilized on Activated CARBON powder and fiber
M.S. Khazravi
mh.khazravi@gmail.com
1
M. Bahmaei
m_bahmaei@iau-tnb.ac.ir
2
M. E. Olya
olya-me@icrc.ac.ir
3
M. Etezad
etezad-ma@icrc.ac.ir
4
Chemistry Department, Tehran North Branch, Islamic Azad University, Tehran, Iran
Chemistry Department, Tehran North Branch, Islamic Azad University, Tehran, Iran
Department of Environmental Research, Institute for Color Science and Technology, Tehran, Iran
Department of Environmental Research, Institute for Color Science and Technology, Tehran, Iran
The objective of this work is investigation of the adsorption and decomposition of Reactive Blue 19 from industrial wastewaters using laccase enzyme immobilized on activated carbon powder and fiber as adsorbent. Time, pH, temperature, stirring rate, the amount of the adsorbent, dye initial concentration, solution flow rate in the column and column height were studied as key operating parameters to determine the optimal adsorption conditions. The results indicated 80.70% of the adsorption for reactive blue 19 by immobilized laccase enzyme on adsorbent. In addition, kinetic parameters of the enzyme (Vmax and Km), optimal temperature effect, optimal pH and thermal stability of the free and stabilized laccase were studied and the results showed 66.66% of laccase enzyme immobilization yield on the adsorbent. The study of adsorption isotherms (Langmuir, Freundlich and Temkin) showed that the process follows a Langmuir model with a correlation coefficient (R2: 0.9389). Dye removal efficiency and characterization of the intermediate products of removal process were investigated using UV-Vis, TOC and LC/MS methods. Kinetic and thermodynamic models were studied based on the obtained results, the adsorption process follows a pseudo second order kinetic model. Determination of Gibbs free energy, ∆G, enthalpy, ∆H and entropy, ∆S, showed that the reaction is a spontaneous, exothermic process.
https://pccc.icrc.ac.ir/article_81492_00f846f8a71234ac2d37898dd3cbbe0c.pdf
Activated carbon powder
Activated carbon fibers
Laccase enzyme
Reactive Blue 19
immobilized Enzyme
eng
Institute for Color Science and Technology (ICST)
Progress in Color, Colorants and Coatings
2008-2134
2383-1790
2019-02-01
12
1
57
70
10.30509/pccc.2019.81493
81493
مقاله پژوهشی
Anticorrosive Performance of Polyester–melamine Coating Fortified with Zinc Ferrite Nanoparticles
S . Mahvidi
mahvidi-sa@icrc.ac.ir
1
M. Gharagozlou
gharagozlou@icrc.ac.ir
2
M. Mahdavian
mahdavian-m@icrc.ac.ir
3
S. Naghibi
sanaz_n77@yahoo.com
4
Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology, Tehran, Iran
Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology, Tehran, Iran
Surface Coatings and Corrosion Department, Institute for Color Science and Technology, Tehran, Iran
Department of Materials Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran
In this study, nanoparticle zinc ferrites with different particle sizes were synthesized via sol-gel method using ferric nitrate and zinc nitrate. The obtained gel was dried and calcined at three different temperatures (i.e. 500, 600 and 800 °C) for 2 h. Adequate amounts of the as-synthesized nanoparticle samples were then added to the mixture of polyester resin and formaldehyde resin. The obtained mixtures were applied on the surface of mild steel specimens, and then the corrosion behavior of the coated mild steel was studied by electrochemical impedance spectroscopy and salt spray. In addition, mechanical and thermal properties of the coating were evaluated using dynamic mechanical thermal analysis. The crystalline and chemical structures of the coatings were investigated using X–ray diffraction analysis and infrared spectroscopy, respectively. The results showed that not only the incorporation of nanoparticle zinc ferrites in the coating has no negative effects on curing, but also increased corrosion protective performance and mechanical properties of the coatings.
https://pccc.icrc.ac.ir/article_81493_bbfd5fbaebdc9732e0953bffdb79fc9d.pdf
Anticorrosion performance
Organic coatings
Polyester melamine paint
Zinc ferrites nanoparticle